Investigation of melamine presence in canned tuna fish by capillary zone electrophoresis method

Melamin gıda endüstrisinde yaygın olarak kullanılan bir kimyasal olup, böbrek hasarına neden olabilmektedir. Buçalışmada Ankarada satışa sunulan dört farklı markaya (A, B, C, D) ait 80 konserve ton balığı örneğinde melamin vepH değerlerinin saptanması amaçlanmıştır. Konserve ton balığı örneklerinde melaminin kantitatif olarak saptanmasıdiyod array dedektörlü kapiler zon elektroforez (CZE-DAD) ile yapılmıştır. Melaminin gözlenebilme ve tayin sınırları sırasıyla 0.21 mg kg -1 ve 0.68 mg kg-1 olarak bulunmuştur. Konserve ton balığı örneklerinde melamin saptanması içinönerilen yöntem, yağda muhafaza edilen ton balıkları için % 104.7 ve light ton balıkları için % 107.6 ortalama gerikazanımlarla başarılı bir şekilde uygulanmıştır. Çalışma süresince analiz edilen örneklerin tamamında melamin düzeyitayin sınırının (0.68 mg kg-1 ) altında bulunmuştur. A, B, C ve D markalarına ait örneklerin ortalama pH değerleri (±SH)sırasıyla 5.89 ± 0.02, 5.86 ± 0.01, 5.83 ± 0.02 ve 5.82 ± 0.02 olarak tespit edilmiştir. Sonuç olarak, çalışma süresincetemin edilen konserve ton balıklarındaki melamin varlığının tüketiciler açısından sağlık riski oluşturmadığı gözlenmiştir.

Konserve Ton balıklarında melamin varlığının kapiler zon elektroforez yöntemi ile araştırılması

Melamine is widely used as a chemical in food industry and may lead to kidney damage. The aim of this study wasto determine melamine and pH value of 80 canned tuna fsh samples of four different brands (A, B, C, D) sold inAnkara, Turkey. Quantitative determination of melamine in canned tuna fsh samples was carried out by capillary zoneelectrophoresis with diode array detector (CZE-DAD). The limits of detection and quantitation for melamine were foundto be 0.21 mg kg -1 and 0.68 mg kg-1, respectively. The proposed method was successfully applied for the analysis ofmelamine in canned tuna fsh samples by mean recovery with 104.7% in oily and 107.6% for light samples. Melaminelevels were found as

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