Tekreaktörde hidrotermal yöntemlerle zno-ag kaplanmış pet dokusuz yüzeylerin hazırlanması ve karakterizasyonu
Surface functionalization of polyethylene terephthalate (PET) nonwoven was achieved by one-pot hydrothermal synthesis of zinc oxide (ZnO) and silver (Ag). The surface morphology and properties of the ZnO-Ag composites coated PET nonwoven were characterized by scanning electron microscope (SEM), X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FT-IR), respectively. The SEM observations revealed the formation of nanostructured deposition on the fiber surfaces. XRD patterns confirmed the deposition of ZnO-Ag composites on the surface of the PET nonwoven. The ZnO-Ag composites coated PET nonwoven demonstrated a remarkable improvement in ultraviolet shielding. The antibacterial properties of the ZnO-Ag composites coated PET nonwoven were also investigated and the experimental results indicated that there was about 94.5% reduction of Escherichia coli and 92.4% reduction of Staphylococcus aureus between the Zno-Ag composites coated PET nonwoven and control samples.
Preparation and characterization of pet nonwoven coated with zno-ag by one-pot hydrothermal techniques
Surface functionalization of polyethylene terephthalate (PET) nonwoven was achieved by one-pot hydrothermal synthesis of zinc oxide (ZnO) and silver (Ag). The surface morphology and properties of the ZnO-Ag composites coated PET nonwoven were characterized by scanning electron microscope (SEM), X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FT-IR), respectively. The SEM observations revealed the formation of nanostructured deposition on the fiber surfaces. XRD patterns confirmed the deposition of ZnO-Ag composites on the surface of the PET nonwoven. The ZnO-Ag composites coated PET nonwoven demonstrated a remarkable improvement in ultraviolet shielding. The antibacterial properties of the ZnO-Ag composites coated PET nonwoven were also investigated and the experimental results indicated that there was about 94.5% reduction of Escherichia coli and 92.4% reduction of Staphylococcus aureus between the Zno-Ag composites coated PET nonwoven and control samples.
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- 1.L.H. Yu, S. Zhang, W. Liu, X.J. Zhu, X.P. Chen, X.S. Chen., 2010, Improving the flame retardancy of PET fabric by photo-induced grafting, Polymer Degradation and Stability, Vol: 95, pp: 1934-1942.
- 2.Kyung-Hye Jung, Man-Woo Huh, Wan Meng, Jiang Yuan, Seok Hee Hyun, Jung-Sook Bae, SamuelM. Hudson, Inn-Kyu Kang., 2007 Preparation and Antibacterial Activity of PET/Chitosan Nanofibrous Mats Using an Electrospinning Technique, Journal of Applied Polymer Science, Vol: 105,pp: 2816 2823
- 3.J.H. Lin, C.W. Lou, C.H. Lei, C.Y. Lin., 2006, Processing conditions of abrasion and heat resistance for hybrid needle-punched nonwoven bag filters, Composites:PartA, Vol: 37, pp:3137
- 4.Laurent Ducoroy, Maryse Bacquet, Bernard Martel, Michel Morcellet., 2008, Removal of heavy metals from aqueous media by cationex change nonwoven PET coated with b-cyclodextrin-polycarboxylic moieties, Reactive & Functional Polymers, Vol: 68, pp: 594600.
- 5.Y. Chen, X.L. Xu, G.H. Zhang, H. Xue, S.Y. Ma., 2009, A comparative study of the microstructures and optical properties of Cu- and Ag-doped ZnO thin films, Physica B, Vol:404, pp:36453649
- 6.Feng Zhang, Yu Wang, Hanjun Chen, Wenlin Feng., 2010, Effects of Ag particles on sintering and electrical properties of ZnO-based varistor, Materials Research Bulletin, Vol: 45, pp:974978.
- 7.Jian Xu, Yonggang Chang, Yunyan Zhang, Shiyu Ma, Yi Qu, Chengtian Xu., 2008, Effect of silver ions on the structure of ZnO and photocatalytic performance of Ag/ZnO composites, Applied Surface Science, Vol: 255, pp:19961999.
- 8.Changdong Gu,Chun Cheng, Haiyou Huang, Tailun Wong, Ning Wang, Tong-Yi Zhang., 2009, Growth and Photocatalytic Activity of Dendrite-like ZnO@Ag Heterostructure Nanocrystals, Crystal Growth&Design, Vol: 9, pp:32783285. 9.Shu-Ting Kuo, Wei-Hsing Tuan, Jay Shieh, Sea-Fue Wang. Effect of Ag on the microstructure and electrical properties of ZnO. Journal of the European Ceramic Society, Vol: 27 (2007) 45214527.
- 10. D.R. Sahu. Studies on the properties of sputter-deposited Ag-doped ZnO films. Microelectronics Journal, Vol: 38(2007)12521256.
- 11. Boen Houng, Cheng-Ju Huang., 2006, Structure and properties of Ag embedded aluminum doped ZnO nanocomposite thin films prepared through a sol gel process, Surface and Coatings Technology, Vol: 201, pp:3188-3192.
- 12. Weiwei Lu, Shuyan Gao, Jianji Wang., 2008, One-Pot Synthesis of Ag/ZnO Self-Assembled 3D Hollow Microspheres with Enhanced Photocatalytic Performance, J. Phys. Chem. C, Vol: 112, pp:1679216800.
- 13. Yunyan Zhang, Jin Mu., 2007, One-pot synthesis, photoluminescence, and photocatalysis of Ag/ZnO composites, Journal of Colloid and Interface Science, Vol: 309, pp:478484.
- 14. Lu Liu, Ming Ge, Huajie Liu, Changsheng Guo, Yuqiu Wang, Zhen Zhou., 2009, Controlled synthesis of ZnO with adjustable morphologies from nanosheets to microspheres, Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol: 348, pp:124129.
- 15. Bi Xu, Zaisheng Cai., 2008, Fabrication of a super hydrophobic ZnO nanorod array film on cotton fabrics Via a chemical route and hydrophobic modification, Applied Surface Science, Vol: 254, pp: 58995904.