Synthesis and investigation extraction properties of 4- methylacetophenone, 4-chloroacetophenone and isonitrosoacetephenone 4-aminobenzoylhydrazones

Bu çalışmada, 4-aminobenzoik asit hidrazinin 4-metilasetofenon, 4-kloroasetofenon ve isonitrosoasetofenon ile reaksiyonundan sırasıyla 4-metilasetofenon 4-aminobenzoil hidrazon $(L_1)$, 4-kloroasetofenon 4-aminobenzoil hidrazon $(L_2)$ ve isonitrosoasetofenon 4-aminobenzoil hidrazon $(L_3)$ bileşikleri sentezlenmiştir. Bu yeni bileşiklerin yapıları $^{1}H-NMR$, IR ve elementel analiz teknikleri kullanılarak aydınlatılmıştır. Ayrıca bu bileşiklerin Ni(ll), Cu(ll), Co(ll), Zn(ll), Mn(ll) ve Cd(ll) iyonları ile katı-sıvı ekstraksiyon özellikleri incelenmiştir.

4-metilasetofenon 4-aminobenzoil hidrazon, 4-kloroasetofenon 4-aminobenzoil hidrazon ve isonitrosoasetofenon 4-aminobenzoil hidrazon'un sentezi ve ekstraksiyon özelliklerinin incelenmesi

4-Methylacetophenone p-aminobenzoylhydrazone $(L_1)$,4-chloroacetophenone p-aminobenzoylhydrazone $(L_2)$ and isonitrosoacetophenone p-aminobenzoylhydrazone $(L_3)$ were prepared by reaction of 4-aminobenzoic acid hyrazide with p-methylacetophenone, p-chloroacetophenone and isonitrosoacetophenone, respectively. The structures of these new compounds were proposed on the basis of elemental analysis, $^{1}H-NMR$ and IR data. The extraction abilities of these new compounds were also examined by the solid-liquid extraction of selected transition metal [ Ni(ll), Cu(ll), Co(ll), Zn(ll), Mn(ll) and Cd(ll)] ions.

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