History, development, and a new concept of phthalocyanines in Turkey
This paper reviews the history of phthalocyanines in Turkey. Phthalocyanines are chemical compounds that were accidently discovered nearly a century ago. The relevant research and articles have grown dramatically in Turkey since our first paper on them containing four [15]crown[5] published in 1986. The ball-type phthalocyanines were produced and published as a new concept in phthalocyanine chemistry for the first time by our group in Turkey in 2006. Unfortunately, with the exception of our work on this subject, almost no papers have been published in Turkey or in other countries since then. We strongly urge scientists to consider working on this new type of phthalocyanine, which shows interesting development potential in electrical, electrochemical, and photovoltaic applications as well as oxygen reduction for fuel cells.
History, development, and a new concept of phthalocyanines in Turkey
This paper reviews the history of phthalocyanines in Turkey. Phthalocyanines are chemical compounds that were accidently discovered nearly a century ago. The relevant research and articles have grown dramatically in Turkey since our first paper on them containing four [15]crown[5] published in 1986. The ball-type phthalocyanines were produced and published as a new concept in phthalocyanine chemistry for the first time by our group in Turkey in 2006. Unfortunately, with the exception of our work on this subject, almost no papers have been published in Turkey or in other countries since then. We strongly urge scientists to consider working on this new type of phthalocyanine, which shows interesting development potential in electrical, electrochemical, and photovoltaic applications as well as oxygen reduction for fuel cells.
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- Hanack, M.; Heckmann, H.; Polley, R. Meth. Org. Chem.(houben-Weyl), Phthalocyanines and Related Compounds 1998, E9d, 717–846.
- Koray, A. R.; Ahsen, V.; Bekaroglu, ¨O. J. Chem. Soc. Chem. Commun. 1986, 932–933.
- Kobayashi, N.; Nishiyama, Y. J. Chem. Soc. Chem. Commun. 1986, 1462–1463.
- Hendriks, O.; Sielcken, O. E.; Drenth, W.; Nolte, R. J. M. J. Chem. Soc. Chem.Commun. 1986, 1464–1465.
- Sirlin, C.; Bosio, L.; Simon, J.; Ahsen, V.; Yılmazer, E.; Bekaro˘glu, ¨O. Chem. Phys. Lett. 1987, 139, 362–364.
- Bardin, M.; Bertounesque, E.; Plichon, V.; Simon, J.; Ahsen, V.; Bekaro˘glu, ¨O. J. Electroanal. Chem. 1989, 271, 173–180.
- Ahsen, V.; Yılmazer, E.; G¨ul, A.; Bekaro˘glu, ¨O. Macromol. Chem. Rapid. Commun. 1987, 8, 243–246.
- Ahsen, V.; Yılmazer, E.; Erta¸s, M.; Bekaro˘glu, ¨O. Dalton Trans. 1988, 401–406.
- Ahsen, V.; Yılmazer, E.; G¨urek, A.; G¨ul, A.; Bekaro˘glu, ¨O. Helv. Chim. Acta 1988, 71, 1616–1621.
- Ahsen, V.; Yılmazer, E.; Bekaro˘glu, ¨O. Macromol. Chem. 1988, 189, 2533–2543.
- Sarıg¨ul, S.; Bekaro˘glu, ¨O. Chem. Ber. 1989, 122, 291–292.
- Ko¸cak, M.; Cihan, A.; Okur, A. ˙I.; Bekaro˘glu, ¨O. J. Chem. Soc. Chem. Commun. 1991, 577–578.
- Musluo˘glu, E.; Ahsen, V.; G¨ul, A.; Bekaro˘glu, ¨O. Chem. Ber. 1991, 124, 2531–2536.
- G¨urek, A.; Ahsen, V.; G¨ul, A.; Bekaro˘glu, ¨O. Dalton Trans. 1991, 3367–3371.
- G¨um¨u¸s, G.; ¨Ozt¨urk, Z. Z.; Ahsen, V.; G¨ul, A.; Bekaro˘ O. Dalton Trans. 1992, 2485–2489.
