The Synthesis and Applications of Cr-Doped GLYMO and GLYMO/DAMO Surface Coating Systems for Absorbing UV-light by Sol-Gel Process

A new glass coating system, containing g- glycidoxypropyltrimethoxysilane/Cr3+ (system I:GLYMO/ Cr3+) and g-glycidoxypropyltrimethoxysilane/N-aminoethyl-3- aminopropyltrimethoxysilane/Cr3+ (system II:GLYMO/DAMO/Cr3+), was synthesized by the sol-gel technique for UV light absorption applications. UV-visible spectroscopy (UV-VIS) was utilized to investigate the optical properties of coating materials. Especially system II showed very low transmission in the UV wavelength regions (300--400 nm) after thermal treatment of the coated surface. The UV transmission property of surfaces did not change at 80, 100, 450 or 500 °C, but a T value as low as 0.07% was obtained between 150 and 450 °C.

The Synthesis and Applications of Cr-Doped GLYMO and GLYMO/DAMO Surface Coating Systems for Absorbing UV-light by Sol-Gel Process

A new glass coating system, containing g- glycidoxypropyltrimethoxysilane/Cr3+ (system I:GLYMO/ Cr3+) and g-glycidoxypropyltrimethoxysilane/N-aminoethyl-3- aminopropyltrimethoxysilane/Cr3+ (system II:GLYMO/DAMO/Cr3+), was synthesized by the sol-gel technique for UV light absorption applications. UV-visible spectroscopy (UV-VIS) was utilized to investigate the optical properties of coating materials. Especially system II showed very low transmission in the UV wavelength regions (300--400 nm) after thermal treatment of the coated surface. The UV transmission property of surfaces did not change at 80, 100, 450 or 500 °C, but a T value as low as 0.07% was obtained between 150 and 450 °C.

___

  • T. Masui, K. Fukuhara, N. Imanaka, T. Sakata, H. Mori and G. Adachi, Chem. Lett. 31, 474 (2002).
  • H. Scroeder, in G. Hass and R.E. Thun (eds.), Physics of Thin Films, Academic Press London, 5, (1985), p.137.
  • A. Makishima, H. Kubo, K. Wada, Y. Kitami and T. Shimohira, J. Am. Ceram. Soc. 69, C127 (1986).
  • D. Kundu and R. Mukherjee, J. Mater. Sci. Lett. 22, 2003, 1647.
  • D.R. Ulrich, J. Non-Cryst. Solids. 100, 174 (1988).
  • Y. Sorek, R. Reisfeld and A.M. Weiss, Chem. Phys. Lett. 244, 371 (1995).
  • R. Reisfeld, Optical Materials, 16, 1 (2001).
  • J.M. Y´a˜nez-Lim´on, J.F. P´erez-Roblez, J. Gonz´ales-Hern´andez, R. Zamorano-Ulloa and D. Ramirez-Rozales, Thin Solid Films, 373, 184 (2000).
  • W. Jia, Y. Wang, I.R. Figuersa and H. Liu, Colloids and Surfaces A, 179, 185 (2001).
  • I.B. Artsbysheva, S.G. Lunter, N.T. Timifeev and Yu.K. Fedorov, J. Glass Phys. Chem. 16, 344 (1990).
  • M.D. Shin and A.A. Tesar, J. Lumin. 51, 189 (1992).
  • S.R. Ramanan and D. Ganguli, J. Non-Cryst. Solids. 212, 299 (1997).
  • M. Herren, H. Nishiuchi and M. Morita, J. Chem. Phys. 101, 4461 (1994).
  • F. Orgaz and H. Rawson, J. Non-Cryst. Solids. 82, 378 (1986).
  • L. Chu, M.W. Daniels and L.F. Francis, Chem. Mater. 9, 2577 (1997).
  • H. Schmidt, J. Non-Cryst. Solids. 2, 189 (1994).
  • W. Que and X. Hu, J. Sol-Gel Sci. Technol. 28, 319 (2003).
Turkish Journal of Chemistry-Cover
  • ISSN: 1300-0527
  • Yayın Aralığı: 6
  • Yayıncı: TÜBİTAK