KURKUMİN TABANLI BİYOPOLİMER FİLMLERİN GÖRÜNÜR IŞIK ALTINDA GELİŞTİRİLMESİ

Çalışmanın amacı, kurkumin ve furan modifiye jelatin kullanarak görünür ışık altında gerçekleşen fotooksidasyon reaksiyonu ile bir kolorimetrik film geliştirmektir. Bu amaçla, sığır jelatini furfuril izosiyanat ile modifiye edilerek görünür ışığa duyarlı furan modifiye jelatin (f-jelatin) sentezlenmiştir. Çalışmada kurkuminin hem görünür ışığa duyarlaştırıcı olarak hem de toplam uçucu bazik azot algılayıcısı olarak kullanılması hedeflenmiştir. F-jelatin, jelatin ve kurkumin oranları değiştirilerek hazırlanan beş farklı filmle mekanik, bariyer, ısıl ve mikro yapı karakterizasyon deneyleri gerçekleştirilmiştir. %20 (h/h) kurkumin eklenmiş f-jelatin ile hazırlanan filmlerin (K20-FG), karakterizasyon deneyleri sonucu en iyi sonucu verdiği ortaya konmuştur. Daha sonra K20-FG filmlerinin farklı amonyak gazı konsantrasyonlarındaki renk değişim miktarına karar verilmiştir. Gaz algı testleri sonucunda proteince yüksek gıdaların bozulma takibinin geliştirilen K20-FG filmleri ile mümkün olabileceği sonucuna varılmıştır.

Anahtar Kelimeler:

Kolorimetrik film, furan modifiye jelatin, kurkumin, görünür ışık, fotooksidasyon

DEVELOPMENT OF CURCUMIN BASED BIOPOLYMER FILMS UNDER VISIBLE LIGHT IRRADIATION

The aim of the study was to develop a colorimetric film with photooxidation reaction under visible light using curcumin and furan modified gelatin. For this purpose, bovine gelatin was modified with furfuryl isocyanate to synthesize photosensitive furan modified gelatin (f-gelatin). In the study, curcumin was expected to serve both as the visible light absorbing photosensitizer and the recognition agent for total volatile basic amines. Mechanical, barrier, thermal and micro structure characterization experiments were carried out with five different films prepared by changing f-gelatin, gelatin and curcumin ratios. Films (K20-FG) prepared with f-gelatin and 20% (v/v) curcumin was shown to give the best results as a result of characterization tests. Later, color difference values of K20-FG films against different concentrations of volatile ammonia were monitored. Gas sensing tests were shown that monitoring of protein rich food spoilage, could be possible with the developed K20-FG films.

Keywords:

colorimetric film, furan modified gelatin, curcumin, visible light, photooxidation,

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