Mermer Tozu ve Atık Lastikle Takviye Edilmiş Oltu/Erzurum (Türkiye) Bölgesine Ait Kil Türleri ve Siltli Kumun Spektroskopik Analizi
Bu çalışmada, Oligosen yaşlı alt sedimanter birim, volkanik birim ve üst sedimanter birimden oluşan Oltu/Erzurum bölgesine ait takviye edilmemiş ve takviye edilmiş (atık lastik ve mermer tozunun farklı miktarlarda eklenmesi ile) kil türleri ve siltli kum örneklerinin kapsamlı bir analizinin verilmesi amaçlanmıştır. Bu örneklerin manyetik özelliklerini incelemek için elektron paramanyetik rezonans kullanılmıştır, kristal doğasını görmek için x-ışını kırınımı performe edilmiştir, yüzey morfolojisini gözlemlemek için taramalı elektron mikroskobu kullanılmış ve elementel kompozisyonu öğrenmek için enerji dağılımlı spektroskopi tercih edilmiştir.
A Spectroscopic Analysis of Clay Types and Silty Sand from Oltu/Erzurum (Turkey) Region Reinforcing with Marble Dust and Waste Tire
In the present study, it has been aimed to give a comprehensive analysis of unreinforced and reinforced materials (with waste tire and marble dust additions in different amounts); clays (green and red) and silty sand, obtained from Oltu/Erzurum region which consists of Oligocene lower upper sedimentary units, volcanic rocks and upper sedimentary units. In order to investigate the magnetic properties of these samples, electron paramagnetic resonance has been used; to see the crystalline natüre x-ray diffraction has been performed; to observe the surface morphology scanning electron microscope has been used and to learn the elemental compositions energy dispersive spectroscopy has been preferred.
___
- Akbulut, S., Arasan, S., Kalkan, E. 2007. Modification of clayey
soils using scrap tire rubber and synthetic fibers. Appl. Clay Sci.,
38: 23-32.
- Altun, S., Sezer, A., Erol, A. 2009. The effects of additives and
curing conditions on the mechanical behavior of a silty soil.
Cold Regions Sci. Tech., 56: 135-140.
- Aygun, Z. 2013. AFM and SEM Studies of VO2+ Doped
Potassium Dihydrogen Citrate Single Crystal Obtained by
Slow Evaporation Method. J. Chem. Crystall., 43: 103-107.
- Aygun, Z., Aygun, M. 2016. Spectroscopic analysis of Ahlat
stone (ignimbrite) and pumice formed by volcanic activity.
Spectrochim. Acta A, 166: 73-78.
- Bennur, TH., Srinivasan, D., Ratnasamy, P. 2001. EPR
spectroscopy of copper and manganese complexes encapsulated
in zeolites. Microporous Mesoporous Mater. 48: 111-118.
- Cubitt, JM. 1979. The Geochemistry, Mineralogy and Petrology
of Upper Paleozoic Shales of Kansas. As Kansas Geological
Survey Bulletin 217.
- Ferreira, CS., Santos, PL., Bonacin, JA., Passos, RR., Pocrifk,
LA. 2015. Rice Husk Reuse in the Preparation of SnO2/SiO2
Nanocomposite. Mater. Res., 3: 639-643.
- Fisli, A., Yuni, R., Krisnandi, K., Gunlazuardi, J. 2017.
Preparatıon and characterızatıon of Fe3O4/SiO2/TiO2
composıte for methylene blue removal ın water. Inter. J. Tech.,
1: 76-84.
- Ghazavi, M., Roustaie, M. 2010. The influence of freeze–thaw
cycles on the unconfined compressive strength of fiberreinforced clay. Cold Regions Sci. Tech. 61: 125–131.
- Jafari, M., Esna-ashari, M. 2012. Effect of waste tire cord
reinforcement on unconfined compressive strength of lime
stabilized clayey soil under freeze–thaw condition. Cold
Regions Sci. Tech., 82: 21-29.
- Kalkan, E., Bayraktutan, MS. 2008. Geotechnical evaluation
of Turkish clay deposits: a case study in Northern Turkey.
Environ. Geo., 55: 937-950.
- Li, J., Hu, Y., Sun, W., Luo, Y., Shi, X. et al. 2016. Facile
preparation of hyaluronic acid-modified Fe3O4@Mn3O4nanocomposites for targeted T1/T2 dual-mode MR imagingof cancer cells. Royal Soc. Chem., 6: 35295-35304.
- Lu, X., Zhang, H., Guo, Y., Wang, Y., Ge, X. et al. 2011.
Hexagonal hydroxyapatite formation on TiO2 nanotubes under urea modulation. Cryst. Engineer. Commun., 13: 3741-3749.
- Marfunin, AS. 1964. Radiospectroscopy of minerals. Geo. J., 4:
361-390.
- Musolino, M.G., Busacca, C., Mauriello, F., Pietropaolo, R.
2010. Aliphatic carbonyl reduction promoted by palladium
catalysts under mild conditions. Appl. Catalysis A, 379: 77-86.
- Rahman, M.A., Halfar, J., Shinjo, R. 2013. X-Ray Diffraction
Is a Promising Tool to Characterize Coral Skeletons. Advan.
Mater. Phys. Chem., 3: 120-125.
- Senderowski, C. 2014. Nanocomposite Fe-Al Intermetallic
Coating Obtained by Gas Detonation Spraying of Milled
Self-Decomposing Powder. J. Thermal Spray Tech., 7: 1124-
1134.
- Shu, Z., Wang, S. 2009. Synthesis and Characterization of
Magnetic Nanosized Fe3O4/MnO2 Composite Particles. J.
Nanomater., 1-5.
- Stoyanova, R., Gorova, M., Zhecheva, E. 2000. EPR monitoring
of Mn4+ distribution in Li4Mn5O12 spinels. J. Phys. Chem.
Solids, 61: 615-620.
- Sun, M., Lan, B., Lin, T., Cheng, G., Ye, F. et al. 2013. Controlled
synthesis of nanostructured manganese oxide: crystalline
evolution and catalytic activities. Cryst. Engineer. Commun.,
15: 7010-7018.
- Taşpolat, LT., Zorluer, İ., Koyuncu, H. 2006. Atik mermer
tozunun geçirimsiz kil tabakalarda donma - çözülmeye etkisi.
Yapı Teknolojileri Elektronik Dergisi, 2: 11-16.
- Wei, H., Jiao, Y., Liu, H. 2015. Effect of freeze–thaw cycles
on mechanical property of silty clay modified by fly ash and
crumb rubber. Cold Regions Sci. Techn., 116: 70–77.
- Yang, S., Cai, W., Zeng, H., Xu, X. 2009. Ultra-fine β-SiC
quantum dots fabricated by laser ablation in reactive liquid at
room temperature and their violet emission. J. Mater. Chem.,
19: 7119-7123.
- Yarbasi, Z., Karabulut, B., Karabulut, A. 2011. An EPR Study
of Gamma Irradiated Medicinal Plants: Cress Seeds and
Mistletoe. Gazi Unv. J. Sci., 2: 203-207.
- Yarbaşı, N. (2016) Geotechnical mapping of Oltu (Erzurum)
residential area and its vicinity. Pamukkale Unv. J. Engineer.
Sci., 22: 538-545.
- Zhang, W., Zeng, Y., Xu, C., Xiao, N., Gao, Y. 2012. A facile
approach to nanoarchitectured threedimensional graphenebased Li–Mn–O composite as high-power cathodes for Liion batteries. Beilstein J. Nanotech., 3: 513-523.