History, development, and a new concept of phthalocyanines in Turkey

This paper reviews the history of phthalocyanines in Turkey. Phthalocyanines are chemical compounds that were accidently discovered nearly a century ago. The relevant research and articles have grown dramatically in Turkey since our first paper on them containing four [15]crown[5] published in 1986. The ball-type phthalocyanines were produced and published as a new concept in phthalocyanine chemistry for the first time by our group in Turkey in 2006. Unfortunately, with the exception of our work on this subject, almost no papers have been published in Turkey or in other countries since then. We strongly urge scientists to consider working on this new type of phthalocyanine, which shows interesting development potential in electrical, electrochemical, and photovoltaic applications as well as oxygen reduction for fuel cells.

History, development, and a new concept of phthalocyanines in Turkey

This paper reviews the history of phthalocyanines in Turkey. Phthalocyanines are chemical compounds that were accidently discovered nearly a century ago. The relevant research and articles have grown dramatically in Turkey since our first paper on them containing four [15]crown[5] published in 1986. The ball-type phthalocyanines were produced and published as a new concept in phthalocyanine chemistry for the first time by our group in Turkey in 2006. Unfortunately, with the exception of our work on this subject, almost no papers have been published in Turkey or in other countries since then. We strongly urge scientists to consider working on this new type of phthalocyanine, which shows interesting development potential in electrical, electrochemical, and photovoltaic applications as well as oxygen reduction for fuel cells.

