Emir Üzümünden Geleneksel Yöntemle Üretilen Doğal Köpüren Şarabın Aroma Bileşiklerinin Belirlenmesi

Bu çalışma, emir üzümünden geleneksel yöntemle (şampanya yöntemi) üretilen doğal köpüren şarapların aroma bileşiklerini ve duyusal özelliklerini belirlemek amacıyla ele alınmıştır. Aroma bileşiklerinin miktarlarının belirlenmesi ve tanımlanması alev iyonlaşma dedektörlü gaz kromatografisi - kütle spektrometresi (GC-MS/FID) ile gerçekleştirilmiştir. Elde edilen sonuçlara göre; köpüren şarapta 21 adet ester, 19 adet yüksek alkol, 10 adet uçucu asit, 4 adet uçucu fenol, 4 adet keton, 4 adet lakton, 2 adet terpen, 1 adet uçucu kükürtlü bileşik ve 1 adet furan bileşiği olmak üzere toplamda 66 adet aroma bileşiği tanımlanmıştır. Toplam aroma konsantrasyonu 160,5 mg/L olarak hesaplanmıştır.Koku aktiflik değerlerine göre, Emir üzümünden elde edilen doğal köpüren şarabın aromasına en büyük katkıyı etil oktanoatın yaptığı, bu bileşiği sırasıyla, etil hekzanoat, etil dekanoat, 4-vinil guaiacol, etil bütanoat, 2-fenil etil asetat, izoamil asetat ve izoamil alkolün izlediği tespit edilmiştir. Öte yandan, köpüren şaraplar hem duyusal hem de köpürme özellikleri bakımından "iyi" olarak değerlendirilmiştir

Aroma Compounds in Sparkling Wine of Emir Grapes Produced by Traditional Method

In this study, aroma compounds of sparkling wine produced with traditional method (Champagne method) obtained from Emir grape and its sensory properties were investigated. Aroma compounds were quantified and identified by gas chromatography (GC)–flame ionisation detection and GC–mass spectrometry. According to results, a total of 66 aroma compounds were identified and quantified including 21 esters, 19 alcohols, 10 volatile acids, 4 volatile phenols, 4 ketones, 4 lactones, 2 terpens, 1 volatile sulfurs, and 1 furan. The total concentration of aroma compounds was 160.5 mg/L. According to odor activity values, the most important contributors to the aroma of a natural Sparkling wine was ethyl octanoate and followed by ethyl hexanoate, ethyl decanoate, 4-vinyl guaiacol, ethyl butanoate, 2-phenyl ethyl acetate, isoamyl acetate, isoamyl alcohol, respectively. On the other hand, sparkling wines were evaluated as “good” in terms of sensory and foaming properties

