A Spectroscopic Analysis of Clay Types and Silty Sand from Oltu/Erzurum (Turkey) Region Reinforcing with Marble Dust and Waste Tire

In the present study, it has been aimed to give a comprehensive analysis of unreinforced and reinforced materials (with waste tire and marble dust additions in different amounts); clays (green and red) and silty sand, obtained from Oltu/Erzurum region which consists of Oligocene lower upper sedimentary units, volcanic rocks and upper sedimentary units. In order to investigate the magnetic properties of these samples, electron paramagnetic resonance has been used; to see the crystalline natüre x-ray diffraction has been performed; to observe the surface morphology scanning electron microscope has been used and to learn the elemental compositions energy dispersive spectroscopy has been preferred.

Mermer Tozu ve Atık Lastikle Takviye Edilmiş Oltu/Erzurum (Türkiye) Bölgesine Ait Kil Türleri ve Siltli Kumun Spektroskopik Analizi

Bu çalışmada, Oligosen yaşlı alt sedimanter birim, volkanik birim ve üst sedimanter birimden oluşan Oltu/Erzurum bölgesine ait takviye edilmemiş ve takviye edilmiş (atık lastik ve mermer tozunun farklı miktarlarda eklenmesi ile) kil türleri ve siltli kum örneklerinin kapsamlı bir analizinin verilmesi amaçlanmıştır. Bu örneklerin manyetik özelliklerini incelemek için elektron paramanyetik rezonans kullanılmıştır, kristal doğasını görmek için x-ışını kırınımı performe edilmiştir, yüzey morfolojisini gözlemlemek için taramalı elektron mikroskobu kullanılmış ve elementel kompozisyonu öğrenmek için enerji dağılımlı spektroskopi tercih edilmiştir.

___

Akbulut, S., Arasan, S., Kalkan, E. 2007. Modification of clayey soils using scrap tire rubber and synthetic fibers. Appl. Clay Sci., 38: 23-32.

Altun, S., Sezer, A., Erol, A. 2009. The effects of additives and curing conditions on the mechanical behavior of a silty soil. Cold Regions Sci. Tech., 56: 135-140.

Aygun, Z. 2013. AFM and SEM Studies of VO2+ Doped Potassium Dihydrogen Citrate Single Crystal Obtained by Slow Evaporation Method. J. Chem. Crystall., 43: 103-107.

Aygun, Z., Aygun, M. 2016. Spectroscopic analysis of Ahlat stone (ignimbrite) and pumice formed by volcanic activity. Spectrochim. Acta A, 166: 73-78.

Bennur, TH., Srinivasan, D., Ratnasamy, P. 2001. EPR spectroscopy of copper and manganese complexes encapsulated in zeolites. Microporous Mesoporous Mater. 48: 111-118.

Cubitt, JM. 1979. The Geochemistry, Mineralogy and Petrology of Upper Paleozoic Shales of Kansas. As Kansas Geological Survey Bulletin 217.

Ferreira, CS., Santos, PL., Bonacin, JA., Passos, RR., Pocrifk, LA. 2015. Rice Husk Reuse in the Preparation of SnO2/SiO2 Nanocomposite. Mater. Res., 3: 639-643.

Fisli, A., Yuni, R., Krisnandi, K., Gunlazuardi, J. 2017. Preparatıon and characterızatıon of Fe3O4/SiO2/TiO2 composıte for methylene blue removal ın water. Inter. J. Tech., 1: 76-84.

Ghazavi, M., Roustaie, M. 2010. The influence of freeze–thaw cycles on the unconfined compressive strength of fiberreinforced clay. Cold Regions Sci. Tech. 61: 125–131.

Jafari, M., Esna-ashari, M. 2012. Effect of waste tire cord reinforcement on unconfined compressive strength of lime stabilized clayey soil under freeze–thaw condition. Cold Regions Sci. Tech., 82: 21-29.

