Synthesis and Complex Formation of Some Novel vic-Dioxime Derivatives of Hydrazones
Three novel vic-dioxime compounds and their transition metal complexes were synthesized for the first time. These ligands are anti-glyoximehydrazine (GH2), anti-2-pyridinealdehydeglyoxime hydrazone (PyGH2) and anti-2-furancarboxaldehydeglyoxime hydrazone (FGH2). The synthesized anti-glyoximehydrazine was reacted with 2-pyridinealdehyde or 2-furancarboxaldehyde to obtain the PyGH2 and FGH2 ligands. Mononuclear complexes of these ligands with a metal-ligand ratio of 1:2 were prepared with Ni(II), Co(II) and Cu(II) ions. The structures of the ligands and complexes were determined by 1H n.m.r, i.r spectroscopy and elemental analytical techniques.
Synthesis and Complex Formation of Some Novel vic-Dioxime Derivatives of Hydrazones
Three novel vic-dioxime compounds and their transition metal complexes were synthesized for the first time. These ligands are anti-glyoximehydrazine (GH2), anti-2-pyridinealdehydeglyoxime hydrazone (PyGH2) and anti-2-furancarboxaldehydeglyoxime hydrazone (FGH2). The synthesized anti-glyoximehydrazine was reacted with 2-pyridinealdehyde or 2-furancarboxaldehyde to obtain the PyGH2 and FGH2 ligands. Mononuclear complexes of these ligands with a metal-ligand ratio of 1:2 were prepared with Ni(II), Co(II) and Cu(II) ions. The structures of the ligands and complexes were determined by 1H n.m.r, i.r spectroscopy and elemental analytical techniques.
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