Sefa DURMUŞ, Orhan ATAKOL, Leyla TATAR, Zehra DURMUŞ, Kaan C. EMREGÜL

Synthesis and crystal structure of a heterobinuclear Ni-Cd complex, { Bis-N, N-dimethylformamide-$mu$- [ N, N-bis(salicylidene)1,3-propanedi amine ] nickel (II) } dichloro cadmium (II)

Çalışmada, N,N'-bis(salisiliden)-l,3-propandiamin ligand olarak kullanıldı ve nikel(II) ile kompleksi hazırlandı. Sonra kadmiyum klorür ile susuz ortamlarda Ni(II)-Cd(II) heterodinükleer kompleksi sentezlendi. X-ışınları diffraksiyonu yöntemleri ve spektroskopik bazı yöntemlerle yapısı aydınlatıldı. Birim hücrede iki simetrik molekül bulunmakta ve tek bir molekül gibi gözlenmektedir.

In this study, N,N'-bis(salicylidene)-l,3propanediamine was used as ligand and its Ni(II) complexes were prepared. Non-aqueous Ni(lI)-Cd(II) heterodinuclear complexes with cadmium chloride were also prepared in non-aqueous media. The structure of the complexes were investigated using x-ray diffaction and some analytical spectroscopic methods. Two symmetrical identical units in the unit cell were observed as one molecule.

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