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  • Hanack, M.; Heckmann, H.; Polley, R. Meth. Org. Chem.(houben-Weyl), Phthalocyanines and Related Compounds 1998, E9d, 717–846.
  • Koray, A. R.; Ahsen, V.; Bekaroglu, ¨O. J. Chem. Soc. Chem. Commun. 1986, 932–933.
  • Kobayashi, N.; Nishiyama, Y. J. Chem. Soc. Chem. Commun. 1986, 1462–1463.
  • Hendriks, O.; Sielcken, O. E.; Drenth, W.; Nolte, R. J. M. J. Chem. Soc. Chem.Commun. 1986, 1464–1465.
  • Sirlin, C.; Bosio, L.; Simon, J.; Ahsen, V.; Yılmazer, E.; Bekaro˘glu, ¨O. Chem. Phys. Lett. 1987, 139, 362–364.
  • Bardin, M.; Bertounesque, E.; Plichon, V.; Simon, J.; Ahsen, V.; Bekaro˘glu, ¨O. J. Electroanal. Chem. 1989, 271, 173–180.
  • Ahsen, V.; Yılmazer, E.; G¨ul, A.; Bekaro˘glu, ¨O. Macromol. Chem. Rapid. Commun. 1987, 8, 243–246.
  • Ahsen, V.; Yılmazer, E.; Erta¸s, M.; Bekaro˘glu, ¨O. Dalton Trans. 1988, 401–406.
  • Ahsen, V.; Yılmazer, E.; G¨urek, A.; G¨ul, A.; Bekaro˘glu, ¨O. Helv. Chim. Acta 1988, 71, 1616–1621.
  • Ahsen, V.; Yılmazer, E.; Bekaro˘glu, ¨O. Macromol. Chem. 1988, 189, 2533–2543.
  • Sarıg¨ul, S.; Bekaro˘glu, ¨O. Chem. Ber. 1989, 122, 291–292.
  • Ko¸cak, M.; Cihan, A.; Okur, A. ˙I.; Bekaro˘glu, ¨O. J. Chem. Soc. Chem. Commun. 1991, 577–578.
  • Musluo˘glu, E.; Ahsen, V.; G¨ul, A.; Bekaro˘glu, ¨O. Chem. Ber. 1991, 124, 2531–2536.
  • G¨urek, A.; Ahsen, V.; G¨ul, A.; Bekaro˘glu, ¨O. Dalton Trans. 1991, 3367–3371.
  • G¨um¨u¸s, G.; ¨Ozt¨urk, Z. Z.; Ahsen, V.; G¨ul, A.; Bekaro˘ O. Dalton Trans. 1992, 2485–2489.
  • Musluo˘glu, E.; G¨urek, A.; Ahsen, V.; G¨ul, A.; Bekaro˘glu, ¨O. Chem. Ber. 1992, 125, 2337–2339. ¨
  • Ozt¨urk, Z. Z.; Musluo˘glu, E.; Ahsen, V.; G¨ul. A.; Bekaro˘glu, ¨O. J. Mat. Sci. 1992, 27, 6183–6186. ¨
  • Ozt¨urk, Z. Z.; Altındal, A.; G¨urek, A.; Bekaro˘glu, ¨O. Synth. Met. 1992, 52, 291–297.
  • Tan, N.; Bekaro˘glu, ¨O. Kadırgan, F. J. Electroanal. Chem. 1994, 364, 251–256.
  • Ko¸cak, M.; G¨urek, A.; G¨ul, A.; Bekaro˘glu, ¨O. Chem. Ber. 1994, 127, 355-358.
  • Ko¸cak, M.; Okur, A. ˙I.; Bekaro˘glu, ¨O. Dalton Trans. 1994, 323–326.
  • G¨urol, ˙I.; Ahsen, V.; Bekaro˘glu, ¨O. Dalton Trans. 1994, 497–500.
  • G¨urek, A.; Bekaro˘glu, ¨O. Dalton Trans. 1994, 1419–1423.
  • Tan, N.; G¨urek, A.; Bekaro˘glu, ¨O.; Kadırgan, F. J. Electroanal. Chem. 1994, 374, 45–52.
  • Dabak, S.; G¨ul, A.; Bekaro˘glu, ¨O. Chem. Ber. 1994, 127, 200–2012.
  • G¨urek, A.; Bekaro˘glu, ¨O. Helv. Chim. Acta 1994, 77, 1616–1622.
  • Musluo˘glu, E.; Bekaro˘glu, ¨O. J. Chem. Res. (S) 1994, 420–421.
  • Ozkaya, A. R.; Okur, A. ˙I.; G¨ul, A.; Bekaro˘glu, ¨O. J. Coord. Chem. 1994, 33, 311– 318. ¨
  • Avcıata, U.; Bozdo˘gan, A. E.; Ko¸cak, M.; G¨ul, A.; Bekaro˘glu, ¨O. J. Coord. Chem. 1995, 35, 319–323.
  • Ozt¨urk, Z. Z.; Zhou, R.; Weimer, U.; Ahsen, V.; Bekaro˘glu, ¨O; G¨opel, W.Sens. Actuators B. 1995, 26–27, 208–212. ¨
  • Dabak, S.; G¨um¨u¸s, G.; G¨ul, A.; Bekaro˘glu, ¨O. J. Coord. Chem. 1996, 38, 287–293.
  • Yılmaz, ˙I.; Bekaro˘glu, ¨O. Chem. Ber. 1996, 129, 967–971.
  • Zhou, R.; Josse, F.; G¨opel, W.; ¨Ozt¨urk, Z. Z.; Bekaro˘glu, ¨O. Appl. Organomet.Chem. 1996, 10, 557–577.
  • Bekaro˘glu, ¨O. Appl. Organomet. Chem. 1996, 10, 605–622.
  • Dabak, S.; Bekaro˘glu, ¨O. New J. Chem. 1997, 21, 267–271.
  • G¨urek, A.; Bekaro˘glu, ¨O. J. Porphyrins Phthalocyanines 1997, 1, 67–76. ¨
  • Ozkaya, A. R.; G¨urek. A. G.; G¨ul, A.; Bekaro˘glu, ¨O. Polyhedron 1997, 16, 1877–1883.
  • G¨urek, A. G.; Bekaro˘glu, ¨O. J. Porphyrins Phthalocaynines 1997, 1, 227–237.
  • Bayır, A. Z.; Hamuryudan, E.; G¨urek, A. G.; Bekaro˘glu, ¨O. J. Porphyrins Phthalocyanines 1997, 1, 349–353.
  • Kandaz, M.; Bekaro˘glu, ¨O. Chem. Ber. 1997, 130, 1833–1836.
  • Ozkaya, A. R.; Yılmaz, ˙I.; Bekaro˘glu, ¨O. J. Porphyrins Phthalocyanines 1998, 2, 483–492. ¨
  • ˙Ion, R. M.; Ko¸cak, M.; Bekaro˘glu, ¨O. Prog. Catal. 1998, 2, 113–118.
  • Avcıata, U.; Bozdo˘gan, A. E.; Ko¸cak, M.; G¨ul, A.; Okur, A. ˙I.; Bekaro˘glu, ¨O.Monatsh. Chem. 1999, 130, 283–293.
  • Hamuryudan, E.; Bayır, Z. A.; Bekaro˘glu, ¨O. Dyes Pigm. 1999, 43, 77–81.
  • Kandaz, M.; Bekaro˘glu, ¨O. J. Porphyrins Phthalocyanines 1999, 3, 339–345.
