Türkiye’de Bir Boya Endüstrisi Atıksu Arıtma Tesisi için Çevre Dostu Teknolojinin Araştırılması

Boya üretim prosesi; Türkiye’de birçok olumsuz çevresel etkiye sahiptir. Bu etkilerden birisi atıksu arıtımıdır. Boya endüstrisi atıksuyu, yüksek miktarda zehirli kimyasal maddeleri, biyolojik olarak parçalanmayan bileşikleri, pigment ve mikroorganizmaları içerir. Sonuç olarak atıksudan; renk, mikroorganizma ve organik madde (KOI) giderimi için ileri bir arıtma prosesine ihtiyaç duyulmaktadır. Atıksuyun yüksek organik madde içeriği, yeterli arıtılmaması durumunda; alıcı ortamda yaşayan organizmalar ve ekosistem için ciddi çevre sorunlarına ve kirliliğe neden olur. Bu kapsamda, uygulanacak arıtma prosesi, çevreye en az zarar verecek şekilde seçilmelidir. Bu çalışmada, Türkiye’deki bir boya endüstrisi atıksu arıtma tesisi için; elektrokoagülasyon (Senaryo-1), Fenton prosesi (Senaryo- 2) ve membran distilasyonu (Senaryo-3) içeren üç adet arıtım senaryosu oluşturulmuştur. Üç senaryo için, Fine-Kinney yöntemiyle çevresel etki değerlendirme gerçekleştirilmiştir. Yatırım yapılmadan önce, en çevre dostu teknolojinin seçilmesi amaçlanmıştır. Değerlendirme sonuçları, Senaryo- 2’nin, 556 toplam etki puanıyla en düşük çevresel etkiye sahip olduğunu göstermektedir. Senaryo- 1 en yüksek toplam etki puanına sahiptir (756). Senaryo 3’e ait toplam etki puanı 637’dir. Değerlendirme sonuçlarına göre, Fenton Prosesi, Türkiye’deki bir boya endüstrisi atıksu arıtma tesisi için en çevre dostu arıtma teknolojisidir.

Investigation of Environmental-friendly Technology for a Paint Industry Wastewater Plant in Turkey

Paint manufacturing process has several unfavorable aspects to theenvironment in Turkey. One of these impacts is wastewater treatment. Paintwastewater contains huge amounts of toxic chemical substances, bio refractorycompounds, pigments and microorganisms. So, advanced treatmentrequirement is available to dispose of colour, microorganisms and chemicaloxygen demand (COD). The high organic content of wastewater causes seriousenvironmental challenges and contamination for the living organisms and theecosystem in the receiver media unless it is treated adequately. In this context,the treatment process to be implemented should be preferred in such a way asto give the least damage to the environment. In this study, three treatmentscenarios that contain electrocoagulation (Scenario-1), Fenton process(Scenario-2) and membrane distillation (Scenario-3) have been created forwastewater treatment facility of a paint industry in Turkey. For three scenarios,environmental impact assessment has been carried out with Fine-Kinneymethod. It is aimed to choose best environmental technology beforeinvestment. The evaluation results revealed that Scenario-2 has the lessenvironmental impacts that total impact value is 556. Scenario-1 has thehighest total impact value as 756, relatively. Total impact value related toScenario-3 is 637. According to the evaluation results, Fenton process is thebest environmental-friendly treatment technology for wastewater treatment ofa paint industry in Turkey.

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  • [1] Yao, J., Wen D, et al. 2016. Zero Discharge Process for Dyeing Wastewater Treatment. Journal of Water Process Engineering, 11 (2016), 98-103.
  • [2] Lotito, A.M., De S.M., et al. 2014. Textile Wastewater Treatment: Aerobic Granular Sludge vs Activated Sludge Systems. Water Research, 54 (2014), 337–346.
  • [3] Libra, J.A., Borchert, M., et al. 2004. Two Stage Biological Treatment of a Diazo Reactive Textile Dye and the Fate of the Dye Metabolites. Chemosphere, 56(2004), 167–180.