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  • [1] Canbaş, A., 1983. Köpüren Şaraplar Çeşitleri ve Teknolojisi. Tekel Enstitüleri, Yayın No: Tekel 278 EM/002, İstanbul, 15s.
  • [2] Anon., 2004. Are You A Connoisseur of Champagne. The Ultimate Wine-Tasting Magazine, No: 5, Bordeaux, 112p.
  • [3] Feulliat, M., Charpentier, C., 1982. Autolysis of yeasts in champagne. American Journal of Enology and Viticulture 33: 6-13.
  • [4] Martinez-Rodriquez, A., Carrascosa, A, V., MartinAlvarez, P.J., Moreno-Arribas, V., Polo, M.C., 2002. Influence of the yeast strain on the changes of the amino acids, peptides and proteins during sparkling wine production by the traditional method. Journal of Industrial Microbiology and Biotechnology 29: 314-322.
  • [5] Azondanlou, R., Darbellay C., Luisier J.-L., Villetaz J., Amadó, R., 2003. Development of a model for quality assessment of tomatoes and apricots. Lebensmittel-Wissenschaft Tecnologie 36: 223– 233.
  • [6] Etievant, P.X., 1991. Wine. -in: MAARSE, H. (Ed.) Food and beverages. Marcel Dekker. Inc., New York, pp. 483–546.
  • [7] Bayanove, C., Baumes, R. L., Crouzet, J., Gunata, Z., 1998. Aromas, ed. C. Flanzy, in Oenologie, Paris, TEC and DOC, 164-235.
  • [8] Cabaroğlu, T.,1995. Nevşehir ve Ürgüp Yöresinde Yetiştirilen Beyaz Emir Üzümünün ve Bu Üzümden Elde Edilen Şarapların Aroma Bileşikleri Üzerine Araştırmalar. Çukurova Üniversitesi Fen Bilimleri Enstitüsü Gıda Mühendisliği Anabilim Dalı Doktora Tezi, Adana. 152s.
  • [9] Cabaroğlu, T., Canbaş, A., Baumes, R., Bayonove, C., Lepoutre, J.P., Gunata, Z., 1997. Aroma composition of a white wine of Vitis vinifera L. cv. Emir as affected by skin contact. Journal of Food Science 62: 680–683.
  • [10] Canbaş, A., Cabaroğlu, T., Erten, H., Nurgel, C., Selli, S., 2001. Önemli Bazı Üzüm Çeşitlerinin Şaraplık Değerlerinin Belirlenmesi ve Elde Edilen Şarapların Kalitesinin Geliştirilmesi Üzerine Araştırmalar. TÜBİTAK-TOGTAG/TARP-1858.
  • [11] Bozdoğan, A., Canbas, A, 2011. Influence of yeast strain, immobilization and aging time on the changes of free amino acids and amino acids in peptides in bottle-fermented sparkling wines obtained from Vitis vinifera cv. Emir. International Journal of Food Science and Technology 46: 1113- 1126.
  • [12] Anon., 2005. Reference Methods for Analysis of Wines. Official Journal of European Communities, Council Regulation (EEC) No:1990R2676-EN- 2005,194s.
  • [13] Van Ruth, S.M., Roozen, J.P., Posthumus, M.A., 1995. Instrumental and sensory evaluation of the flavour of dried French beans (Phaseolus vulgaris) influenced by storage conditions. Journal of Agricultural and Food Chemistry 69: 1909-1914.
  • [14] Rega, B., Fournier, N., Guichard, E., 2003. Solid Phase Microextration (SPME) of orange juice flavor: odor representativeness by direct gas chromatography olfactometry (D-GC-O). Journal of Agricultural and Food Chemistry 51: 7092-7099.
  • [15] Mehinagic, E., Royer, G., Bertrand, D., Symoneaux, R., Jourjon, F., 2004. Prediction of apple sensory quality by physical measurements. Postharvest Biology and Technology 34: 257-269.
  • [16] Blanch, G.P., Reglero, G., Herraiz, M., Tabera, J., 1991. A comparison of different extraction methods for the volatile components of grape juice. Journal of Chromatographic Science 29: 11-15.
  • [17] Priser, C., Etievant P.X., Nicalous S., Bruno., 1997. Representative champagne wine extracts for gas chromatography olfactometry analysis. Journal of Agricultural and Food Chemistry 45: 3511-3514.
  • [18] Schneider, R., Baumes, R., Bayanove, C., Razungles, A., 1998. Volatile compounds involved in the aroma of sweet fortified wines (Vins doux naturels) from Grenache Noir. Journal of Agricultural and Food Chemistry 46: 3230-3237.
  • [19] Schneider, R., Razungles, A., Augier, C., Baumes, R., 2001. Monoterpenic and norisoprenoidic glycoconjugates of Vitis vinifera L. cv. 62 Melon B. as precursors of odorants in Muscadet wines. Journal of Chromatography A 936: 145-157.
  • [20] Van den Dool H. and Kratz P. D., 1963. A generalization of the retention index system including linear temperature programmed gas-liquid partition chromatography. Journal of Chromatography 11: 463-471.
  • [21] Cabaroğlu, T., Canbaş, A., Lepoutre, J., P., Gunata, Z., 2002. Free and bound volatile composition of red wines of Vitis vinifera L. cv. Öküzgözü and Boğazkere grown in Turkey. American Journal of Enology and Viticulture 53: 64-68.
  • [22] Office International De La Vigne Et Du Vin., 1994. OIV standard for the international wine competitions, Bull. O.I.V., 67: 551-597.
  • [23] Crettenand, J., 1999. Wine-Tasting. Vigne et Vin Publications Internationales, Bordeaux- France.
  • [24] Gallart, M., Tomas, X., Suberbiola, G., LopezTamames, E., Buxaderas, S., 2004. Relationship between foam parameters obtained by the gassparging method and sensory evaluation of sparkling wines. Journal of the Science of Food and Agriculture 84: 127–133.
  • [25] Verstrepen, K.J., Derdelinckx, G., Verachtert, H., Delvaux, F.R., 2003. Yeast flocculation: what brewers should know. Applied Microbiology Biotechnology 61: 197-205.
  • [26] Mahattanatawee, K., Rouseff, R., M. V. Filomena, Naim, M., 2005. Identification and aroma impact of norisoprenoids in orange juice. Journal of Agricultural and Food Chemistry 53: 393-397.
  • [27] Guth, H., 1997. Quantification and sensory studies of character impact odorants of different white wine varieties. Journal of Agricultural and Food Chemistry 45: 3027-3032.
  • [28] Cabaroğlu, T., Canbaş, A., Lepoutre, J., P., Gunata, Z., 2002. Aroma compounds of Vitis vinifera L. cv. Emir grown in central Anatolia. Journal International Des Sciences Da La Vigne Et Du Vin 36(4): 213- 219.
  • [29] Tang, C.S., Jennings, W.G., 1967. Volatile components of apricot. Journal of Agricultural and Food Chemistry 15: 24-28.
  • [30] Issanchou, S., Schlich, P., Guichard, E., 1989. Odour profiling of the components of apricot flavour. Description by correspondence analysis. Science des Aliments 9: 351-370.
  • [31] Bayonove, C., Baumes, R., Crouzet, J., Gunata, Z., 2000. Aromas. In: Enología Fundamentos científicos tecnológicos, AMV, pp. (137-176), Mundi-Prensa, ISBN: 84-v8476-074-X, Madrid.
  • [32] Falqué, E., E. Fernández, D. Dubourdieu. 2001. Differentiation of white wines by their aromatic index. Talanta 54: 271–281.
  • [33] Ferreira, V., Ortίn, N., Escudero, A., Lόpez, R., Cacho, J., 2002. Chemical characterization of the aroma of grenache rose wines: aroma extract dilution analysis, quantitative determination, and sensory reconstitution studies. Journal of the Science of Food and Agriculture 50: 4048–4054.
  • [34] Bosch-Fusté, J., Riu-Aumatell, M., Guadayol, J.M., Caixach, J., López-Tamames, E., Buxaderas, S., 2007. Volatile profiles of sparkling wines obtained by three extraction methods and gas chromatography–mass spectrometry analysis. Food Chemistry 105: 428–435.
Akademik Gıda-Cover
  • ISSN: 1304-7582
  • Yayın Aralığı: Yılda 4 Sayı
  • Başlangıç: 2003
  • Yayıncı: Sidas Medya Limited Şirketi