Synthesis of a novel antiweathering nanocomposite superhydrophobic room temperature vulcanized (RTV) silicon rubber enhanced with nanosilica for coating high voltage insulators

Synthesis of a novel antiweathering nanocomposite superhydrophobic room temperature vulcanized (RTV) silicon rubber enhanced with nanosilica for coating high voltage insulators

A new nanocomposite superhydrophobic of the RTV (room temperature vulcanized) silicon rubber reinforced with a different percentage of nanosilica was prepared by a two-stage sol-gel route to obtain a superhydrophobic surface coating on high voltage glass insulator, preventing the dust-water droplet from adhering to its surface. The cold spraying technique was utilized to build up a thin nanocomposite superhydrophobic layer on the glass insulator containing different percentages of the nanosilica particles, such as 23 wt %, 33 wt %, and 44 wt % with RTV silicon substrate. The synthesized nanocomposite was analyzed using the contact angle, roughness, adhesion, hardness, and dielectric strength tests. Moreover, the prepared RTV silicon rubber/nanosilica superhydrophobic nanocomposite layer was characterized using the field emission scanning electron microscope (FESEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), and the particle size analysis test. Based on the results, the nanosilica particles were well-incorporated into the RTV silicon rubber, obtaining an excellent homogenous distribution thin layer on its surface, supporting its capability to be a superior superhydrophobic surface. The results reveal that the RTV silicon rubber/ 33wt % nanosilica was the best as a superhydrophobic behavior with a contact angle reaching higher than 158˚± 3; also, a significant change in the dielectric strength was obtained to be 25.5 kV (using a speed voltage of 5.0 kV/s). Importantly, the flashover test was also conducted, and it was found that there was a significant change in the leak current between the coated and uncoated samples. The leak current of the coated sample with a superhydrophobic nanocomposite was reduced to 2.5 mA, while the uncoated sample became 3.2 mA using a voltage load value of 60 kV. The results presented here may improve the nanocomposite material as an antiweathering superhydrophobic thin layer supported by the prepared nano-SiO2 particles against the dust-water droplets which may be adhesive to the high voltage glass insulator.

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  • 1. Meena M, Sinhamahapatra A, Kumar A. Superhydrophobic polymer composite coating on glass via spin coating technique. Colloid and Polymer Science 2019; 297 (11): 1499 –1505. doi: 10.1007/s00396-019-04560-z
  • 2. Siri R, Thongrom S, Dommelen P, Muensit N, Daengngam C. Demonstrating spray deposition of self-regulated nanorough layers for stable transparent superhydrophobic film coatings. Thin Solid Films 2019; 686: 137429, doi: 10.1016/j.tsf.2019.137429
  • 3. Nishimoto S, Bhushan B. Bioinspired self-cleaning surfaces with superhydrophobicity, superoleophobicity, and superhydrophilicity. Royal Socity Chemistry Advanced 2013; 3 (3): 671–690. doi: 10.1039/c2ra21260a
  • 4. Bhushan B, Jung Y, Koch K. Self-Cleaning Efficiency of Artificial Superhydrophobic Surfaces. Langmuir 2009; 25 (5): 3240–3248. doi: 10.1039/b818940d
  • 5. Darmanin T, Guittard F. Recent advances in the potential applications of bioinspired superhydrophobic materials. Jounral of Materials Chemistry A 2014; 2 (39): 16319–16359. doi: 10.1039/C4TA02071E
  • 6. Zang D, Zhu R, Wu C, Yu X, Zhang Y. Fabrication of stable superhydrophobic surface with improved anticorrosion property on magnesium alloy. Scripta Materialia 2013; 69 (8): 614–617. doi: 10.1016/j.scriptamat.07.014