- Musluo˘glu, E.; G¨urek, A.; Ahsen, V.; G¨ul, A.; Bekaro˘glu, ¨O. Chem. Ber. 1992, 125, 2337–2339. ¨
- Ozt¨urk, Z. Z.; Musluo˘glu, E.; Ahsen, V.; G¨ul. A.; Bekaro˘glu, ¨O. J. Mat. Sci. 1992, 27, 6183–6186. ¨
- Ozt¨urk, Z. Z.; Altındal, A.; G¨urek, A.; Bekaro˘glu, ¨O. Synth. Met. 1992, 52, 291–297.
- Tan, N.; Bekaro˘glu, ¨O. Kadırgan, F. J. Electroanal. Chem. 1994, 364, 251–256.
- Ko¸cak, M.; G¨urek, A.; G¨ul, A.; Bekaro˘glu, ¨O. Chem. Ber. 1994, 127, 355-358.
- Ko¸cak, M.; Okur, A. ˙I.; Bekaro˘glu, ¨O. Dalton Trans. 1994, 323–326.
- G¨urol, ˙I.; Ahsen, V.; Bekaro˘glu, ¨O. Dalton Trans. 1994, 497–500.
- G¨urek, A.; Bekaro˘glu, ¨O. Dalton Trans. 1994, 1419–1423.
- Tan, N.; G¨urek, A.; Bekaro˘glu, ¨O.; Kadırgan, F. J. Electroanal. Chem. 1994, 374, 45–52.
- Dabak, S.; G¨ul, A.; Bekaro˘glu, ¨O. Chem. Ber. 1994, 127, 200–2012.
- G¨urek, A.; Bekaro˘glu, ¨O. Helv. Chim. Acta 1994, 77, 1616–1622.
- Musluo˘glu, E.; Bekaro˘glu, ¨O. J. Chem. Res. (S) 1994, 420–421.
- Ozkaya, A. R.; Okur, A. ˙I.; G¨ul, A.; Bekaro˘glu, ¨O. J. Coord. Chem. 1994, 33, 311– 318. ¨
- Avcıata, U.; Bozdo˘gan, A. E.; Ko¸cak, M.; G¨ul, A.; Bekaro˘glu, ¨O. J. Coord. Chem. 1995, 35, 319–323.
- Ozt¨urk, Z. Z.; Zhou, R.; Weimer, U.; Ahsen, V.; Bekaro˘glu, ¨O; G¨opel, W.Sens. Actuators B. 1995, 26–27, 208–212. ¨
- Dabak, S.; G¨um¨u¸s, G.; G¨ul, A.; Bekaro˘glu, ¨O. J. Coord. Chem. 1996, 38, 287–293.
- Yılmaz, ˙I.; Bekaro˘glu, ¨O. Chem. Ber. 1996, 129, 967–971.
- Zhou, R.; Josse, F.; G¨opel, W.; ¨Ozt¨urk, Z. Z.; Bekaro˘glu, ¨O. Appl. Organomet.Chem. 1996, 10, 557–577.
- Bekaro˘glu, ¨O. Appl. Organomet. Chem. 1996, 10, 605–622.
- Dabak, S.; Bekaro˘glu, ¨O. New J. Chem. 1997, 21, 267–271.
- G¨urek, A.; Bekaro˘glu, ¨O. J. Porphyrins Phthalocyanines 1997, 1, 67–76. ¨
- Ozkaya, A. R.; G¨urek. A. G.; G¨ul, A.; Bekaro˘glu, ¨O. Polyhedron 1997, 16, 1877–1883.
- G¨urek, A. G.; Bekaro˘glu, ¨O. J. Porphyrins Phthalocaynines 1997, 1, 227–237.
- Bayır, A. Z.; Hamuryudan, E.; G¨urek, A. G.; Bekaro˘glu, ¨O. J. Porphyrins Phthalocyanines 1997, 1, 349–353.
- Kandaz, M.; Bekaro˘glu, ¨O. Chem. Ber. 1997, 130, 1833–1836.
