The effects of raw and leached cocoa bean hulls were investigated as a fat replacer in pound cakes. This substitution was applied for raw (RCBH) and leached (LCBH) grinded cacao bean hulls/oil in the ratios of 30/70 (30%), 40/60 (40%) and 50/50 (50%). Chemical, physical and sensorial properties of raw and leached cocoa bean hulls were studied as well as fat substituted cakes. Ash, protein, total phenolic compounds and total antioxidant activity decreased with leaching process. Crude fiber content increased in fat substituted cakes compared to control cake. RCBH cakes showed higher bioactive components than LCBH cakes because of raw cocoa bean hulls were higher phenolic compounds and total antioxidant activities than leached cocoa bean hulls. The results showed that 50% of vegetable oil replacement with raw cocoa bean hull in cake formulation significantly improved chemical, physical and sensory properties of fat substituted cakes.
___
AACC. 2000a. International. Approved methods of analysis. Method 44-40. 01. Moisture Modified Vacuum-Oven Method (10th ed.). St. Paul, MN: AACC International
AACC. 2000b. American Association of Cereal Chemists. Approved methods of analysis, Method 10-05. Rapeseed Displacement Method, 10th ed., St. Paul, MN, ABD.
AACC. 2000c. International. Approved methods of analysis. Method 74-09. 01-04. Bread Firmness by Universal Testing Machine. (10th Ed.). St. Paul, MN: AACC International
Altuğ T. 1987. Toz kakaoda tağşiş saptama metodları üzerine, PhD. Thesis (Supervisor: Dr. Meral Gönül), Ege University Engineering Faculty, Food Engineering Department, 76 p.
Altuğ T, Elmacı Y. 2005. Gıdalarda Duyusal Değerlendirme, Meta Basım Matbaacılık Hizmetleri, 61-90 s.
AOAC. 2007. Association of Official Analytical Chemist. 2007. Official Methods of Analysis, 18th ed. MD, USA.
Arlorio M, Coisson JD, Restani P, Martelli A. 2001. Characterization of pectins and some secondary compounds from Theobroma cacao hulls. Journal Food Science, 66(5), 653-656.
Arlorio M, Coȉsson JD, Travaglia F, Varsaldi F, Miglio G, Lombardi G, Martelli A. 2005. Antioxidant and biological activity of phenolic pigments from Theobroma cocoa hulls extracted with supercritical CO2, Food Research International 38, 1009 – 1014.
Balestra F, Cocci E, Pinnavaia G, Romani, S. 2011. Evaluation of antioxidant, rheological and sensorial properties of wheat flour dough and bread containing ginger powder, LWT - Food Science and Technology, Volume 44, Issue 3, April 2011, Pages 700–705.
Beckett ST. 2008. The science of chocolate (Second). Cambridge: RSCPublishing.
Beckett ST. 2009. Industrial chocolate manufacture and use (4a ed.). Wiley-Blackwell.
Bruna C, Eichholz I, Rohn S, Kroh LW, Huyskens – Keil S. 2009. Bioactive compounds and antioxidant activity of cocoa hulls (Theobroma cocoa L.) from different origins, Journal of Applied Botany and Food Quality, 83: 9–13.
Chaplin MF. 2003. Fiber and water binding, Proceedings of the Nutrition Society, 62: 223–227.
Collar C, Rosell CM, Muguerza B, Moulay L. 2009. Breadmaking performance and keeping behavior of cocoasoluble fiber-enriched wheat breads. Food Science and Technology International, 15(1): 79-87.
Fernandes SS, Salas-Mellado MM. 2017. Addition of chia seed mucilage for reduction of fat content in bread and cakes. Food Chemistry, 227: 237–244.
Garcia–Serna E, Martinez–Saez N, Mesias M, Morales JF. Dolores del Castillo M. 2014. Use of Coffee Silverskin and Stevia to Improve the Formulation of Biscuits, Polish Journal of Food and Nutrition Sciences, Vol. 64, No. 4, pp. 243–251, http://journal.pan.olsztyn.pl
Heimler D, Vignolini P, Dini MG, Vincieri F, Romani A. 2005. Antiradical Activity and Polyphenol Composition of Local Brassicaceae Edible Varieties, Food Chemistry, 82: 1511- 1517.
ICO. 2016. International Cocoa Organization Production of cocoa beans. ICCO Quarterly Bulletin of Cocoa Statistics, XLII.
Kongor JE, Hinneha M, Van de Walle D, Afoakwa OE, Boeckx, P, Dewettinck K. 2016. Factors influencing quality variation in cocoa (Theobroma cacao) bean flavour profile — A review, Food Research International, 82: 44–52.
Kopp GM, Pearson SM, Shah M. 2011. Process for milling cocoa shells, http://www.google.com/patents/US8067051 (Date accessed: 05.02.2017).
Lecumberri E, Mateos R, Izquierdo-Pulido M, Rupérez P, Goya, L, Bravo L. 2007. Dietary fiber composition, antioxidant capacity and physico-chemical properties of a fiber-rich product from cocoa (Theobroma cacao L.), Food Chemistry, 104: 948–954.
Martín-Cabrejas MA, Valiente C, Esteban RM, Mollá E. 1994. Cocoa hull: A potential source of dietary fiber. Journal of the Science of Food and Agriculture, 66: 307-311.
Martínez R, Torres P, Meneses MA, Figueroa JG, Pérez-Álvarez JA, Viuda-Martos M. 2012. Chemical, technological and in vitro antioxidant properties of cocoa (Theobroma cacao L.) co-products. Food Research International, 49: 39–45.
Martínez-Cervera S, Salvador A, Muguerza B, Moulay L, Fiszman SM. 2011. Cocoa fiber and its application as a fat replacer in chocolate muffins, Food Science and Technology, 44: 729-736.
Okiyama DCG, Navarro SLB, Rodrigues CEC. 2017. Cocoa shell and its compounds: Applications in the food industry. Trends in Food Science & Technology, 63: 103-112
Prasad M, Simmons P, Maher MJ. 2004. Release characteristics of organic fertilizers. Acta Horticulturae, 644: 163-170.
Rapisarda P, Tomaino A, Cascio R, Bonina F, De Pasquale F, Saija A. 1999. Antioxidant effectiveness as influenced by phenolic content of fresh orange juice. J. Agric. Food Chem., 47: 4718-4723.
Saija A, Trombetta D, Tomaino A, Lo Cascio R, Princi P, Uccella N, Bonina F, Castelli F. 1998. ‘In vitro’ evaluation of the antioxidant activity and bio membrane interaction of the plant phenols oleuropein and hydroxytyrosol, Int. J. Pharm., 166: 123-133.
Skerget M, Kotnik P, Hadolin M, Hras AR, Simonic M, Knez Z. 2005. Phenols, proanthocyanidins, flavones and flavonols in some plant materials and their antioxidant activities, Food Chemistry, 89: 191-198.
Yang J, Xiao A, Wang C. 2014. Novel development and characterization of dietary fiber from yellow soybean hulls, Food Chemistry, 161: 367–375.