  • ˙Ion, R. M.; Yılmaz, ˙I.; Bekaro˘glu, ¨O. J. Serb. Chem. Soc. 1999, 64, 453–462.
  • Merey, S¸.; Bekaro˘glu, ¨O. Dalton Trans. 1999, 4503–4510.
  • Kandaz, M.; Yılmaz, ˙I.; Bekaro˘glu, ¨O. Polyhedron 2000, 19, 115–121.
  • Bekaro˘glu, ¨O. J. Porhyrins Phthalocyanines 2000, 4, 465–473. ¨
  • Ozkaya, A. R.; Hamuryudan, E.; Bayır, Z. A.; Bekaro˘ O. J. Porphyrins Phthalocyanines 2000, 4, 689–697.
  • G¨ursoy, S; Bayır, Z. A.; Hamuryudan, E.; Bekaro˘glu, ¨O. Monatsh. Chem.2000, 131, 287–292.
  • A˘gırta¸s, S.; Ion, R. M.; Bekaro˘glu, ¨O. Mat. Science Eng. 2000, 7, 105–110.
  • G¨ursoy, S.; Cihan, A.; Ko¸cak, M. B.; Bekaro˘glu, ¨O. Monatsh. Chem. 2001,132, 813–819.
  • Altındal, A.; ¨Ozt¨urk, Z. Z.; Dabak, S.; Bekaro˘glu, ¨O. Sens. Actuators Chem. B 2001, 77, 389–394.
  • A˘gırta¸s, S.; Bekaro˘glu, ¨O. J. Porphyrins Phthalocyanines 2001, 5, 717–723.
  • Abdurrahmano˘glu, S¸.; Altındal, A.; ¨Ozkaya, A. R.; Bulut, M.; Bekaro˘glu, ¨O. Chem. Commun. 2004, 2096–2097.
  • Abdurrahmano˘glu, S¸.; ¨Ozkaya, A. R.; Bulut, M.; Bekaro˘glu, ¨O. Dalton Trans.2004, 4022–4029.
  • Altındal, A.; Abdurrahmano˘glu, S¸.; Bulut, M.; Bekaro˘glu, ¨O. Synth. Met. 2005, 150, 181–187.
  • Bekaro˘glu, ¨O. Structure Bonding (Functional Phthalocyanine Molecular Materials) 2010, 135, 105–136 and litera- ture given therein.
  • G¨ursoy, S.; Ko¸cak, M.; Cihan, A., G¨ul, A.; Bekaro˘glu, ¨O. Transition Met. Chem. 2000, 25, 474–477.
  • Tolbin, A. Y.; Ivanov, A. V.; Tomilova, L. G.; Zefirov, N. S. Mendelev Commun.2002, 12, 96–97.
  • Tolbin, A. Y.; Ivanov, A. V.; Tomilova, L. G.; Zefirov, N. S. J. PorphyrinsPhthalocyanines 2003, 7, 162–167.
  • Ceyhan, T.; Altındal, A.; ¨Ozkaya, A. R.; Erbil, M. K.; Salih, B.; Bekaro˘glu, ¨O. ChemCommun. 2006, 320–322.
  • Ceyhan, T.; Altındal, A.; ¨Ozkaya, A. R.; Erbil, M. K.; C¸ elikbı¸cak, ¨O.; Salih, B.; Bekaro˘glu, ¨O. Polyhedron 2007, 26, 4239–4249.
  • Ceyhan, T.; Altındal, A.; ¨Ozkaya, A. R.; Salih, B.; Erbil, M. K.; Bekaro˘glu, ¨O.J. Porphyrins Phthalocyanines 2007, 11, 625–634.
  • Y¨uksel, H.; Ceyhan, T.; Ba˘gcı, F.; Ya˘glıo˘glu, H. G.; Elmalı, A.; Bekaro˘glu, ¨O. Opt. Commun. 2008, 281, 3897–3901.
  • Odaba¸s, Z.; Altındal, A.; ¨Ozkaya, A. R.; Bulut, M.; Salih, B.; Bekaro˘glu, ¨O.Polyhedron 2007, 26, 695–707.
  • Ceyhan, T.; ¨Ozda˘g, M. A.; Salih, B.; Erbil, M. K.; Elmalı, A.; ¨Ozkaya, A. R.;Bekaro˘glu, ¨O. Eur. J. Inorg. Chem. 2008, 4943–4950.
  • De la Torre, G.; Vazquez, P.; Lopez, F. A.; Torres, T. Chem. Rev. 2004, 104, 3723–3750.
  • Ceyhan, T.; Y¨uksel, M.; Ya˘glıo˘glu, H. G.; Salih, B.; Erbil, M. K.; Elmali, A.; Bekaro˘glu, ¨O. Dalton Trans. 2008, 2407–2413.
  • Ceyhan, T.; Altındal, A.; ¨Ozkaya, A. R.; Salih, B.; Bekaro˘glu, ¨O. Dalton Trans.2009, 10318–10329.
  • Ceyhan, T.; Altındal, A.; ¨Ozkaya, A. R.; Salih, B.; Bekaro˘glu, ¨O. Dalton Trans.2010, 39, 9801–9814.
  • A˘gırta¸s, M. S.; Altındal, A.; Salih, B.; Saydam, S.; Bekaro˘glu, ¨O. Dalton Trans.2011, 40, 3315–3324.
  • Salan, ¨U.; Altındal, A.; ¨Ozkaya, A. R.; Salih, B.; Bekaro˘glu, ¨O. Dalton Trans.2012, 41, 5177–5187.
  • Ko¸c, ˙I.; ¨Ozer, M.; ¨Ozkaya, A. R.; Bekaro˘glu, ¨O. Dalton Trans. 2009, 6368–6376.
  • S¸eng¨ul, A.; Do˘gan, H. Z.; Altındal, A.; ¨Ozkaya, A. R.; Salih, B.; Bekaro˘glu, ¨O.Dalton Trans. 2012, 41, 7559–7572.
  • Ermi¸s, E.; C¸ imen, Y.; Dumluda˘g, F.; ¨Ozkaya, A. R.; Salih, B.; Bekaro˘glu, ¨O.Polyhedron 2013, 49, 129–137.
  • Samuel, M.; Menon, C. S.; Unnikrishnan, N. V. J. Phys. Condens. Matter. 2006, 18, 35.
  • Colesniuc, C. N.; Biswas, R. R.; Hevia, S. A.; Balatsky, A. V.; Schuller, I. K. Phys.Rev. B 2011, 83, 085414.
  • Yazıcı, A.; ¨Un¨u¸s, N.; Altındal, A.; Salih, B.; Bekaro˘glu, ¨O. Dalton Trans. 2011, 40, 3373–3779.
  • Yazıcı, A.; ¨Ozkan, C.; Gezer, M. B.; Altındal, A.; Salih, B.; Bekaro˘glu, ¨O.Inorg. Chim. Acta 2013, 404, 40–48.
  • Basak, A. S.; ¨Ozkaya, A. R.; Altındal, A.; Salih, B.; Seng¨ul, A.; Bekaro˘glu, ¨O.Dalton Trans. 2014, 43, 5858–5870.
Turkish Journal of Chemistry-Cover
  • ISSN: 1300-0527
  • Yayın Aralığı: Yılda 6 Sayı
  • Yayıncı: TÜBİTAK
Sayıdaki Diğer Makaleler

