ZEID ABDULLAH ALOTHMAN, ERKAN YILMAZ, MOHAMED HABİLA, MUSTAFA SOYLAK

117139

Separation and preconcentration of lead(II), cobalt(II), and nickel(II) on EDTA immobilized activated carbon cloth prior to flame atomic absorption spectrometric determination in environmental samples

The synthesis and characterization of ethylenediaminetetraacetic acid immobilized activated carbon cloth was performed in the present work. It was used for preconcentration-separation of lead(II), cobalt(II), and nickel(II) at trace levels as an adsorbent. Factors including pH, concentration and volume of eluent, sample and eluent flow rates, sample volume, and effect of coexisting ions on the solid phase extraction of analytes were examined. The preconcentration factor was 50. The detection limits for Pb(II), Co(II), and Ni(II) were 4.39, 0.99 and 0.91 $\mu $g L$^{-1}$, respectively. The adsorption capacity for Pb(II), Co(II), and Ni(II) ions was found as 11.0, 11.2, and 10.2 mg g$^{-1}$, respectively. The validation of the method was performed by the analysis of certified reference materials (SPS-WW2 wastewater and BCR-146R sewage sludge amended soil (industrial origin)). The method was successfully applied for the determination of lead, cobalt, and nickel in fertilizer and water samples from Kayseri, Turkey.
Anahtar Kelimeler:

EDTA modified activated carbon cloth, metal, preconcentration, adsorption, flame atomic absorption spectrometry

Separation and preconcentration of lead(II), cobalt(II), and nickel(II) on EDTA immobilized activated carbon cloth prior to flame atomic absorption spectrometric determination in environmental samples

The synthesis and characterization of ethylenediaminetetraacetic acid immobilized activated carbon cloth was performed in the present work. It was used for preconcentration-separation of lead(II), cobalt(II), and nickel(II) at trace levels as an adsorbent. Factors including pH, concentration and volume of eluent, sample and eluent flow rates, sample volume, and effect of coexisting ions on the solid phase extraction of analytes were examined. The preconcentration factor was 50. The detection limits for Pb(II), Co(II), and Ni(II) were 4.39, 0.99 and 0.91 $\mu $g L$^{-1}$, respectively. The adsorption capacity for Pb(II), Co(II), and Ni(II) ions was found as 11.0, 11.2, and 10.2 mg g$^{-1}$, respectively. The validation of the method was performed by the analysis of certified reference materials (SPS-WW2 wastewater and BCR-146R sewage sludge amended soil (industrial origin)). The method was successfully applied for the determination of lead, cobalt, and nickel in fertilizer and water samples from Kayseri, Turkey.
Keywords:

EDTA modified activated carbon cloth, metal, preconcentration, adsorption, flame atomic absorption spectrometry,

