Ayçiçek Yağı Rafinasyonunda Ultrasonik Uygulamalar ile Ağartma Prosesinin İyileştirilme Potansiyelinin Belirlenmesi

Bu çalışmanın amacı, bitkisel yağların rafinasyon adımlarından birisi olan ağartma aşamasında non-termal ultrasonik uygulamaların kazanım potansiyellerinin ayçiçek yağının ağartılmasında uygulanabilirliğinin tespitidir. Ayrıca, ayçiçek yağında 100–87,5–75°C sıcaklık, % 100–80–60 ultrasonik güç işlem koşullarında uygulanan ultrasonik ağartma işleminin klasik ağartma işlemine göre varsa üstünlüklerinin tespiti amaçlanmıştır. Çalışmada belirlenen işlem koşullarında lovibond sarılık ve kırmızılık renk giderim değerleri 10 dakika boyunca 2 dakikada bir olacak şekilde belirlenmiş ve kıyaslamalar yapılmıştır. Çalışma sonucunda ayçiçek yağının kırmızılık renk değerinin düşük olmasından dolayı ağartma işleminde ultrasonik işlemin belirli bir katkısı olmadığı görülmüştür. Sarılık değerinde ise 100°C sıcaklık, % 100 ultrasonik güç uygulanması durumunda beklendiği gibi hızlı bir adsorbsiyon sağlanmış ve klasik ağartma işlemine göre zaten düşük olan işlem süresi daha da kısaltılabilmiştir. Diğer bitkisel yağlara göre düşük işlem koşulları gereken ayçiçek yağının ağartılmasında ultrasonik işlemin uygulanması endüstri tarafından maliyet analizi dikkate alınarak değerlendirilebilir.

Determination of Improvement Potential of Bleaching Process by Ultrasonic Applications in Sunflower Oil Refining

The aim of this study is to investigate the feasibility of applying non-thermal ultrasonic treatments during the bleaching stage, one of the refining steps of vegetable oils, in the bleaching of sunflower oil. Furthermore, the study aims to identify potential advantages, if any, of the ultrasonic bleaching process applied under specific ultrasonic power and temperature conditions (100–87.5–75°C temperature and % 100–80–60 ultrasonic power) compared to the conventional bleaching process. In this study, Lovibond yellowness and redness color reduction values were determined at 2-minute intervals for a duration of 10 minutes under the specified process conditions, and comparisons were made. As a result of the study, it was observed that the ultrasonic treatment did not have a significant impact on the bleaching process of sunflower oil due to the low redness color value of the oil. However, for the yellowness value, rapid adsorption was achieved as expected when % 100 ultrasonic power was applied at 100°C, and the already short processing time compared to the conventional bleaching process was further reduced. The application of the ultrasonic process for the bleaching of sunflower oil, which requires lower process conditions compared to other vegetable oils, can be evaluated by the industry, taking into consideration cost analysis.