New soluble amidoamine substituted phthalocyanines: synthesis, characterization, and investigation of their solution properties

Senem ÇOLAK, Salih Zeki YILDIZ

N-bridged dimers of tetrapyrroles complexed by transition metals: syntheses, characterization methods, and uses as oxidation catalysts

Ümit İŞCİ, Fabienne DUMOULİN, Alexander B. SOROKİN, Vefa AHSEN

Water-soluble phthalocyanines containing azo dye; microwave-assisted synthesis and photochemical properties of ZnPcs

Cihan KANTAR, Emrah ATACI, Selami ŞAŞMAZ

Nature of second-order nonlinear optical response in phthalocyanine derivatives: a density functional theory study

Chiming WANG, Chao CHEN, Qingqi ZHANG, Dongdong QI, Jianzhuang JIANG

Microwave-assisted synthesis of novel nonperipherally substituted metallophthalocyanines bearing (7-(trifluoromethyl)quinolin-4-yl)oxy groups

Didem EVREN, Hacer Yasemin YENİLMEZ, Ayfer Kalkan BURAT

Diphenylethoxy-substituted metal-free and metallophthalocyanines as potential photosensitizer for photodynamic therapy: synthesis and photophysical and photochemical properties

Yusuf YILMAZ, Ali ERDOĞMUŞ, Muhammet Kasım ŞENER

Synthesis and characterization of tetra-substituted titanium(IV) phthalocyanines with axial ligand

Deniz Kutlu TARAKCI, İlke GÜROL

TD-DFT calculations and MCD spectroscopy of porphyrin and phthalocyanine analogues: rational design of photosensitizers for PDT and NIR region sensor applications

John MACK, Martijn WILDERVANCK, Tebello NYOKONG

Synthesis and characterization of novel 2-{[2-(dimethylamino)ethyl](methyl)amino} ethoxy-substituted metallophthalocyanines

Hilal ZENGİN, Hacer Yasemin YENİLMEZ, Ayfer Kalkan BURAT, Zehra Altuntaş BAYIR

History, development, and a new concept of phthalocyanines in Turkey

Özer BEKAROĞLU