PDF

___

  • Soylak, M.; Yilmaz, E. J. Hazard. Mater. 2010, 182, 704–709.
  • Kozlowska, J.; Kozlowski, C. A.; Koziol, J. Sep. Purif. Technol. 2007, 57, 430–434.
  • Tajik, S.; Taher, M. A. Desalination 2011, 278, 57–64.
  • Hajiaghababaei, L.; Ghasemi, B.; Badiei, A.; Goldooz, H.; Ganjali, M. R.; Ziarani, G. M. J. Environ. Sci. 2012, , 1347–1354.
  • Chamjangali, M. A.; Bagherian, G.; Mokhlesian, A.; Bahramian, B. J. Hazard. Mater. 2011, 192, 1641–1649.
  • Durukan, I.; S¸ahin, C. A.; Bektas, S. Microchem. J. 2011, 98, 215–219.
  • Li, Q. S.; Chen, Y.; Fu, H. B.; Cui, Z. H.; Shi, L.; Wang, L. L.; Liu, Z. F. J. Hazard. Mater. 2012, 227, 148–154.
  • Rashed, M. N. J. Trace Elem. Med. Bio. 2011, 25, 181–187.
  • Karak, T.; Bhagat, R. M. Food Res. Int. 2010, 43, 2234–2252.
  • Yildiz, D.; Kula, I.; Sahin, N. Eurasian J. Anal. Chem. 2013, 8, 112–122.
  • Kazi, T. G.; Baig, J. A.; Shah, A. Q.; Kandhro, G. A.; Khan, S.; Afridi, H. I.; Kolachi, N. F.; Wadhwa, S. K.; Shah F.; Mehmood Baig, A. J. AOAC Int. 2011, 94, 293–299.
  • Chandrasekaran, K.; Balarama Krishna, M. V.; Karunasagar, D. J. Anal. At. Spectrom. 2010, 25, 1348–1353.
  • Sanchez Rojas, F.; Bosch Ojeda, C.; Cano Pavon, J. M. Talanta 2007, 71, 918–922.
  • Zhang, J.; Zhang, G.; Zhao, C.; Quan, X.; Jia, Q. Microchem. J. 2012, 100, 95–99.
  • Bobrowski, A.; B´as, B.; Dominik, J.; Niewiara, E.; Szalinska, E.; Vignati, D.; Zarebski, J. Talanta 2004, 63, –1012.
  • Malik, A. K.; Kaul, K. N.; Lark, B. S. Turk. J. Chem. 2001, 25, 99–105.
  • Saracoglu, S.; Yilmaz, E.; Soylak, M. Curr. Anal. Chem. 2012, 8, 358–364.
  • Tavallali, H.; Asrari, E.; Attaran, A. M.; Tabandeh, M. Int. J. Chem Tech Res. 2010, 2, 1731–1737.
  • Sahmetlioglu, E.; Yilmaz, E.; Aktas, E.; Soylak, M. Talanta 2014, 119, 447–451.
  • Krawczyk, M.; Jeszka-Skowron, M.; Matusiewicz, H. Microchem. J. 2014, 117, 138–143.
  • Saracoglu, S.; Soylak, M.; Kacar Peker, D. S.; Elci, L.; dos Santos, W. N. L.; Lemos, V. A.; Ferreira, S. L. C. Anal. Chim. Acta 2006, 575, 133–137.
  • Cesur, H.; Batı, B. Turk. J. Chem. 2002, 26, 599–605.
  • Taher, M. A.; Mobarakeh, S. Z. M.; Mohadesi, A. R. Turk. J. Chem. 2005, 29, 17–25.
  • Yilmaz, E.; Soylak, M. Environ. Monitor. Assess. 2014, 186, 5461–5468.
  • Yu, H.; Pang, J.; Wu, M.; Wu, Q.; Huo, C. Anal. Sci. 2014, 30, 1081–1087.
  • Roushani, M.; Abbasi, S.; Khani, H.; Sahraei, R. Food Chem. 2015, 173, 266–273.
  • Peng, H.; Zhang, N.; He, M.; Chen B.; Hu, B. Talanta 2015, 131, 266–272.
  • Shah, F.; Soylak, M.; Kazi T. G.; Afridi, H. I. J. Anal. Atom. Spectrom. 2013, 28, 601–605.
  • Monneyron, P.; Faur-Brasquet, C.; Sakoda, A.; Suzuki, M.; Le Cloirec, P. Langmuir 2002, 18, 5163–5169. 30. Mahmoud, M. E.; Osman, M. M.; Amer, M. E. Anal. Chim. Acta 2000, 415, 33–40.
  • Zang, Z.; Hu, Z.; Li, Z.; He, Q.; Chang, X. J. Hazard. Mater. 2009, 172, 958–963.
  • Alothman, Z. A.; Yilmaz, E.; Habila, M.; Soylak, M. Ecotox. Environ. Safe. 2015, 112, 74–79.
  • Skoog, D.; West, A.; Holler, M. Fundamentals of Analytical Chemistry ; Holt, Rinehart and Winston, Inc.: New York, NY, USA, 1995.
  • Baytak, S.; Turker, A. R. J. Hazard. Mater. 2006, 129, 130–136.
  • Akama, Y.; Ueda, T. Cellulose Chem. Technol. 2013, 47, 479–486.
  • Ingle, J. D.; Crouch S. R. Spectrochemical Analysis; Prentice Hall: Englewood Cliffs, NJ, USA, 1988.
  • Rouquerol, J.; Avnir, D.; Fairbridge, C. W.; Everett, D. H.; Haynes, J. M.; Pernicone, N.; Ramsay, J. D. F.; Sing, K. S. W.; Unger, K. K. Pure Appl. Chem. 1994, 66, 1739–1758.
  • Soylak, M.; Erdogan, N. D. J. Hazard. Mater. 2006, 137, 1035–1041.
  • Ipeaiyeda, A. R.; Asagunla, O. J. J. Environ. Anal. Toxicol. 2014, 4, 257–261.
  • Soylak, M.; Elci, L.; Dogan, M. Anal. Lett. 1993, 26, 1997–2007.
  • Cesur, H. Turk. J. Chem. 2003, 27, 307–314.
  • Ghaedi, M.; Niknam, K.; Taheri, K.; Hosseinian, H.; Soylak, M. Food Chem. Toxicol. 2010, 48, 891–897.
  • Soylak, M.; Saracoglu, S.; Divrikli, U.; Elci, L. Environ. Monit. Assess. 2007, 127, 169–176.
  • K¨u¸c¨ukbay, F. Z.; Demir, M. Turk. J. Chem. 2003, 27, 375–382.
  • Soylak, M.; Elci, L. J. Trace Microprobe Techn. 2000, 18, 397–403.
  • Azizi, P.; Golshekan, M.; Shariati, S.; Rahchamani, J. Environ. Monit. Assess. 2015, 187, 185.
  • Allen, S. J.; McKay, G.; Porter, J. F. J. Colloid Interf. Sci. 2004, 280, 322–333.
  • Ngeontae, W.; Aeungmaitrepirom, W.; Tuntulani, T. Talanta 2007, 71, 1075–1082.
  • Tuzen, M.; Saygi, K. O.; Soylak , M. J. Hazard. Mater. 2008, 152, 632–639.
  • Narin, I.; Soylak, M.; Kayakirilmaz, K.; Elci, L.; Dogan, M. Anal. Lett. 2003, 36, 641–658.
  • Tuzen, M.; Soylak , M.; Elci, L. Anal. Chim. Acta 2005, 548, 101–108.
  • Kumar, M.; Rathore, D. P. S.; Singh, A. K. Talanta 2000, 51, 1187–1196.
  • Alothman, Z. A.; Habila, M.; Yilmaz E.; Soylak, M. Microchim. Acta 2012, 177, 397–403.
  • Duran, A.; Tuzen, M.; Soylak, M. J. Hazard. Mater. 2009, 169, 466–471.
  • Chooto, P.; Innuphat, C.; Wararattananurak, P.; Lapinee, C. ScienceAsia 2015, 41, 35–41.
  • Duran, A.; Soylak, M.; Tuncel, S. A. J. Hazard. Mater. 2008, 155, 114–120.
  • Hol, A.; Kartal, A. A.; Akdogan, A.; El¸ci, A.; Arslan, T.; El¸ci, L. Acta Chim. Slov. 2015, 62, 196–203.
  • Bulut, V. N.; Gundogdu, A.; Duran, C.; Senturk, H. B.; Soylak, M.; Elci, L.; Tufekci, M. J. Hazard. Mater. 2007, , 155–163.
Turkish Journal of Chemistry-Cover
  • ISSN: 1300-0527
  • Yayın Aralığı: 6
  • Yayıncı: TÜBİTAK
Arşiv
Sayıdaki Diğer Makaleler