  • [4] Yang, C., Li, L., et al. 2015. Advanced Treatment of Textile Dyeing Secondary Effluent Using Magnetic Anion Exchange Resin and its Effect Onorganic Fouling in Subsequent RO Membrane. Journal of Hazardous Materials, 284(2015), 50– 57.
  • [5] Akyol, A. 2012. Treatment of Paint Manufacturing Wastewater by Electrocoagulation. Desalination, 285(2012), 91- 99.
  • [6] Zhang, J., Giorno, L., Drioli, E. 2006. Study of a Hybrid Process Combining PACs and Membrane Operations for Antibiotic Wastewater Treatment. Desalination, 194(2006), 101–107.
  • [7] Akyol, A., Yatmaz, H.C., Bayramoglu, M. 2004. Photocatalytic Decolourization of Remazol Red RR in Aqueous ZnO Suspensions. Applied Catalysis B: Environmental, 54(2004), 19–24.
  • [8] Fu, J., Kyzas, G.Z. 2014. Wet Air Oxidation for the Decolorization of Dye Wastewater: An overview of the Last Two Decades. Chinese Journal of Catalysis, 35(2014), 1–7.
  • [9] Wu, H.F., Wang, S.H., Kong, H.L., Liu, T.T., Xia, M.F., 2007. Performance of Combined Process of Anoxic Baffled Reactor Biological Contact Oxidation Treating Printing and Dyeing Wastewater. Bioresource Technology 98 (2007), 1501-1504.
  • [10] APHA. 1995. Standard methods for the examination of water and wastewater, 19th ed. American Public Health Association/American Water Works Association/Water Environment Federation, Washington, DC, USA.
  • [11] Toro, J., Requena, I., Duarte, O., Zamorano, M.A. 2013. Qualitative Method Proposal to Improve Environmental Impact Assessment. Environmental Impact Assessment Review 43(2013), 9–20.
  • [12] Wathern, P. 1994. An introductory guide to EIA. In:Wathern, P. (Ed.), Environmental Impact Assessment: Theory and Practice. Biddles Ltd, Guilford and King's Lynn, London, 353 p.
  • [13] Wood, C.H. 2003. Environmental Impact Assessment: A Comparative Review. 2nd ed. Prentice Hall, London, 430 p.
  • [14] Bilgin, A. 2015. Analysis of the Environmental Impact Assessment (EIA) Directive and the EIA decision in Turkey. Environ. Environmental Impact Assessment Review, 53(2015), 40-51.
  • [15] Çakmak, E. 2014. Atölye Tipi Üretim Yapan Sanayi İşletmelerinde İş Sağlığı ve Güvenliği, Reseach Thesis, ÇASGEM, Ankara.
  • [16] Kinney, G.F., Wiruth, A.D. 1976. Practical Risk Analysis for Safety Management, Technical Report 5865, CA: Naval Weapons Center, 27, California, 27 p.
  • [17] Oturakçı, M., Dağsuyu, C., Kokangül, A. 2015. A New Approach to Fine Kinney Method and an Implementation Study. The Journal of Operations Research, Statistics, Econometrics and Management Information Systems alphanumeric journal, 3 (2015), 83-92.
  • [18] Krithika, D., Philip, L. 2016. Treatment of Wastewater from Water-based Paint Industries Using Submerged Attached Growth Reactor. International Biodeterioration & Biodegradation 107 (2016),31-41.
  • [19] Holt, P.K., Barton, G.W., Mitchell, C.A. 2005. The Future for Electrocoagulation as a Localized Water Treatment Technology. Chemosphere, 59(2005), 355–367.
  • [20] Kobya, M., Hiz, H. et al. 2006. Treatment of Potato Chips Manufacturing Wastewater by Electrocoagulation. Desalination, 190(2006), 201–211.
  • [21] Daneshvar, N., Sorkhabi, H.A., Kasiri, M.B. 2004. Decolorization of Dye Solution Containing Acid Red 14 by Electrocoagulation with a Comparative Investigation of Different Electrode Connections. Journal of Hazardous Materials, 112(2004), 55–62.
