Janserin ÖZKURT, Nuran AY

414159

Lüminesans özellik gösteren hekzagonal bor nitrür üretiminin araştırılması

Lüminesans özellik gösteren hekzagonal bor nitrür (hBN) borik asit, melamin Eu+3 ve Dy+3 ‘un 1200 °C’de 1 saat ısıl işlemi ile sentezlendi. Bor nitrür UV ışık ile uyarıldığında Eu+3 ve Dy+3 iyonlarının varlıkları maviden kırmızıya emisyon göstermiştir. Farklı [Dy+3 / Eu+3] oranları kullanılarak enerji verimliliği en yüksek olan formülasyon belirlenmiştir. Yüksek enerji verimliliğine (~0,83) sahip emisyon [Dy+3 / Eu+3] = 0,5 oranında görülmüştür. Ayrıca Dy+3 iyonlarının miktarının artmasıyla ışıldama yoğunluğunun azaldığı görülmüştür. Işıldama göstermeyen disprozyum borat (DyBO3) fazının oluşumu lüminesans özelliği olumsuz etkilemiştir.
Anahtar Kelimeler:

lüminesans, hekzagonal bor nitrür, evropiyum, disprozyum, karakterizasyon

Investigation of hexagonal boron nitride production with luminescent properties

Hexagonal boron nitride (hBN) with luminescent properties was synthesized by heat treatment of boric acid, melamine, Eu+3 and Dy+3 at 1200 °C for 1 hour. When boron nitride was excited with UV light, the presence of Eu+3 and Dy+3 ions showed emission from blue to red. The formulation with the highest energy efficiency was determined by using different [Dy+3 / Eu+3] ratios. Emission with high energy efficiency (~0.83) was observed at a rate of [Dy+3 / Eu+3] = 0.5. In addition, it was observed that the luminescence intensity decreased with the increase of the amount of Dy+3 ions. The formation of the non-emitting dysprosium borate (DyBO3) phase effected the luminescence property negatively.
Keywords:

luminescence, hexagonal boron nitride, europium, dysprosium, characterization,

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Bor Dergisi-Cover
  • ISSN: 2149-9020
  • Yayın Aralığı: Yılda 4 Sayı
  • Başlangıç: 2016
  • Yayıncı: TENMAK Bor Araştırma Enstitüsü
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