  • 7. Farhadi S, Farzaneh M, Kulinich S. Anti-icing performance of superhydrophobic surfaces. Applied Surface Science 2011; 257 (14): 6264– 6269. doi: 10.1016/j.apsusc.2011.02.057
  • 8. Peng C, Xing S, Yuan Z, Xiao J, Wang C et al. Preparation and anti-icing of superhydrophobic PVDF coating on a wind turbine blad. Applied Surface Science 2012; 259: 764–768. doi: 10.1016/j.apsusc.2012.07.118
  • 9. Fu Y, Jiang J, Zhang Q, Zhan X, Chen F. Robust liquid-repellent coatings based on polymer nanoparticles with excellent self-cleaning and antibacterial performances. Jounral of Materials Chemistry A 2017; 5 (1): 275–284. doi: 10.1039/c6ta06481g
  • 10. Privett B, Youn J, Hong S, Lee J, Han J et al. Antibacterial fluorinated silica colloid superhydrophobic surfaces. Langmuir 2011; 27 (15): 9597–9601. doi: 10.1021/la201801e
  • 11. Trinh Q, Nguyena D, Hossain M, Mok Y. Deposition of superhydrophobic coatings on glass substrates from hexamethyldisiloxane using a kHz-powered plasma jet. Surface and Coatings Technology 2019; 361: 377–385. doi: 10.1016/j.surfcoat.2019.01.068
  • 12. Solaree L, Monshi A, Ghayour H. A new approach for the fabrication of hydrophobic silica coatings on glass using sol–gel method. Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry 2013; 45 (12): 1769–1772. doi: 10.1080/15533174.2013.872132
  • 13. Wang B, Hua Y,Ye Y,Chen R, Li Z. Transparent superhydrophobic solar glass prepared by fabricating groove-shaped arrays on the surface. Applied Surface Science 2017; 426: 957–964. doi: 10.1016/j.apsusc.2017.07.169
  • 14. Zhou X, Wang G,Wang M, Zhang Y, Yin W et al. A simple preparation method for superhydrophobic surface on silicon rubber and its properties. Progress in Organic Coatings 2020; 143: 105612. doi: 10.1016/j.porgcoat.2020.105612
  • 15. Raghuraman G, Lu C, Zhang Z, Yang S. Highly transparent and superhydrophobic surfaces from co-assembly of nanoparticles (100 nm). Langmuir 2011; 27 (7): 4594. doi: 10.1021/la104067c
  • 16. Wolfs M, Darmanin T, Guittard F. Superhydrophobic fibrous polymers. Polymer Reviews 2013; 53 (3): 460–505. doi: 10.1080/15583724.2013.808666
  • 17. Erbil H, Demirel A, Avci Y, Mert O. Transformation of a simple plastic into a superhydrophobic surface. Science 2003; 299 (5611): 1377– 1380. doi: 10.1126/science.1078365
  • 18. Zhang M, Yu J, Chen R, Liu Q, Liu J et al. Highly transparent and robust slippery lubricant-infused porous surfaces with anti-icing and anti-fouling performances. Journal of Alloys and Compounds 2019; 803: 51–60. doi: 10.1016/j.jallcom.2019.06.241
  • 19. Zhu J, Liao K. Preparation of superhydrophobic surface with tunable adhesion on glass substrate. Materials Research Express 2020; 7 (7): 76409. doi: 10.1088/2053-1591/aba90e
  • 20. Junfe O, Hu W, Li C, Wang Y, Xue M et al. Tunable water adhesion on titanium oxide surfaces with different surface structures. ACS Applied Materials Interfaces 2012; 4 (11): 5737–41. doi: 10.1021/am301946t
  • 21. Bormashenko E. Wetting of real solid surfaces: New glance on well-known problems. Colloid and Polymer Science 2013; 291 (2): 339–342. doi: 10.1007/s00396-012-2778-8
  • 22. Gu H, Wang C, Gong S, Mei Y, Li H et al. Investigation on contact angle measurement methods and wettability transition of porous surfaces. Surface and Coatings Technolgy 2016; 292: 72–77. doi: 10.1016/j.surfcoat.2016.03.014
  • 23. Mittal K. Contact Angle, Wettability and Adhesion. London: CRC Press; 2003.
  • 24. Moretto H, Schulze M, Wagner G. Silicones. Ullmann’s Encyclopedia of Industrial Chemistry 2000; 675–712. doi: 10.1002/14356007.a24
  • 25. Lindyberg J. RTV Silicone Adhesive Sealants. in Adhesives in Manufacturing, 1st edition., G. L. Schneberger, Ed. Routledge: Taylor and Francis Group; 1983.