- Ozkaya, A. R.; Yılmaz, ˙I.; Bekaro˘glu, ¨O. J. Porphyrins Phthalocyanines 1998, 2, 483–492. ¨
- ˙Ion, R. M.; Ko¸cak, M.; Bekaro˘glu, ¨O. Prog. Catal. 1998, 2, 113–118.
- Avcıata, U.; Bozdo˘gan, A. E.; Ko¸cak, M.; G¨ul, A.; Okur, A. ˙I.; Bekaro˘glu, ¨O.Monatsh. Chem. 1999, 130, 283–293.
- Hamuryudan, E.; Bayır, Z. A.; Bekaro˘glu, ¨O. Dyes Pigm. 1999, 43, 77–81.
- Kandaz, M.; Bekaro˘glu, ¨O. J. Porphyrins Phthalocyanines 1999, 3, 339–345.
- ˙Ion, R. M.; Yılmaz, ˙I.; Bekaro˘glu, ¨O. J. Serb. Chem. Soc. 1999, 64, 453–462.
- Merey, S¸.; Bekaro˘glu, ¨O. Dalton Trans. 1999, 4503–4510.
- Kandaz, M.; Yılmaz, ˙I.; Bekaro˘glu, ¨O. Polyhedron 2000, 19, 115–121.
- Bekaro˘glu, ¨O. J. Porhyrins Phthalocyanines 2000, 4, 465–473. ¨
- Ozkaya, A. R.; Hamuryudan, E.; Bayır, Z. A.; Bekaro˘ O. J. Porphyrins Phthalocyanines 2000, 4, 689–697.
- G¨ursoy, S; Bayır, Z. A.; Hamuryudan, E.; Bekaro˘glu, ¨O. Monatsh. Chem.2000, 131, 287–292.
- A˘gırta¸s, S.; Ion, R. M.; Bekaro˘glu, ¨O. Mat. Science Eng. 2000, 7, 105–110.
- G¨ursoy, S.; Cihan, A.; Ko¸cak, M. B.; Bekaro˘glu, ¨O. Monatsh. Chem. 2001,132, 813–819.
- Altındal, A.; ¨Ozt¨urk, Z. Z.; Dabak, S.; Bekaro˘glu, ¨O. Sens. Actuators Chem. B 2001, 77, 389–394.
- A˘gırta¸s, S.; Bekaro˘glu, ¨O. J. Porphyrins Phthalocyanines 2001, 5, 717–723.
- Abdurrahmano˘glu, S¸.; Altındal, A.; ¨Ozkaya, A. R.; Bulut, M.; Bekaro˘glu, ¨O. Chem. Commun. 2004, 2096–2097.
- Abdurrahmano˘glu, S¸.; ¨Ozkaya, A. R.; Bulut, M.; Bekaro˘glu, ¨O. Dalton Trans.2004, 4022–4029.
- Altındal, A.; Abdurrahmano˘glu, S¸.; Bulut, M.; Bekaro˘glu, ¨O. Synth. Met. 2005, 150, 181–187.
- Bekaro˘glu, ¨O. Structure Bonding (Functional Phthalocyanine Molecular Materials) 2010, 135, 105–136 and litera- ture given therein.
- G¨ursoy, S.; Ko¸cak, M.; Cihan, A., G¨ul, A.; Bekaro˘glu, ¨O. Transition Met. Chem. 2000, 25, 474–477.
- Tolbin, A. Y.; Ivanov, A. V.; Tomilova, L. G.; Zefirov, N. S. Mendelev Commun.2002, 12, 96–97.
- Tolbin, A. Y.; Ivanov, A. V.; Tomilova, L. G.; Zefirov, N. S. J. PorphyrinsPhthalocyanines 2003, 7, 162–167.
- Ceyhan, T.; Altındal, A.; ¨Ozkaya, A. R.; Erbil, M. K.; Salih, B.; Bekaro˘glu, ¨O. ChemCommun. 2006, 320–322.
