Siyah çayların aroma maddeleri üzerine araştırma

Araştırmada, Ortodoks yöntemiyle üretilen ve iki fabrikadan (Selimiye ve Çayeli) alınan 7'şer pasaj çay kullanılmıştır. Bu çayların ekstraktları, Llkens-Nickerson aparatı kullanılarak, aynı anda destilasyon-ekstraksiyon (SDE) yöntemi ile elde edilmiştir. Ekstraktların uçucu aroma bileşenleri, gaz kromatografi (GC) ve gaz kromatografi / kütle spektrometre (GC / MS) ile analiz edilmiştir. Çay örneklerinin analizi sonucu, alkoller, aldehitler, asitler, hidrokarbonlar, ketonlar, laktonlar ve fenolikler grubunda olan 25 ile 38 arasında değişen uçucu aroma bileşeni teşhis edilmiştir. Bu bileşenlerden oranı % 5 ve daha çok olanlar, büyükten küçüğe, Selimiye fabrikası çaylarında benzoik asit, trans-2-hekzenal, a-iyonon; Çayeli fabrikası çaylarında benzoik asit, trans-2-hekzenal, guayakol, hekzanoik asit, dekanoik asit, cis-3-hekzen-1-ol ve siklohekzanoldür.

Research on the aroma compounds of black tea

Seven tea samples produced with the Orthodox Method from each of the Çayeli and Selimiye plants were used in this research. The extracts of these tea samples were obtained with the simultaneous steam distillation and extraction (SDE) method by using Likens-Nickerson apparatus. Volatile aroma compounds of the extracts were analyzed with gas chromatography (GC) and gas chramatography / mass spectrometer (GC/MS). As a result of analysis of tea samples, 25 to 38 volatile aroma compounds including alcohols, aldehydes, acids, hydrocarbons, ketones, lactones and phenolics groups were identified and quantified. Aroma compounds which account for 5 % or more in total, from the highest to the lowest, were benzole acid, E-2-hexenal, a-ionone In Selimiye plant teas and benzole acid, E-2-hexenal, guaiacol, hexanoic acid, decanoic acid, Z-3-hexen-1-ol, cyclohexanol in Çayeli plant teas.

___

  • FERNANDO, V. and ROBERTS, G. R. 1984. The effect of process parameters on seasonal development of flavour in black tea. J.Sci.Food Agric. 35: 71 -76.
  • GROSCH, W. 1982. Lipit degradation products and flavours. In: Morton ID, MacLeod A.J.(eds) Food flavours. Part A-Introduction. Elsevier, Amsterdam, 325 sayfa.
  • GUENTHER, E. 1955. The essential oils. Vol I., Van Nostrand Company, New York, 427 sayfa.
  • HATANAKA, A. and KAJIWARA, T. 1981. Occurrence of (E)-3-hexenal in Thea sinensis leaves. Z.Naturforsch. 36B:755-758.
  • HAZAKRIKA, M., MAHANTA, P. K. and TAKEO, T. 1984. Studies on some volatile flavour constituents in Orthodox black teas of various clones and flushes in North-east India. J.Sci.Food Agric. 35:1201-1207.
  • KAJIWARA, T., SEIKYA, J., ASANO M. and HATANAKA, A. 1982. Enantioselectivity of enzymatic clevage reaction of 13-hydroperoxy linolenic acid to C-6 aldehyde and 12-oxo acid in tea chloroplasts. Agric. Biol. Chem. 46: 3087-3088.
  • KAWAKAMI, M., KOBAYASHI, A. and KATOR, K. 1993. Volatile constituents of Rooibos Tea (Aspalathus linearis) as affected by extraction process. J.Agric. Food Chem. 41: 633-636.
  • KAWAKAMI, M., GANGULY, N. S., BANERJEE, J. and KOBAYASHI, A. 1995. Aroma composition of Oolong tea and black tea by brewed extraction method and characterizing compounds of Darjeeling tea aroma. J. Agric. Food Chem. 43:200-207. MA, S.,
  • WATANABE, N., YAGI, A. and SAKATA, K. 2001. The(3R,9R)-3-hydroxy-7,8-dihryro-p-ionol disaccharide glycoside is an aroma precursor in tea tea leaves. Phytochemistry. 56: 819-825.
  • MAHANTA, P. K., HAZARIKA, M. and TAKEO, T. 1985. Flavour volatiles and lipids in various components of tea shoots Camellia sinensis, (L.),O. Kuntze. J. Sci.Food Agric. 36:1130-1132.
  • MAHANTA, P. K. and BARUAH, S. 1988. Flavour volatiles of Assam CTC black teas manufactured from different plucking standards and Orthodox teas manufactured from different altitudes of Darjeeling. J. Sci. Food Agric. 45: 317-324.
  • MUGGLER-CHAVAN, F., VIANI, R., BRICOUT, J., MARION, J. P., MECHTLER, H., REYMOND, D. and EGLI, R. 1969. Sur la composition de l'arome de the (3). Identification de deux cetones apparanrees aux ionones. Helv. Chim. Acta. 52:549-550.
  • NATARAJAN, C, ANANDARAMAN, S. and SHANKARANAYARANA, M. 1974. Tea flavor. Biochem. Rew. 45:10-36.
  • RAVICHANDRAN, R. aıîd PARTHIBAN, R. 1998. The impact of processing techniques on tea volatiles. Food Chemistry.62(3): 347-353.
  • RAVICHANDRAN, R. 2002. Carotenoid composition, distribution and degradation to flavour volatiles during black tea manufacture and the effect of carotenoid supplementation on tea quality and aroma. Food Chemistry. 78: 23-28.
  • RENNER, E. and MELCHER, F. 1978. Untersuchungen überdie Minorfettsâuren des Milchfetts. Milchwissenschaft. 33:281-284.
  • SAIJO, R. and TAKEO, T. 1970. The formation of aldehydes from amino acids by tea leaves extracts. Agric. Biol. Chem. 34:227-233.
  • SCHREIER, P. 1988. Modern methods of plant analysis. New series,Vol.8; Springer, Berlin, 296 sayfa. TAKEO T. 1981. Production of linalool and geranlol by hydrolytic breakdown of bound forms in disrupted tea shoots.Phytochemistry. 20: 2145-2146.
  • TAKEO, T. and Mahanta, P. K. 1983. Comparison of black tea aromas of Orthodox and CTC tea and of black teas made from different varieties. J.Sci.Food Agric. 34: 307-310.
  • TRESSL, R., KOSSA, T., RENNER, R. and KOPPLER, H. 1976. Gaschromatographisch-massenspektrometrische Untersuchungen über die Bildung von Phenolen und aromatischen Kohlenwasserstoffen in Lebensmitteln. Z Lebensm Unters Forsch. 162:123-130.