Bu çalışmada, saf nikel, Ni-B alaşım ve Ni-B/hBN kompozit kaplamalar elektrodepolama yoluyla üretilmiştir. Bu kaplamaları elde etmek için banyoya eklenen bileşenlerin miktarları sabit tutulmuş ve her birinin ayrı ayrı kaplama üzerine etkileri araştırılmıştır. Üretilen kaplamaların kristal yapıları XRD ile, yüzey morfolojileri ve kimyasal içerik analizleri SEM ve EDS ile, elektrokimyasal davranışları ise dönüşümlü voltametri (CV) ile incelenmiştir. Ayrıca kaplamaların korozyon dayanımları % 3.5 NaCl içeren çözelti içerisinde açık devre potansiyeli ve Tafel ekstrapolasyon metotlarıyla belirlenmiştir. Elde edilen sonuçlara göre ince taneli, düzgün yüzeyli ve kompakt kaplamalar üretilmiştir. Banyoya eklenen bileşenler kristal yapıyı, korozyon dayanımını ve diğer özellikleri ciddi derecede etkilemektedir.
___
H. Ogihara, M. Safuan, T. Saji, Effect of electrodeposition conditions on hardness of Ni–B/diamond composite films, Surface&Coatings Technology, 212: 180- 184, 2012.
N. Kanani, Electroplating: Basic Principles, Processes and Practice, Elsevier Advanced Technology, Oxford, U.K., 2004.
K.E. Hou, Y.C. Chen, Preparation and wear resistance of pulse electrodeposited Ni– W/Al2O3 composite coatings, Applied Surface Science, 257: 6340-6346, 2011.
L. Benea, Electrodeposition and tribocorrosion behaviour of ZrO2–Ni composite coatings, J. Appl. Electrochem., 39:1671-1681, 2009.
C.C. Koch, Structural nanocrystalline materials: an overwiew, j. Mater. Sci., 42: 1403, 2007.
R.A. Shakoor, R. Kahraman, U.S. Waware, Y. Wang, W. Gao, Synthesis and Properties of Electrodeposited Ni-B-Zn Ternary Alloy Coatings, Int. J. Electrochem. Sci., 9:5520, 2014.
H. Ogihara, K. Udagawa, T. Saji, Effect of boron content and crystalline structure on hardness in electrodeposited Ni–B alloy films, Surface&Coatings Technology, 206, 2933-2940, 2011.
Y. N. Bekish, S. K. Poznyak, L. S. Tsybulskaya, T. V. Gaevskaya, Electrodeposited Ni–B alloy coatings; Structure, corrosion resistance and mechanical properties, Electrochimica Acta, 55, 2223-2231, 2009.
K.H. Lee, D. Chang, S.C. Kwon, Properties of electrodeposited nanocrystalline Ni–B alloy films, Electrochimica Acta, 50, 4538- 4543, 2005.
B. Ertuğ, Powder Preparation, Properties and Industrial Applications of Hexagonal Boron Nitride, Intech, chapter 2, 33-55, 2013.
S. Sangeetha, G. P. Kalaignan, Tribological and electrochemical corrosion behavior of Ni–W/BN (hexagonal) nano-composite coatings, Ceramics International, Volume 41, Issue 9, Part A, 10415-10424, 2015.
M.K. Tripathi, D.K. Singh, V.B. Singh, Electrodeposition of Ni-Fe/BN nanocomposite coatings from a non-aqueous bath and their characterization, Int. J. of Electrochemical Science, 8, 3454-3471, 2013.
Z. Shahri, S.R. Allahkaram, Effect of particles concentration and current density on Co-hBN nanocomposite coatings properties, Iranian Journal of Materials Science&Engineering, vol 9, number 4, 2012.
Z. Shahri, S.R. Allahkaram, A. Zarebidaki, Electrodeposition and characterization of Co–BN(h) nanocomposite coatings, Applied Surface Science, 279, 174-181, 2013.
Z. Shahri, S.R. Allahkaram, Effect of plating parameters on microstructure and tribological properties of Co−BN(hexagonal) nano composite coatings, Trans. Of Nonferrous Metals Society of China, 23, 2929-2938, 2013.
E. Pompei, L. Magagnin, N. Lecis, P.L. Cavallotti, Electrodeposition of nikel-BN composite coatings, Electrochimica Acta, 54, 2571-2574, 2008.
M. Pushpavanam, S.R. Natarajan, Nickel- Boron Nitride Electrocomposites, Metal Finishing, 1995.
S. Paydar, A. Jafari, M.E. Bahrololoom, V. Mozafari, Enhancing Ni electroplated matrix through mixed boron nitride-carbide reinforcement, Vacuum, 92, 52-57, 2012.
S. Paydar, A. Jafari, M.E. Bahrololoom, V. Mozafari, Influence of BN and B4C particulates on wear and corrosion resistance of electroplated nickel matrix composite coatings, Tribology, vol 9, no 2, 105-110, 2015.
R.A. Shakoor, R. Kahraman, U.S. Waware, Wang Y., Gao W., Properties of electrodeposited Ni-B-Al2O3 composite coatings, Materials and Design, 64: 127- 135, 2014.
H. Ogihara, H. Wang, T. Saji, Electrodeposition of Ni–B/SiC composite films with high hardness and wear resistance, Applied Surface Science, 296: 108-113, 2014.
Y. Wang, S. Wang, X. Shu, W. Gao, W. Lu, B. Yan, Preparation and property of solenhanced Ni–B–TiO2 nano-composite coatings, J. of Alloys and Compounds, 617: 472-478, 2014.
R.A. Shakoor, R. Kahraman, U.S. Waware, Y. Wang, W. Gao, Properties of Electrodeposited Ni-B-ZrO2 Composite Coatings, Int. J. of Electrochemical Science, 10: 2110-2119, 2015.
K. Krishnaveni, T.S.N.S. Narayanan, S.K. Seshadri, Electrodeposited Ni–B–Si3N4 composite coating: Preparation and evaluation of its characteristic properties, J. of Alloys and Compounds, 466: 412-420, 2008.
R.A. Shakoor, R. Kahraman, U. S. Waware, Y. Wang, W. Gao, Synthesis and properties of electrodeposited Ni–B–CeO2 composite coatings. Materials and Design, 59:421– 429, 2014.
A. L. Patterson, The Scherrer formula for Xray particle size determination, Phys. Rey. 56 978-982, 1939.
G. Gyawali, S.W. Lee, Effect of SiC and hBN codeposition on microstructural and tribological properties of Ni-SiC-hBN composite coatings, Ceramic Processing Research, Vol 16, No: 2, 213-217, 2015.
M. Motoyama, Y. Fukunaka, T. Sakka, Y.H. Ogota, Effect of Surface pH on Electrodeposited Ni Films, Journal of the Electrochemical Society, 153, C502, 2006.