Hava ÖZAY, Mehmet YILDIRIM, Özgür ÖZAY

Synthesis and characterization of novel urea and thiourea substitute cyclotriphosphazene compounds as naked-eye sensors for F$^{-}$ and CN$^{-}$ anions

Novel hexakisurea and thiourea cyclotriphosphazene compounds (3-7) were synthesized. The structure of all compounds was identified using FT-IR $^{1}$H, $^{13}$C, and $^{31}$P NMR spectroscopy; MALDI-TOF MS; and elemental analysis. The optical sensor properties for anions of 3-7 were investigated using UV-Vis spectroscopy. It was determined that compounds 6 and 7 are spectrophotometric and naked eye sensors for F$^{-}$ and CN$^{-}$ anions, respectively. Sensor properties of these compounds for anions were investigated using UV-Vis spectroscopy. The stoichiometry of host-guest complexes was found to be 1:6.

Anahtar Kelimeler:

Cyclotriphosphazene, urea, thiourea, naked-eye sensor

Synthesis and characterization of novel urea and thiourea substitute cyclotriphosphazene compounds as naked-eye sensors for F$^{-}$ and CN$^{-}$ anions

Keywords:

Cyclotriphosphazene, urea, thiourea, naked-eye sensor,

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