Preparation of rapid (chain-stopped) alkyds by incorporation of gum rosin and investigation of coating properties

In this study, the synthesis, characterization, and properties of a short oil length chain–stopped(rapid) alkyd resin is investigated. Gum rosin modified alkyd resin (RA-GR) was prepared using soybean oil, phthalic anhydride, glycerin and gum rosin acid. An alkyd modified with benzoic acid (RA-BA) was also prepared for comparison. FTIR analyses and GPC measurements of the alkyds were used for characterization. Other properties such as the viscosity, acid value, and solid content of the final resins were determined. Separately, the synthesized resins were used in paint formulations without any changes in other parameters such as filler, airdrying agents, solvents, etc. Paints were applied to metal and glass surfaces and the effect of gum rosin was investigated by looking at touch and hard drying times, adhesion to metals and gloss changes. Compared to the benzoic acid modified resin (RA-BA), gum rosin modified resin (RA-GR) exhibited remarkable positive effects on the paint with a better adhesion to the metals, and short drying times without any loses in the glosses.

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1. Dizman C, Tasdelen MA, Yagci Y. Recent advances in the preparation of functionalized polysulfones. Polymer International 2013; 62: 991-1007. doi: 10.1002/pi.4525
2. Wegner G. Functional polymers. Acta Materialia 2000; 48 (1): 253-262. doi: 10.1016/S1359-6454(99)00298-0
3. Alam M, Akram D, Sharmin E, Zafar F, Ahmad S. Vegetable oil based eco-friendly coating materials: a review article. Arabian Journal of Chemistry 2014; 7 (4): 469-479. doi: 10.1016/j.arabjc.2013.12.023
4. Hofland A. Alkyd resins: from down and out to alive and kicking. Progress in Organic Coatings 2012; 73 (4): 274-282. doi: 10.1016/j.porgcoat.2011.01.014
5. Williams RC. Advances in alkyd resins. Applied Polymer Science: 21st Century 2000: 471-481. doi: 10.1016/b978- 008043417-9/50027-1
6. Defeyt C, Langenbacher J, Rivenc R. Polyurethane coatings used in twentieth century outdoor painted sculptures. Part I: Comparative study of various systems by means of ATR-FTIR spectroscopy. Heritage Science 2017; 5 (11): 1-11. doi: 10.1186/s40494-017-0124-7
7. Van Haveren J, Oostveen EA, Miccichè F, Noordover BAJ, Koning JE et al. Resins and additives for powder coatings and alkyd paints, based on renewable resources, Journal of Coatings Technology and Research 2007; 4 (2): 177-186. doi: 10.1007/s11998-007-9020-5
8. Jovičić MC, Radičević RZ, Budinski-Simendić JK. Curing of alkyds based on semi-drying oils with melamine resin. Journal of Thermal Analysis and Calorimetry 2008; 94 (1): 143-150. doi: 10.1007/s10973-008-9004-4
9. Dighe A, Toliwal S, Khotpal R. Chain stop alkyds from solvent fractionated aregemone and rubber seed oils. Journal of Scientific and Industrial Research 2000; 59 (10): 808-813.
10. Ogunniyi DS, Odetoye TE. Preparation and evaluation of tobacco seed oil-modified alkyd resins. Bioresource Technology 2008; 99 (5): 1300-1304. doi: 10.1016/j.biortech.2007.02.044
11. Ikhuoria EU, Okieimen FE, Obazee EO, Erhabor T. Synthesis and characterization of styrenated rubber seed oil alkyd. African Journal of Biotechnology 2011; 10 (10): 1913-1918. doi: 10.5897/AJB10.681
12. Odetoye TE, Ogunniyi DS, Olatunji GA. Studies on the preparation of Parinari polyandra benth seed oil alkyd resins. Journal of Applied Polymer Science 2013; 127 (6): 4610-4616. doi: 10.1002/app.37999
13. Ezeh IE, Umoren SA, Essien EE, Udoh AP. Studies on the utilization of Hura crepitans L. seed oil in the preparation of alkyd resins. Industrial Crops and Products 2012; 36 (1): 94-99. doi: 10.1016/j.indcrop.2011.08.013
14. Kumar S, Gupta SK. Rosin: a naturally derived excipient in drug delivery systems. Polimer ów w Medycynie 2013; 43 (1): 45-48.
15. Ma S, Li T, Liu X, Zhu J. Research progress on bio-based thermosetting resins. Polymer International 2016; 65 (2): 164-173. doi: 10.1002/pi.5027
16. Zheng Y, Yao K, Lee J, Chandler D, Wang J et al. Well-defined renewable polymers derived from gum rosin. Macromolecules 2010; 43 (14): 5922-5924. doi: 10.1021/ma101071p
17. Yadav BK, Gidwani B, Vyas A. Rosin: recent advances and potential applications in novel drug delivery system. Journal of Bioactive and Compatible Polymers 2016; 31 (2): 111-126. doi: 10.1177/0883911515601867
18. Wang J, Liu S, Yu J, Lu C, Wang C et al. Rosin-Derived Monomers and Their Progress in Polymer Application. In: Tang C, Ryu CY (editors). Sustainable Polymers from Biomass. Weinheim, Germany: Wiley-VCH Verlag GmbH & Co. KGaA, 2017, pp. 103-149. doi: 10.1002/9783527340200.ch6
19. Yao K, Wang J, Zhang W, Lee JS, Wang C et al. Degradable rosin-ester-caprolactone graft copolymers. Biomacromolecules 2011; 12 (6): 2171-2177. doi: 10.1021/bm200460u
20. El-Ghazawy RA, El-Saeed AM, Al-Shafey AI, Abdul-Raheim ARM, El-Sockary MA. Rosin based epoxy coating: synthesis, identification and characterization. European Polymer Journal 2015; 69: 403-415. doi: 10.1016/j.eurpolymj.2015.06.025
21. Yebra DM, Kiil S, Dam-Johansen K, Weinell C. Reaction rate estimation of controlled-release antifouling paint binders: rosin-based systems. Progress in Organic Coatings 2005; 53 (4): 256-275. doi: 10.1016/j.porgcoat.2005.03.008
22. Wang J, Yu J, Liu Y, Chen Y, Wang C et al. Synthesis and characterization of a novel rosin-based monomer: free-radical polymerization and epoxy curing. Green Materials 2013; 1 (2): 105-113. doi: 10.1680/gmat.12.00013
23. Liu Y, Yao K, Chen X, Wang J, Wang Z et al. Sustainable thermoplastic elastomers derived from renewable cellulose, rosin and fatty acids. Polymer Chemistry 2014; 5 (9): 3170-3181. doi: 10.1039/c3py01260c
24. Kugler S, Ossowicz P, Malarczyk-Matusiak K, Wierzbicka E. Advances in rosin-based chemicals: the latest recipes, applications and future trends. Molecules 2019; 24 (9): 1651. doi: 10.3390/molecules24091651
25. Wilbon PA, Chu FX, Tang CB. Progress in renewable polymers from natural terpenes, terpenoids, and rosin. Macromolecular Rapid Communications 2013; 34 (1): 8-37. doi: 10.1002/marc.201200513
26. Soucek MD, Khattab T, Wu J. Review of autoxidation and driers. Progress in Organic Coatings 2012; 73 (4): 435-454. doi: 10.1016/j.porgcoat.2011.08.021

ISSN: 1300-0527
Yayın Aralığı: Yılda 6 Sayı
Yayıncı: TÜBİTAK

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