Yavuz TAŞKESENLİGİL, Metin BALCI, Ferhan TÜMER, Cavit KAZAZ

2221

An investigation of the formation mechanism of allene or alkyne in the 6, 7-benzobicyclo (3.2.1) octane system by deuterium labeling experiments

An investigation of the formation mechanism of allene or alkyne in the 6, 7-benzobicyclo (3.2.1) octane system by deuterium labeling experiments

In order to reveal the real intermediate in the base-promoted reaction of 1,3-bromo-4,4-dideuterio-6,7-benzobicyclo[3.2.1]octa-2,6-diene 10 was synthesized and its HBr elimination reaction studied. Reaction of 10 with potassium tert-butoxide yielded butoxyl ether 18 in which proton-deuterium exchange has occured.
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Turkish Journal of Chemistry-Cover
  • ISSN: 1300-0527
  • Yayın Aralığı: Yılda 6 Sayı
  • Yayıncı: TÜBİTAK
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