IMPACTS OF NANOSCALE INCLUSIONS ON FIRE RETARDANCY, THERMAL STABILITY, AND MECHANICAL PROPERTIES OF POLYMERIC PVC NANOCOMPOSITES

A number of different nanoscale inclusions including nanoclay, nanotalc, and graphene were incorporated with polyvinyl chloride (PVC), dispersed in N,N-Dimethylacetmide (DMAC) and cast in rectangular aluminum (Al) molds prior to the testing. The fire retardancy, thermal stability, and mechanical properties of the PVC nanocomposites were determined using the ASTM UL 94 standard, thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), and microtensile test units. Surface morphology studies of the resultant materials were also carried out using scanning electron microscopy (SEM). Test results showed that the fire retardancy, thermal stability, and mechanical properties of the PVC nanocomposites were significantly enhanced in the presence of nanoscale inclusions. Among the inclusions, graphene had the major impact on improving the physical properties, which may be because of its higher thermal conductivity, mechanical strength, size, and shape. Polymers have a wide range of applications in daily life, but they are highly flammable and mechanically not stable for different applications. This study has shown that the weakness of the PVC could be significantly enhanced by incorporating nanoscale inclusions for various industrial purposes.

___

  • [1] R. Horrocks and D. Price, Fire Retardant Materials, Woodhead Publishing Limited, England, 2001.
  • [2] F. Laoutid, L. Bonnaud, M. Alexandre, J.-M. Lopez-Cuesta, and P. Dubois, “New Prospects in Flame Retardant Polymer Materials: From Fundamentals to Nanocomposites,” Materials Science and Engineering: R: Reports, 2009, Vol. 63(3), pp. 100–125.
  • [3] T. Hull, A. A. Stec, and S. Nazare, “Fire Retardant Effects of Polymer Nanocomposites,” Journal of Nanoscience and Nanotechnology, 2009, Vol. 9(7), pp. 4478–4486.
  • [4] Ghazinezami, A. Jabbarnia, S. Soltani, N. Nuraje, and R. Asmatulu, “Improving the Fire Retardancy of Polymeric Structures via Additions of Nanoclay and Graphene Nanoflakes,” The V International Workshop on Technology and New Materials for Industry, Environment and Health Protection, Issyk-Kul, Kyrgyzstan, September 16–18, 2013, 9 pages.
  • [5] M. Alexandre and P. Dubois, “Polymer-Layered Silicate Nanocomposites: Preparation, Properties and Uses of a New Class of Materials,” Materials Science and Engineering: R: Reports, 2000, Vol. 28(1), pp. 1–63.
  • [6] B.H. Cipiriano, T. Kashiwagi, S. R. Raghavan, Y. Yang, E. A. Grulke, K. Yamamoto, J. R. Sheilds, and J. F. Douglas, “Effects of Aspect Ratio of MWNT on the Flammability Properties of Polymer Nanocomposites,” Polymer, 2007, 48(20), pp. 6086–6096.
  • [7] A.Ghazinezami, “Fire Retardancy, Thermal Stability and Mechanical Properties of Polymeric Based Nanocomposites,” M.S. Thesis, Wichita State University, December, 2013.
  • [8] P. H. Nam, P. Maiti, M. Okamoto, T. Kotaka, N. Hasegawa, and A. Usuki, “A Hierarchical Structure and Properties of Intercalated Polypropylene/Clay Nanocomposites,” Polymer, 2001, Vol. 42(23), pp. 9633–9640.
  • [9] R. Verdejo, M. M. Bernal, L. J. Romasanta, and M. A. Lopez-Manchado, “Graphene Filled Polymer Nanocomposites,” Journal of Materials Chemistry, 2011, Vol. 21(10), pp. 3301–3310.
  • [10] Szentes, C. S. Varga, G. Horvath, Z. Konya, J. Szel, and A. Kukovecz, “Electrical Resistivity and Thermal Properties of Compatibilized Multi-Walled Carbon Nanotube/Polypropylene Composites,” eXPRESS Polymer Letters, 2012, Vol. 6(6), pp. 494–502.
  • [11] L. Wang, L. Zhang, and M. Tian, “Improved Polyvinylpyrrolidone (PVP)/Graphite Nanocomposites by Solution Compounding and Spray Drying,” Polymers for Advanced Technologies, 2012, Vol. 23(3), pp. 652–659.
  • [12] P. Estelle, S. Halelfadl, and T. Mare, “Thermal Conductivity of CNT Water based Nanofluids: Experminetal Trends and Models Overview,” Journal of Thermal Engineering, 2015, Vol. 1, pp. 381-390.
  • [13]W. S. Khan., R. Asmatulu., and M. Eltabey, “Electrical and Thermal Characterization of Electrospun PVP Nanocomposite Fibers,” Journal of Nanomaterials, 2013, Volume 2013, 9 pages.