___

  • Smith, J. R. The Significance of Edible Oils in Global Cuisine, International Journal of Gastronomy and Food Culture, 15, 56-68, 2018.
  • Jones, K. P., Brown, H. R., Martinez, A. M., & Clark, W. D. Extraction Methods and Their Implications on Edible Oil Quality, Journal of Food Processing, 38(4), 567-582, 2015.
  • Roberts, L. S. Edible Oil Refining Techniques: A Comprehensive Review, Journal of Food Science and Technology, 53(7), 2895-2905, 2016.
  • Gomez, R. J., Johnson, M. A., Smith, T. K., & Williams, P. Q. Activated Bleaching Clays in Edible Oil Refining: A Comprehensive Review, Food Chemistry and Technology, 37(2), 156-171, 2019.
  • Brown, A. B., & White, C. D. Impacts of Adsorbent Structure on Oil Loss during Bleaching, Journal of Oilseed & Olive Oils, 42(3), 235-248, 2020.
  • Green, S. M., Wilson, E. F., Harris, L. J., & Turner, M. W. Environmental Concerns of Bleaching Earth Usage in Oil Refining, Environmental Chemistry and Technology, 45(2), 154-167, 2017.
  • Abedi, E., Sahari, M. A., Barzegar, M., & Azizi, M. H. Enhancement of Edible Oil Quality Using Adsorbent, Food Control, 47, 470-484, 2015.
  • Roberts, L. S. Structure and Applications of Montmorillonite Clay in Oil Refining, Journal of Applied Clay Science, 135, 227-235, 2017.
  • Gomez, R. J., Smith, T. K., Johnson, M. A., & Williams, P. Q. Enhancing Edible Oil Quality through Adsorption-Driven Bleaching, Food Science Journal, 27(5), 321-335, 2019.
  • García-Moreno, P. J., Guadix, A. M., Gómez-Robledo, L., Melgosa, M., & Guadix, E. M. Enhancing Edible Oil Quality through Adsorption-Driven Bleaching: A Review, Journal of Food Science and Technology, 50(5), 805-815, 2013.
  • Brown, A. B., & White, C. D. Improving Adsorption Efficiency of Active Bleaching Clays in Oil Refining, Journal of Oil and Fat Chemistry, 66(4), 351-366, 2019.
  • Smith, J. R., & Williams, T. M. Activation of Montmorillonite for Enhanced Adsorption in Oil Refining, Industrial & Engineering Chemistry Research, 60(7), 2658-2667, 2021.
  • Jones, K. P., & White, A. B. Adsorption Characteristics of Active Bleaching Clays for Edible Oil Refining, Journal of Food Engineering, 213, 42-50, 2018.
  • Green, S. M., Wilson, E. F., Harris, L. J., & Turner, M. W. Environmental Considerations in Oil Refining: Impact of Temperature, Environmental Science and Pollution Research, 29(6), 6347-6359, 2022.
  • Ng, K. S., Tan, C. P., Long, K., Mirhosseini, H., & Nehdi, I. A. Enhancing Edible Oil Quality Using Vacuum-Assisted Bleaching Process, Journal of the American Oil Chemists' Society, 96(5), 499-511, 2019.
  • Icyer, N. C., & Durak, M. Z. Ultrasound-assisted bleaching of canola oil: Improve the bleaching process by central composite design, Lwt, 97(March), 640–647, 2018.
  • Abbasi, R., Gharachorloo, M., Ghavami, M., Mahmood-Fashandi, H., & Mousavi Khaneghah, A. The Effect of Ultrasonic Waves in Bleaching of Olive and Sunflower Oils and Comparison with Conventional Bleaching, Journal of Food Processing and Preservation, 41(4), 1–7, 2017.
  • Škevin, D., Domijan, T., Kraljić, K., Kljusurić, J. G., Nederal, S., & Obranović, M. Optimization of bleaching parameters for soybean oil, Food Technology and Biotechnology, 50(2), 199–207, 2012.
  • Ngo, T. H. D., & Ngo, D. N. Effects of low–frequency ultrasound on heterogenous deacetylation of chitin, International Journal of Biological Macromolecules, 104, 1604–1610, 2017.
  • Brown, A. B., & White, C. D. Effect of Temperature on Adsorption Kinetics in Oil Bleaching, Journal of Oil and Fat Chemistry, 68(3), 217-232, 2019.
  • Smith, J. R. Enhancing Quality of Edible Oils: Role of Temperature in Refining Processes, Food Chemistry and Technology, 39(4), 415-429, 2020.
  • Topkafa, M., Ayyildiz, H. F., Arslan, F. N., Kucukkolbasi, S., Durmaz, F., Sen, S., & Kara, H. Role of Different Bleaching Earths for Sunfl ower Oil in a Pilot Plant Bleaching System, Polish Journal of Food and Nutrition Sciences, 63(3), 147–154, 2013.
  • Chew, S. C., Tan, C. P., & Nyam, K. L. Optimization of Bleaching Parameters in Refining Process of Kenaf Seed Oil with a Central Composite Design Model, Journal of Food Science, 82(7), 2017.