Spectrophotometric determination of iron species using ionic liquid ultrasound assisted dispersive liquid--liquid microextraction

ALIREZA BAZMANDEGAN, ALI MOHAMMAD HAJI SHABANI, SAYESSTEH DADFARNIA, MAHBOUBEH SAEIDI, MASOUD ROHANI MOGHADAM

Enzyme-assisted modification of cellulose/chitin fibers with NIPAAm

ANAMARIA IRIMIA, EMILIA CSISZAR, MARIUS DOBROMIR, FLORICA DOROFTEI, CORNELIA VASILE

Green and efficient synthesis of novel bispyrazoles through a tandem Knoevenagel and Michael type reaction using nanowire zinc oxide as a powerful and recyclable catalyst

KHALIL ESKANDARI, BAHADOR KARAMI, SAEED KHODABAKHSHI, SEYYED JAFAR HOSEINI

Solid-phase total synthesis of cyclic peptide brachystemin A and its immunomodulating activity

ZAFAR ALI SHAH, ALMAS JABEEN, SAMREEN SOOMRO, M.AHMED MESAIK, M.IQBAL CHOUDHARY, FARZANA SHAHEEN

Properties and some in vitro studies of 6-phosphogluconate dehydrogenase purified from the liver of Chalcalburnus tarichi, the only fish living in Lake Van's highly alkaline water (pH 9.8)

MUHAMMET GÜLER, VEDAT TÜRKOĞLU, MEHMET RIZA KIVANÇ

New tetrazolic azo dyes linked to (thio)barbiturate and electron-rich aromatics as potential antimicrobial agents

NADER NOROOZI PESYAN, DAVOUD SOLEIMANI, NIMA HOSSEINI JAZANI

Spectrophotometric determination of iron species using ionic liquid ultrasound assisted dispersive liquid liquid microextraction

Alireza SHAMILI BAZMANDEGAN, Ali Mohammad SHABANI HAJI, Mahboubeh SAEIDI, Masoud MOGHADAM ROHANI, Shayessteh DADFARNIA

A new series of Cu(II) and Ni(II) complexes of NO bidentate 4-NO2 -benzoylhydrazones: synthesis, characterization, and biological studies

Hatice KÜÇÜK BAŞPINAR, Berna ÇELİK ÖZBEK, Emel KARA MATARACI

Separation and preconcentration of lead(II), cobalt(II), and nickel(II) on EDTA immobilized activated carbon cloth prior to flame atomic absorption spectrometric determination in environmental samples

ZEID ABDULLAH ALOTHMAN, ERKAN YILMAZ, MOHAMED HABİLA, MUSTAFA SOYLAK

A new series of Cu(II) and Ni(II) complexes of NO bidentate 4-NO$_{2}$-benzoylhydrazones: synthesis, characterization, and biological studies

HATİCE BAŞPINAR KÜÇÜK, EMEL MATARACI KARA, BERNA ÖZBEK ÇELİK