Amberlyst A21 İle Everzol Black Boyasının Adsorpsiyonu: İzoterm ve Kinetik Çalışmalar

Bu çalışmada Everzol Black boyasının sulu çözelti ortamından giderimi Amberlyst A21 ile incelenmiştir. pH, temas süresi ve başlangıç boya derişimi gibi değişik parametrelerin boya adsorpsiyonu üzerine etkileri çalışılmıştır. Langmuir, Freundlich ve Temkin izoterm modelleri denge adsorpsiyon verilerinin analizi için kullanılmıştır. Ayrıca adsorpsiyon kinetik verileri yalancı birinci ve ikinci dereceden kinetik modeller kullanılarak incelenmiştir. Çalışma sonuçlarına göre Amberlyst A21 ile Everzol Black giderimi Langmuir izoterm modeli ve yalancı birinci dereceden adsorpsiyon kinetiği ile tanımlanabilir.

Adsorption of Everzol Black by Using Amberlyst A21: Isotherm and Kinetic Studies

In this paper, removal of Everzol Black dye from aqueous solutions was investigated with Amberlyst A21. The effects of different parameters such as pH, contact time and initial dye concentration on dye adsorption were studied. Langmuir, Freundlich and Temkin isotherm models were used to analyze the equilibrium data. Also, adsorption kinetic data were tested using pseudo-first order and pseudo-second order models. According to the results of the study, removal of Everzol Black dye with Amberlyst A21 can be described with Langmuir isotherm model and pseudo-first order kinetic model.

