Synthesis and Characterization of Metal Complexes of Cu(II), Ni(II), Zn(II), Co(II), Mn(II) and Cd(II) with Tetradentate Schiff Bases

4-(Benzeneazo)salicylaldehyde was synthesized with aniline, sodium nitrite and salicylaldehyde. Two tetradentate ligands, N,N'-bis[4-(benzeneazo) salicylaldehyde]-o-phenylenediamine (H2L) and N,N'-bis[4-(benzeneazo) salicylaldehyde]ethylenediamine (H2L') were formed by the 2:1 molar condensation of 4-(benzeneazo) salicylaldehyde with o-phenylenediamine or ethylenediamine. Their Cu(II), Ni(II), Zn(II), Co(II), Mn(II) and Cd(II) complexes were synthesized and characterized by elemental analysis, molar conductivity measurements, and infrared and electronic spectral data. Two ligands and their Ni(II) and Zn(II) complexes were further identified using 1H NMR spectra. The results suggest that the metal is bonded to the ligand through the phenolic oxygen and the imino nitrogen.

Synthesis and Characterization of Metal Complexes of Cu(II), Ni(II), Zn(II), Co(II), Mn(II) and Cd(II) with Tetradentate Schiff Bases

4-(Benzeneazo)salicylaldehyde was synthesized with aniline, sodium nitrite and salicylaldehyde. Two tetradentate ligands, N,N'-bis[4-(benzeneazo) salicylaldehyde]-o-phenylenediamine (H2L) and N,N'-bis[4-(benzeneazo) salicylaldehyde]ethylenediamine (H2L') were formed by the 2:1 molar condensation of 4-(benzeneazo) salicylaldehyde with o-phenylenediamine or ethylenediamine. Their Cu(II), Ni(II), Zn(II), Co(II), Mn(II) and Cd(II) complexes were synthesized and characterized by elemental analysis, molar conductivity measurements, and infrared and electronic spectral data. Two ligands and their Ni(II) and Zn(II) complexes were further identified using 1H NMR spectra. The results suggest that the metal is bonded to the ligand through the phenolic oxygen and the imino nitrogen.

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Kaynak Göster

Bibtex @araştırma makalesi { tbtkchem142576, journal = {Turkish Journal of Chemistry}, issn = {1300-0527}, eissn = {1303-6130}, address = {}, publisher = {TÜBİTAK}, year = {2006}, volume = {30}, pages = {41 - 48}, doi = {}, title = {Synthesis and Characterization of Metal Complexes of Cu(II), Ni(II), Zn(II), Co(II), Mn(II) and Cd(II) with Tetradentate Schiff Bases}, key = {cite}, author = {Lıu, Jian-ning and Wu, Bo-wan and Zhang, Bing and Lıu, Yongchun} }
APA Lıu, J , Wu, B , Zhang, B , Lıu, Y . (2006). Synthesis and Characterization of Metal Complexes of Cu(II), Ni(II), Zn(II), Co(II), Mn(II) and Cd(II) with Tetradentate Schiff Bases . Turkish Journal of Chemistry , 30 (1) , 41-48 .
MLA Lıu, J , Wu, B , Zhang, B , Lıu, Y . "Synthesis and Characterization of Metal Complexes of Cu(II), Ni(II), Zn(II), Co(II), Mn(II) and Cd(II) with Tetradentate Schiff Bases" . Turkish Journal of Chemistry 30 (2006 ): 41-48 <
Chicago Lıu, J , Wu, B , Zhang, B , Lıu, Y . "Synthesis and Characterization of Metal Complexes of Cu(II), Ni(II), Zn(II), Co(II), Mn(II) and Cd(II) with Tetradentate Schiff Bases". Turkish Journal of Chemistry 30 (2006 ): 41-48
RIS TY - JOUR T1 - Synthesis and Characterization of Metal Complexes of Cu(II), Ni(II), Zn(II), Co(II), Mn(II) and Cd(II) with Tetradentate Schiff Bases AU - Jian-ning Lıu , Bo-wan Wu , Bing Zhang , Yongchun Lıu Y1 - 2006 PY - 2006 N1 - DO - T2 - Turkish Journal of Chemistry JF - Journal JO - JOR SP - 41 EP - 48 VL - 30 IS - 1 SN - 1300-0527-1303-6130 M3 - UR - Y2 - 2021 ER -
EndNote %0 Turkish Journal of Chemistry Synthesis and Characterization of Metal Complexes of Cu(II), Ni(II), Zn(II), Co(II), Mn(II) and Cd(II) with Tetradentate Schiff Bases %A Jian-ning Lıu , Bo-wan Wu , Bing Zhang , Yongchun Lıu %T Synthesis and Characterization of Metal Complexes of Cu(II), Ni(II), Zn(II), Co(II), Mn(II) and Cd(II) with Tetradentate Schiff Bases %D 2006 %J Turkish Journal of Chemistry %P 1300-0527-1303-6130 %V 30 %N 1 %R %U
ISNAD Lıu, Jian-ning , Wu, Bo-wan , Zhang, Bing , Lıu, Yongchun . "Synthesis and Characterization of Metal Complexes of Cu(II), Ni(II), Zn(II), Co(II), Mn(II) and Cd(II) with Tetradentate Schiff Bases". Turkish Journal of Chemistry 30 / 1 (Ocak 2006): 41-48 .
AMA Lıu J , Wu B , Zhang B , Lıu Y . Synthesis and Characterization of Metal Complexes of Cu(II), Ni(II), Zn(II), Co(II), Mn(II) and Cd(II) with Tetradentate Schiff Bases. Turk J Chem. 2006; 30(1): 41-48.
Vancouver Lıu J , Wu B , Zhang B , Lıu Y . Synthesis and Characterization of Metal Complexes of Cu(II), Ni(II), Zn(II), Co(II), Mn(II) and Cd(II) with Tetradentate Schiff Bases. Turkish Journal of Chemistry. 2006; 30(1): 41-48.
IEEE J. Lıu , B. Wu , B. Zhang ve Y. Lıu , "Synthesis and Characterization of Metal Complexes of Cu(II), Ni(II), Zn(II), Co(II), Mn(II) and Cd(II) with Tetradentate Schiff Bases", Turkish Journal of Chemistry, c. 30, sayı. 1, ss. 41-48, Oca. 2006
  • ISSN: 1300-0527
  • Yayın Aralığı: Yılda 6 Sayı
  • Yayıncı: TÜBİTAK

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