  • [22] Vidal, J., Villegas, L. et al. 2016. Removal of Acid Black 194 Dye from Water by Electrocoagulation with Aluminum Anode. Journal of Environmental Science and Health, Part A, 51(2016), 289–296.
  • [23] Kobya, M., Demirbas, E., Akyol, A. 2009. Electrochemical Treatment and Operating Cost Analysis of Textile Wastewater Using Sacrificial Iron Electrodes. Water Science and Technology, 60(2009), 2261–2270.
  • [24] Aoudj, S., Khelifa, A. et al. 2010. Electrocoagulation Process Applied to Wastewater Containing Dyes from Textile Industry. Chemical Engineering and Processing, 49(2010), 1176–1182.
  • [25] Fajardoa, A.S., Martins, R.C. et al. 2017. Dye Wastewaters Treatment Using Batch and Recirculation Flow Electrocoagulation Systems. Journal of Electroanalytical Chemistry, 801(2017), 30–37.
  • [26] Kılıç, Y.M., Kestioğlu, K. 2008. Investigation of Applicability of Advanced Oxidation Processes for Industrial Wastewater Treatment. Journal of Uludağ University Engineering Faculty, 13(2008), 67-80.
  • [27] Kurt, U., Avsar, Y., Gonullu, M.T. 2006. Treatability of Water-based Paint Wastewater with Fenton Process in Different Reactor Types. Chemosphere, 64(2006), 1536–1540.
  • [28] Szpyrkowicz, L., Juzzolino, C., Santosh, N.K. 2001. A Comparative Study on Oxidation of Disperse Dyes by Electrochemical Process, Ozone, Hypochlorite and Fenton Reagent. Water Research, 35(2001), 2129–2136.
  • [29] Neamtu, M., Yediler, A. et al. 2004. Decolorization of Disperse Red 354 Azo Dye in Water by Several Oxidation Processes—A Comparative Study. Dyes and Pigments, 60(2004), 61–68.
  • [30] Kang, S.F., Liao, C.H., Hung, H.P. 1999. Peroxidation Treatment of Dye Manufacturing Wastewater in the Presence of Ultraviolet Light and Ferrous Ions. Journal of Hazardous Materials B, 65(1999), 317–333.
  • [31] An, A.K., Guo, J. 2016. High Flux and Antifouling Properties of Negatively Charged Membrane for Dyeing Wastewater Treatment by Membrane Distillation. Water Research, 103(2016), 362- 371.
  • [32] Dasgupta, J., Sikder, J. et al. 2015. Remediation of Textile Effluents by Membrane Based Treatment Techniques: A state of the Art Review. Journal of Environmental Management, 147(2015), 55-72.
  • [33] Tang, C., Chen, V. 2002. Nanofiltration of Textile Wastewater for Water Reuse. Desalination, 143(2002),11-20.
  • [34] Alcaina-Miranda, M.I., Barredo-Damas, S. et al. 2009. Nanofiltration as a Final Step Towards Textile Wastewater Reclamation. Desalination, 240(2009), 290-297.
  • [35] Aouni, A., Fersi, C. et al. 2012. Reactive Dyes Rejection and Textile Effluent Treatment Study Using Ultrafiltration and Nanofiltration Processes. Desalination, 297(2012), 87-96.
  • [36] Han, R., Zhang, S. et al. 2009. Treating Sulphur Black Dye Wastewater with Quaternized Poly (phthalazinone ether sulfone ketone) Nanofiltration Membranes. Separation and Purification Technology, 67(2009), 26-30.
  • [37] Mo, J.H., Lee, Y. et al. 2008. Treatment of Dye Aqueous Solutions Using Nanofiltration Polyamide Composite Membranes for the Dye Wastewater Reuse. Dye Pigment, 76(2008), 429- 434.
Süleyman Demirel Üniversitesi Fen Bilimleri Enstitüsü Dergisi-Cover
  • ISSN: 1300-7688
  • Yayın Aralığı: Yılda 3 Sayı
  • Başlangıç: 1995
  • Yayıncı: Süleyman Demirel Üniversitesi