Nevzat KÜLCÜ, Ulrich FLÖRKE, Hakan ARSLAN

Crystal Structure of the cis-bis[4-chloro-N-(pyrrolidine-1-carbothioyl)-benzamido] copper(II) Complex

The crystal and molecular structure of the cis-bis[4-chloro-N-(pyrrolidine-1-carbothioyl)-benzamido] copper(II) complex was determined by single-crystal X-ray diffraction. The title compound, C24H24N4O2 S2Cl2Cu, crystalizes in the triclinic space group P-1, with Z = 4 and unit cell parameters a = 8.3877(5) Å, b = 12.7904(8) Å, c = 24.160(2) Å, a = 95.923(1) °, b = 96.001(1) °, and g = 95.048(1) °. The copper atom is 4-fold coordinated by 2 S and 2 O atoms and shows a slightly distorted planar quadratic ligand arrangement.

Anahtar Kelimeler:

Thioureas, X-ray structures, Benzoylthiourea complexes, Cu(II) complex

Crystal Structure of the cis-bis[4-chloro-N-(pyrrolidine-1-carbothioyl)-benzamido] copper(II) Complex

Keywords:

Thioureas, X-ray structures, Benzoylthiourea complexes, Cu(II) complex,

PDF

___

M. Schuster, B. Kugler and K.H. K¨onig, J. Anal. Chem. 338, 717 (1990).
K. H. K¨onig, M. Schuster, G. Schneeweis and B. Steinbrech, Zeit. Anal. Chem. 319, 66 (1984).
L. Beyer, H. Hoyer, J. Liebscher and H. Hartmann, Z. Chem. 21, 81 (1981).
G. Dschuster, Nachr. Chem. Tech. Lab. 40, 68 (1992).
J. Hartung, K. Rosenbaum, L. Beyer, J. Losade and V. Fernandez, J. Ptrakt. Chem. 333, 557 (1991).
M. Guttmann, K.H. Lubert and L. Beyer, Fresenius J. Analyt. Chem. 356, 263 (1996).
X. Shen, X. Shi, B. Kang, Y. Tong, Y. Liu, L. Gu, Q. Liu and Y. Huang, Polyhedron, 18, 33 (1998).
A. Mohamadou, I. Dechamps-Olivier and J.P. Barbier, Polyhedron, 13, 3277 (1994).
I. Dechamps-Olivier, E. Guillion, A. Mohamadou and J.P. Barbier, Polyhedron, 15, 3617 (1996).
F.A. Frech and E.J. Blanz, Cancer Res. 25, 1454 (1965).
E.J. Blanz and F.A. French, Cancer Res. 28, 2419 (1965).
F.A. Frech and E.J. Blanz, J. Med. Chem. 9, 585 (1966).
F.A. Frech, E.J. Blanz, J.R.D. Amaral and D.A. French, J. Med. Chem. 13, 1117 (1970).
H. Arslan, N. Ozpozan and T. Ozpozan, Thermochimica Acta, 329, 57 (1999).
N. Ozpozan, T. Ozpozan, H. Arslan, F. Karipcin and N. K¨ulc¨u, Thermochimica Acta, 336, 97 (1999).
N. Ozpozan, H. Arslan, T. Ozpozan, N. Ozdes and N. K¨ulc¨u, Thermochimica Acta, 343, 127 (2000).
N. Ozpozan, H. Arslan, T. Ozpozan, M. Merdivan and N. K¨ulc¨u, J. Ther. Anal., 61, 955 (2000).
H. Arslan, U. Fl¨orke and N. K¨ulc¨u, Acta Crystallographica, E59, o641 (2003).
H. Arslan, U. Fl¨orke and N. K¨ulc¨u, Transition Metal Chemistry, 28(7), 816 (2003).
H. Arslan, U. Fl¨orke and N. K¨ulc¨u, Journal of Chemical Crystallography, 33, 919 (2003).
H. Arslan, D. Vanderveer, F. Emen and N. K¨ulc¨u, Z. Kristallogr. NCS, 218, 479 (2003).
H. Arslan, U. Fl¨orke and N. K¨ulc¨u, Acta Chim. Slov., in press, (2004).
G. Avsar, H. Arslan, H-J, Haupt and N. K¨ulc¨u, Turk. J. Chem., 27, 281 (2003).
G. Binzet, U. Fl¨orke, N. K¨ulc¨u and H. Arslan, Acta Crystallographica, E59, m705-m706 (2003).
F.M. Emen, U. Fl¨orke, N. K¨ulc¨u and H. Arslan, Acta Crystallographica, E59, o1159 (2003).
E. Kayhan, F.M. Emen, U. Fl¨orke, N. K¨ulc¨u and H. Arslan, Acta Crystallographica, E59, o1237 (2003).
G. Binzet, U. Fl¨orke, N. K¨ulc¨u and H. Arslan, Z. Kristallogr. NCS, 219, in press, (2004).
F.M. Emen, U. Fl¨orke, N. K¨ulc¨u and H. Arslan, Acta Crystallographica, E59, m582 (2003).
Bruker (1998). SHELXTL. Version 5.1. Bruker AXS Inc., Madison, Wisconsin, USA.
V.R. Richter, L. Beyer and J. Kaiser, Z. Anorg. Allg. Chem., 461, 67 (1980).