Kalkan, E., Bayraktutan, MS. 2008. Geotechnical evaluation of Turkish clay deposits: a case study in Northern Turkey. Environ. Geo., 55: 937-950.

Li, J., Hu, Y., Sun, W., Luo, Y., Shi, X. et al. 2016. Facile preparation of hyaluronic acid-modified Fe3O4@Mn3O4nanocomposites for targeted T1/T2 dual-mode MR imagingof cancer cells. Royal Soc. Chem., 6: 35295-35304.

Lu, X., Zhang, H., Guo, Y., Wang, Y., Ge, X. et al. 2011. Hexagonal hydroxyapatite formation on TiO2 nanotubes under urea modulation. Cryst. Engineer. Commun., 13: 3741-3749.

Marfunin, AS. 1964. Radiospectroscopy of minerals. Geo. J., 4: 361-390.

Musolino, M.G., Busacca, C., Mauriello, F., Pietropaolo, R. 2010. Aliphatic carbonyl reduction promoted by palladium catalysts under mild conditions. Appl. Catalysis A, 379: 77-86.

Rahman, M.A., Halfar, J., Shinjo, R. 2013. X-Ray Diffraction Is a Promising Tool to Characterize Coral Skeletons. Advan. Mater. Phys. Chem., 3: 120-125.

Senderowski, C. 2014. Nanocomposite Fe-Al Intermetallic Coating Obtained by Gas Detonation Spraying of Milled Self-Decomposing Powder. J. Thermal Spray Tech., 7: 1124- 1134.

Shu, Z., Wang, S. 2009. Synthesis and Characterization of Magnetic Nanosized Fe3O4/MnO2 Composite Particles. J. Nanomater., 1-5.

Stoyanova, R., Gorova, M., Zhecheva, E. 2000. EPR monitoring of Mn4+ distribution in Li4Mn5O12 spinels. J. Phys. Chem. Solids, 61: 615-620.

Sun, M., Lan, B., Lin, T., Cheng, G., Ye, F. et al. 2013. Controlled synthesis of nanostructured manganese oxide: crystalline evolution and catalytic activities. Cryst. Engineer. Commun., 15: 7010-7018.

Taşpolat, LT., Zorluer, İ., Koyuncu, H. 2006. Atik mermer tozunun geçirimsiz kil tabakalarda donma - çözülmeye etkisi. Yapı Teknolojileri Elektronik Dergisi, 2: 11-16.

Wei, H., Jiao, Y., Liu, H. 2015. Effect of freeze–thaw cycles on mechanical property of silty clay modified by fly ash and crumb rubber. Cold Regions Sci. Techn., 116: 70–77.

Yang, S., Cai, W., Zeng, H., Xu, X. 2009. Ultra-fine β-SiC quantum dots fabricated by laser ablation in reactive liquid at room temperature and their violet emission. J. Mater. Chem., 19: 7119-7123.

Yarbasi, Z., Karabulut, B., Karabulut, A. 2011. An EPR Study of Gamma Irradiated Medicinal Plants: Cress Seeds and Mistletoe. Gazi Unv. J. Sci., 2: 203-207.

Yarbaşı, N. (2016) Geotechnical mapping of Oltu (Erzurum) residential area and its vicinity. Pamukkale Unv. J. Engineer. Sci., 22: 538-545.

Zhang, W., Zeng, Y., Xu, C., Xiao, N., Gao, Y. 2012. A facile approach to nanoarchitectured threedimensional graphenebased Li–Mn–O composite as high-power cathodes for Liion batteries. Beilstein J. Nanotech., 3: 513-523.
Karaelmas Fen ve Mühendislik Dergisi-Cover
  • ISSN: 2146-4987
  • Yayın Aralığı: Yılda 2 Sayı
  • Başlangıç: 2011
  • Yayıncı: ZONGULDAK BÜLENT ECEVİT ÜNİVERSİTESİ