___

  • H. Altaher, “Preliminary Study of the Effect of Using Biosorbents on the Pollution of the Treated Water,” Global Nest Journal, vol. 16, no. 4, pp. 707-716, 2014.
  • S. Chakrabarti and B. K. Dutta, “Photocatalytic degradation of model textile dyes in wastewater using ZnO as semiconductor catalyst,” Journal of Hazardous Materials B, vol. 112, no. 3, pp. 269-278, 2004.
  • L. L. He, X. P. Liu, Y. X. Wang, Z. X. Wang, Y. J. Yang, Y. P. Gao, B. Liu and X. Wang, “Sonochemical degradation of methyl orange in the presence of Bi2WO6: Effect of operating parameters and the generated reactive oxygen species,” Ultrasonic Sonochemistry, vol. 33, pp. 90-98, 2016.
  • C. R. Holkar, A. J. Jadhav, D. V. Pinhari, N. M. Mahamuni and A. B. Pandit, “A critical review on textile wastewater treatments: Possible approaches,” Journal of Environmental Management, vol. 182, pp. 351-366, 2016.
  • A. Paz, J. Carbollo, M. J. Perez and J. M. Dominguez, “Biological treatment of model dyes and textile wastewaters,” Chemosphere, vol. 181, pp. 168-177, 2017.
  • Y. Wei, Q. Ji, L. Chen, J. Hao, C. Yao and X. Dong, “Preparation of an inorganic coagulant-polysilicate-magnesium for dyeing wastewater treatment: Effect of acid medium on the characterization and coagulant performance,” Journal of Taiwan Institute of Chemical Engineers, vol. 72, pp. 142-148, 2017.
  • R. Y. Lin, B. S. Chen, G. L. Chen, J. Y. Wu, H. C. Chiu and S. Y. Suen, “Preparation of porous PMMA/Na+-montmorillonite cationexchange membranes for cationic dye adsorption,” Journal of Membrane Science, vol. 326, no. 1, pp. 117-129, 2009.
  • J. H. Huang, C. F. Zhou, G. M. Zeng, X. Li, H. J. Huang, J. Niu, F. Li, L. J. Shi and S. B. He, “Studies on the solubilization of aqueous methylene blue in surfactant using MEUF,” Seperation and Purification Technology, vol. 98, pp. 497-502, 2012.
  • I. Elaissaoui, H. Akrout and L. Bousselmi, “Electrochemical degradation of dye on lead dioxide electrodeposited on stainless steel: effect of cyclic voltammetry parameters,” Desalination and Water Treatment, vol. 57, no. 46, pp. 22120-22132, 2016.
  • N. Nikooe and E. Saljoughi, “Preparation and characterization of novel PVDF nanofiltration membranes with hydrophilic property for filtration of dye aqueous solution,” Applied Surface Science, vol. 413, pp. 41-49, 2017.
  • M. Sharma, S. Hazra and S. Basu, “Kinetic and isotherm studies on adsorption of toxic pollutants using porous ZnO@SiO2 monolith,” Journal of Colloid and Interface Science, vol. 504, pp. 669-679, 2017.
  • W. Konicki, M. Aleksandrzak and E. Mijowska, “Equilibrium, kinetic and thermodynamic studies on adsorption of cationic dyes from aqueous solutions using graphene oxide,” Chemical Engineering Research and Design, vol. 123, pp. 35-49, 2017.
  • U. D. Gül and H. Silah, “Comparision of color removal from reactive dye contaminated water by systems containing fungal biosorbent, active carbon and their mixture,” Water Science & Technology, vol. 70, no. 7, pp. 1168-1174, 2014.
  • J. Yang, M. Zhang, Y. Zhang, L. Ding, J. Zheng and J. Xu, “Facile synthesis of magnetic magnesium silicate hollow nanotubes with high capacity for removal of methylene blue,” Journal of Alloys and Compounds, vol. 721, pp. 772-778, 2017.
  • M. Hasan, A. L. Ahmad and B. H. Hameed, “Adsorption of reactive dye onto crosslinked chitosan/oil palm ash composite beads,” Chemical Engineering Journal, vol. 136, pp. 164-172, 2008.
  • M. D. Victor-Ortega, J. M. Ochando-Pulido and A. Martinez-Ferez, “Phenols removal from industrial effluents through novel polymeric resins: Kinetics and equilibrium studies,” Separation and Purification Technology, vol. 160, pp. 136-144, 2016.
  • S. K. Sarı and D. Özmen, “Desing of optimum response surface experiments for the adsorption of acetic, butyric, and oxalic acids on Amberlyst A21,” Journal of Dispersion Science and Technology, 2017. doi.org/10.1080/01932691.2017.1316208.
  • K. F. Hassan, “Rapid separation of radiogallium from Zn and Cu targets using anion exchange technique,” Journal of Radioanalytical and Nuclear Chemistry, vol. 289, no. 3, pp. 801-804, 2011.
  • M. Wawrzkiewicz and Z. Hubicki, “Remazol Black B removal from aqueous solutions and wastewater using weakly basic anion exchange resins,” Central European Journal of Chemistry, vol. 9, no. 5, pp. 867- 876, 2011.
  • B. Kumar, K. Smita, E. Sanchez, C. Stael and L. Cumbal, “Andean Sachainchi (Plukenetiavolubilis L.) shell biomass as new biosorbents for Pb2+ and Cu2+ ions,” Ecological Engineering, vol. 93, pp. 152- 158, 2016.
  • T. A. H. Nguyen, H. H. Ngo, W. S. Guo, J. Zhang, S. Liang, Q. Y. Yue, Q. Li and T. V. Nguyen, “Applicability of agricultural waste and by-products for adsorptive removal of heavy metals from waste water,” Bioresource Technology, vol. 148, pp. 574- 585, 2013.
  • S. Wang, B. Yang and Y. Liu, “Synthesis of a hierarchical SnS2 nanostructure for efficient adsorption of Rhodamine B dye,” Journal of Colloid and Interface Science, vol. 507, pp. 225-233, 2017.
  • M. Bagchi and L. Ray, “Adsorption behavior of reactive blue 4, a triazine dye on drycells of Rhizopus oryzane in a batch system,” Chemical Speciation & Bioavailability, vol. 27, no. 3, pp. 112-120, 2015.
  • M. V. Subbaiah and D. S. Kim, “Adsorption of methyl orange from aqueous solution by aminated pumpkin seed powder: Kinetics, isotherms, and thermodynamic studies,” Ecotoxicology and Environmental Safety, vol. 128, pp. 109-117, 2016.
  • H. M. F. Freundlich, “Over the adsorption in solution,” The Journal of Physical Chemistry, vol. 57, pp. 385-471, 1906. [26] I. Langmuir, “The adsorption of gases on plane surfaces of glass, mica and platinum,” Journal of American Chemical Society, vol. 40, no. 9, pp. 1361–1403, 1918.
  • Z. Zhang, D. Shi, H. Ding, H. Zheng and H. Chen, “Biosorption characteristics of 1,8- dihydroxy anthraquinone onto Aspergillus oryzae CGMCC5992 biomass,” International Journal of Environmental Science and Technology, vol. 12, no. 10, pp. 3351-3362, 2015.
  • R. Jain, V. K. Gupta and S. Sikarwar, “Adsorption and desorption studies on hazardous dye Naphthol Yellow S,” Journal of Hazardous Materials, vol. 182, no. 1-3, pp. 749-756, 2010.
  • D. Guimarães and V. A. Leão, “Batch and fixed-bed assessment of sulphate removal by the weak base ion exchange resin Amberlyst A21,” Journal of Hazardous Materials, vol. 280, pp. 209-215, 2014.
  • M. Greluk and Z. Hubicki, “Evaluation of polystyrene anion exchange resin for removal of reactive dyes from aqueous solutions,” Chemical Engineering Research and Design, vol. 91, no.7, pp. 1343-1351, 2013.
  • H. Yu, T. Wang, W. Dai, X. Li, X. Hu and N. Ma, “Single and Bicomponent Anionic Dyes Adsorption Equilibrium Studies on Magnolia-Leaf-Based Porous Carbons,” Royal Society of Chemistry, vol. 79, no. 5, pp. 63970-63977, 2015.