  • 26. Topcu A, Erdogan E, Cengiz U. Preparation of stable, transparent superhydrophobic film via one step one pot sol-gel method. Colloid and Polymer Science 2018; 296 (9): 1523–1532. doi: 10.1007/s00396-018-4377-9
  • 27. Seyedmehdi S, Zhang H, Zhu J. Applied Surface Science Superhydrophobic RTV silicone rubber insulator coatings. Applied Surface Science 2012; 258 (7): 2972–2976. doi: 10.1016/j.apsusc.2011.11.020
  • 28. Veluchamy P, Barathan S, Sivakumar G, Anandhan N. X-ray diffraction analysis on the effect of silica fume and water in blended cement paste. International Journal of Applied Engineering Research 2009; 4 (11): 2369-77.
  • 29. Nallathambi G, Ramachandran T, Rajendran V, Palanivelu R. Effect of silica nanoparticles and BTCA on physical properties of cotton fabrics. Materials Research 2011; 14 (4): 552–559. doi: 10.1590/S1516-14392011005000086
  • 30. Gao Y, Yan Z, Gray J, He X, Wang D et al. Polymer–inorganic solid–electrolyte interphase for stable lithium metal batteries under lean electrolyte conditions. Nature Materials 2019; 18 (4): 384–389, doi: 10.1038/s41563-019-0305-8
  • 31. Indulekha K, Behera P, Rajeev R, Gouri C, Ninan K. Polyfluoroalkyl siloxanes with varying trifluoropropyl content: Synthesis, characterization and solvent resistance studies. Journal of Fluorine Chemistry 2017; 200: 24–32. doi: 10.1016/j.jfluchem.2017.05.007
  • 32. Liu T, Sun C, Ma F. Study on the synthesis and thermal degradation of vinylphenylpolysilsesquioxane. Journal of Analytical and Applied Pyrolysis 2018; 130: 249–255. doi: 10.1016/j.jaap.2017.12.024
  • 33. Ji J, Ge X, Pang X, Liu R, Wen S et al. Synthesis and characterization of room temperature vulcanized silicone rubber using methoxylcapped MQ silicone resin as self-reinforced cross-linker. Polymers (Basel) 2019; 11 (7): 1142. doi: 10.3390/polym11071142
  • 34. Sun D, Kang S, Liu C, Lu Q, Cui L et al. Effect of zeta potential and particle size on the stability of $SiO_2$ nanospheres as carrier for ultrasound imaging contrast agents. International Journal of Electrochemical Science 2016; 11 (10): 8520–8529. doi: 10.20964/2016.10.30
  • 35. Fauchais P, Vardelle A. Thermal plasmas surface treatment. Materials Surface Processing by Directed Energy Techniques 2006; 311–344. doi: 10.1016/B978-008044496-3/50010-1
  • 36. Gong X, He S. Highly durable superhydrophobic polydimethylsiloxane/silica nanocomposite surfaces with good self-cleaning ability. American Chemical Society Omega 2020; 5 (8): 4100–4108. doi: 10.1021/acsomega.9b03775
  • 37. Ju S, Chen M, Zhang H, Zhang Z. Dielectric properties of nanosilica/low-density polyethylene composites: The surface chemistry of nanoparticles and deep traps induced by nanoparticles. Express Polymer Letters 2014; 8 (9): 682–691. doi: 10.3144/expresspolymlett.2014.71
  • 38. Bico J, Marzolin C, Quere D. Superhydrophobic states. Nature Materials 2003; 2 (7): 457–460. doi: 10.1038/nmat924
  • 39. Li J, Sun C, Sima W, Yang Q. Stage pre-warning based on leakage current characteristics before contamination flashover of porcelain and glass insulators. IET Generation, Transmission & Distribution 2009; 3 (7): 605–615. doi: 10.1049/IET-Digital Library.2008.0604
  • 40. Feng L, Li S, Li Y, Li H, Zhang L et al. Super-hydrophobic surfaces: From natural to artificial. Advanced Materials 2002; 14 (24): 1857– 1860. doi: 10.1002/adma.200290020
Turkish Journal of Chemistry-Cover
  • ISSN: 1300-0527
  • Yayın Aralığı: Yılda 6 Sayı
  • Yayıncı: TÜBİTAK
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