- Ceyhan, T.; Altındal, A.; ¨Ozkaya, A. R.; Erbil, M. K.; C¸ elikbı¸cak, ¨O.; Salih, B.; Bekaro˘glu, ¨O. Polyhedron 2007, 26, 4239–4249.
- Ceyhan, T.; Altındal, A.; ¨Ozkaya, A. R.; Salih, B.; Erbil, M. K.; Bekaro˘glu, ¨O.J. Porphyrins Phthalocyanines 2007, 11, 625–634.
- Y¨uksel, H.; Ceyhan, T.; Ba˘gcı, F.; Ya˘glıo˘glu, H. G.; Elmalı, A.; Bekaro˘glu, ¨O. Opt. Commun. 2008, 281, 3897–3901.
- Odaba¸s, Z.; Altındal, A.; ¨Ozkaya, A. R.; Bulut, M.; Salih, B.; Bekaro˘glu, ¨O.Polyhedron 2007, 26, 695–707.
- Ceyhan, T.; ¨Ozda˘g, M. A.; Salih, B.; Erbil, M. K.; Elmalı, A.; ¨Ozkaya, A. R.;Bekaro˘glu, ¨O. Eur. J. Inorg. Chem. 2008, 4943–4950.
- De la Torre, G.; Vazquez, P.; Lopez, F. A.; Torres, T. Chem. Rev. 2004, 104, 3723–3750.
- Ceyhan, T.; Y¨uksel, M.; Ya˘glıo˘glu, H. G.; Salih, B.; Erbil, M. K.; Elmali, A.; Bekaro˘glu, ¨O. Dalton Trans. 2008, 2407–2413.
- Ceyhan, T.; Altındal, A.; ¨Ozkaya, A. R.; Salih, B.; Bekaro˘glu, ¨O. Dalton Trans.2009, 10318–10329.
- Ceyhan, T.; Altındal, A.; ¨Ozkaya, A. R.; Salih, B.; Bekaro˘glu, ¨O. Dalton Trans.2010, 39, 9801–9814.
- A˘gırta¸s, M. S.; Altındal, A.; Salih, B.; Saydam, S.; Bekaro˘glu, ¨O. Dalton Trans.2011, 40, 3315–3324.
- Salan, ¨U.; Altındal, A.; ¨Ozkaya, A. R.; Salih, B.; Bekaro˘glu, ¨O. Dalton Trans.2012, 41, 5177–5187.
- Ko¸c, ˙I.; ¨Ozer, M.; ¨Ozkaya, A. R.; Bekaro˘glu, ¨O. Dalton Trans. 2009, 6368–6376.
- S¸eng¨ul, A.; Do˘gan, H. Z.; Altındal, A.; ¨Ozkaya, A. R.; Salih, B.; Bekaro˘glu, ¨O.Dalton Trans. 2012, 41, 7559–7572.
- Ermi¸s, E.; C¸ imen, Y.; Dumluda˘g, F.; ¨Ozkaya, A. R.; Salih, B.; Bekaro˘glu, ¨O.Polyhedron 2013, 49, 129–137.
- Samuel, M.; Menon, C. S.; Unnikrishnan, N. V. J. Phys. Condens. Matter. 2006, 18, 35.
- Colesniuc, C. N.; Biswas, R. R.; Hevia, S. A.; Balatsky, A. V.; Schuller, I. K. Phys.Rev. B 2011, 83, 085414.
- Yazıcı, A.; ¨Un¨u¸s, N.; Altındal, A.; Salih, B.; Bekaro˘glu, ¨O. Dalton Trans. 2011, 40, 3373–3779.
- Yazıcı, A.; ¨Ozkan, C.; Gezer, M. B.; Altındal, A.; Salih, B.; Bekaro˘glu, ¨O.Inorg. Chim. Acta 2013, 404, 40–48.
- Basak, A. S.; ¨Ozkaya, A. R.; Altındal, A.; Salih, B.; Seng¨ul, A.; Bekaro˘glu, ¨O.Dalton Trans. 2014, 43, 5858–5870.