  • [14] R. F. Zinati, M. R. Razfar, and H. Nazockdast, “Numerical and experimental investigation of FSP of PA 6/MWCNT composite,” Journal of Materials Processing Technology, 2014, Vol. 214, pp. 2300-2315. [15] S. Ramesh, G. B. Teh, R. Louh, Y. K. Hou, P. Y. Sin, and L. J. Yi, “Preparation and Characterization of Plasticized High Molecular Weight PVC-Based Polymer Electrolytes,” Indian Academy of Science, 2010, Vol. 35(1), pp. 87–95.
  • [16] M. Stephan, S. G Kumar, N. G. Renganathan, and M. A Kulandainathan, “Characterization of Poly(Vinylidene Fluoride–hexafluoropropylene) (PVdF–HFP) Electrolytes Complexed with Different Lithium Salts,” European Polymer Journal, 2005, Vol. 41, pp. 15–21.
  • [17] Hitachi High-Tech Dcience Corporation, Thermal Analysis of Polyvinyl Chloride, TA No. 65, 1995.
  • [18] M. Abu-Abdeen, “Static and Dynamic Mechanical Properties of Poly(Vinyl Chloride) Loaded with Aluminum Oxide Nanopowder,” Materials and Design, 2012, Vol. 33, pp. 523–528.
  • [19] W. B. Xu, Z. F. Zhou, M. L. Ge, and W. P. Pan, “Polyvinyl Chloride/Montmorillonite Nanocomposites: Glass Transition Temperature and Mechanical Properties,” Journal of Thermal Analysis and Calorimetry, 2004, Vol 78 (1), pp. 1–9.
  • [20] M. Polaskova, T. Sedlacek , A. Kharlamov, R. Pivokonsky, and P. Saha, “Polyvinylchloride Filled with Bismuth Oxychloride Powder,” Polymer Processing Society Conference,” Larnaca, Cyprus, 2009, p. 97–105.
  • [21] Chen, J.H., Gunes, F., Kim, B.H., and Lee, J.M. “Graphene and 2D Materials: From Synthesis to Applications,” Journal of Nanomaterials, 2016 (in press).
  • [22] B. Yin and M. Hakkarainen, “Flexible and Strong Ternary Blends of Poly(Vinyl Chloride), Poly(Butylene Adipate) and Nanoparticle-Plasticizers,” Material Chemistry and Physics, 2013, Vol.139(2-3) , pp.734–740.
  • [23] Liu, Y. F. Luo, Z. X. Jia, B. C. Zhong, S. Q. Li, B. C. Guo1, and D. M. Jia, “Enhancement of Mechanical Properties of Poly(Vinyl Chloride) with Polymethyl Methacrylate-grafted Halloysite Nanotube,” eXPRESS Polymer Letters, 2011, Vol.5(7), pp. 591–603.
  • [24] Ghazinezami, A. Jabbarnia, and R. Asmatulu, “Fire Retardancy of Polymeric Materials Incorporated with Nanoscale Inclusions,” ASME International Mechanical Engineering Congress and Exposition, San Diego, CA, November 15–21, 2013, 6 pages.
  • [25] M. Zhang, P. Ding, B. Qu, and A. Guan, “A new method to prepare flame retardant polymer composites,” Journal of Materials Processing Technology, 2012, Vol. 208, pp. 342-347. [26] A. Liu and L. A. Berglund, “Fire-Retardant and Ductile Clay Nanopaper Biocomposites Based on Montmorrilonite in Matrix of Cellulose Nanofibers and Carboxymethyl Cellulose,” European Polymer Journal, 2013, Vol. 49, pp. 940–949 . [27] W.S. Khan, R. Asmatulu, I. Ahmed, and T.S. Ravigururajan “Thermal Conductivities of Electrospun PAN and PVP Nanocomposite Fibers Incorporated with MWCNTs and NiZn Ferrite Nanoparticles,” International Journal of Thermal Sciences, 2013, Vol. 71, pp. 74-79.
  • [28] Y. Arao, Flame Retardancy of Polymer Nanocomposite, Springer, Switzerland, 2015.
  • [29] G. Beyer. “ Flame Retardancy of Nanocomposites – from Research to Technical Products,”Journal of Fire Science, Vol.5, 2005, pp.75-87.
  • [30] P. Estelle, S. Halelfadl, T. Mare, “Thermal Conductivity of CNT Water Based Nanofluids: Experimental Trends and Models Overview”, Journal of Thermal Engineering, Yildiz Technical University Press, Istanbul, Turkey, Vol. 1, Issue No. 2, pp. 381-390, April 2015.
  • [31] B. Decker, Y. Gan, S. Calderon, “Thermoelectric Properties of Bismuth Telluride Filled Silicone”, Journal of Thermal Engineering, Yildiz Technical University Press, Istanbul, Turkey, Vol. 1, Special Issue 3, No. 6, pp. 402-407, May, 2015.
  • [32] Uysal, “Relation Between Drill Bit Temperature And Chip Forms In Drilling Of Carbon Black Reinforced Polyamide”, Journal of Thermal Engineering, Yildiz Technical University Press, Istanbul, Turkey, Vol. 1, Special Issue 2, No. 7, pp. 655-658, February, 2015.