Katı atık ve arıtma çamurlarının değerlendirilmesinde alternatif termal teknolojiler ve uygulamaları

Katı atık ve arıtma çamurlarının tek başına veya diğer yakıtlarla birlikte yakılmasına alternatif teknolojiler araştırmak için iki önemli sebep bulunmaktadır. Bunlar, yanma boyunca oluşan büyük oranlardaki baca gazı emisyonları ve küldür. Yanma sonrası başlangıç kuru kütlenin yaklaşık %50'si kül olarak kalmakta ve bir çok toksik ağır metalleri içermektedir. Böylece külün uzaklaştırılması karmaşık hale gelmektedir. Bu kül miktarını azaltmak için piroliz, yakma ve gazlaştırma işlemlerinin kombinasyonu şeklinde bir çok yeni teknoloji geliştirilmiştir. Bu makalede yeni teknolojiler ve uygulamaları özetlenmektedir.

Alternative technologies for thermal processing of sewage sludge and solid wastes and applications

There are two main forces for the search for alternative technologies to mono/co-combustion of sewage sludges and wastes. These are the large quantity of flue gas and ash formed during combustion. After combustion, up to 50 wt % of the input dry mass of sludge remains as ash and most of the toxic heavy metals in sludge are retained, this complicates ash disposal. To reduce the quantity of ash for disposal, there are several new technologies which are combinations of the three process, i.e. pyrolysis, combustion and gasifications. This paper summarizes the new alternative technologies and applications.

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  • 1. Liptak B.G., Bouis P.,A., Hazardous Waste and Solid Waste, Lewis Publishers, CRC Press LLC, 2000.
  • 2. Sebastian F., Environmental Engineers Handbook, Edited by Liptak B.G., Chilton Book Company, 1974.
  • 3. Henmi M., Okazawa K., and Sota K., “Energy Saving in Sewage Sludge Incineration with Indirect Heat Drier”, National Waste Processing Conference, Denver, 1986.
  • 4. Otero M., Diez C., Calvo L.F., Garcia A.I., “Analysis of the Co-Combustion of Sewage Sludge and Coal by TG-MS”, Biomass and Bioenergy, Vol 22, 2002.
  • 5. Vesilind P.A, Ramsey T.B., “Effect of Drying Temperature on Fuel Value of Wastewater Sludge”. Wastewater Management and Reseaech, Vol 14, p.189- 196, 1992.
  • 6. Römer R., “Thermal Treatment of Sewage Sludge-Combustion, Drying Energy Recovery, Emissions”, In: Klarschlamm Entssorgung 1, Daten-Dioxine, Entwasserung, Verwetung, Entsorgungsvorschlage, Düsseldorf: VDI GmbH, p.250-271, 1991.
  • 7. Albertson O.E., Bruno J.M., “Sludge Incineration: Thermal Destruction of Residues”, Proceedings of the Symposium: Water Environment Federation, Alexandria, USA, 1992.
  • 8. Werther J., Ogada T., “Sewage Sludge Combustion”, Progress in Energy and Combustion Science, 25; p. 55-116., 1999.
  • 9. Lungwitz H., Werther J., “Alternative Processes for Thermal Treatment and Use of Sewage Sludge”, Thome-Kozmiensky K.J. Editor. Abfallwirtschaft am Wendepunkt. TK, Neuruppin, p. 717-742, 1997.
  • 10. Ogada T., Combustion and Emission Characteristics of Sewage Sludge in a Bubling Fluidized Bed Combustor, Ph.D. Dissertation, Technical University of Hamburg, Hamburg, 1995.
  • 11. Spliethoff H., ve ark., Ber. Dtsch. Wiss.Ges. Erdoel, Eredgas Kohle, Tagungsber,1996.
  • 12. Lu G.Q., Low J.C.F., Liu C.Y., Lua A.C., “Surface Area Development of Sewage Sludge During Pyrolysis”, Fuel, Vol 74 No.3, p.344-348, 1995.
  • 13. Piskorz J., Scott D.S., Westerberg I.B., Ind.Eng.Chem. Process Des. Dev. Vol 25, 1986.
  • 14. Bridge T.R., Environ. Tech. Lett. Vol 3, 1982.
  • 15. Storm C., ve ark., DGMK Tagungsber, Proceedings ICCS’97, Volume 2, p.721- 724, 1997.
  • 16. Bridge T.R., “Sludge Derived Oil-Wastewater Treatment Implications”, Environ. Technol. Lett. Vol 3, 151-156, 1982.
  • 17. Lu G.Q., Low J.C.F., Liu C.Y., “Surface Area Development of Sewage Sludge During Pyrolysis”, Fuel, Vol 3, p.344-348, 1995.
  • 18. Piskorz J., Scott D.S., Westerberg I.B., “Flash Pyrolysis of Biomass”, Ind. Eng.Chem. Proc. Design Develop, Vol 25, p.265-270, 1986.
  • 19. Rumphorst M.P., Ringel H.D., “Pyrolysis of Sewage Sludge and Use of Pyrolysis Coke”, J. Anal and Applied Pyrolysis, 28:p.137-155. 1994.
  • 20. Lendormi T., Prevot C., Doppenbe F., Foussard J.N., “Supercritical Wet Oxidation of Municipal Sewage Sludge Comparison of Batch and Continuous Experiments”, Water Science and Technology, Vol 44, 5, p.161-169, 2001.
  • 21. Lendormi T., Prevot C., Doppenbe F., Sperandio M., “Wet Oxidation of Domestic Sludge and Process Integration”, Water Science and Technology, Vol 44, 10, p.163-169, 2001.
  • 22. Hall J.E., “Sewage Sludge Production Treatment and Disposal in the European Union”, J CIWEM, Vol 9, p.335-342, 1995.
  • 23. Boon A., Thomas V., “Resource of Rubbish”, The Chemical Engineer, 25-30, 1996.
  • 24. Van Voorneburg F., “Treatment and Disposal of Municipal Sludge in the Nederland”, J CIWEM, Vol. 7, p.116-121, 1993.
  • 25. Kaminsky W., Augustin T., Bellmann U., Krüger-Betz M., “Pyrolisis of Industrial and Municipal Sewage Sludges”, Recycling von Klarschlamm 1. Berlin: EF für Energie-und Umwelttechnik GmbH, p.309-316, 1987.
  • 26. Kaminsky W., Ying Y., “Chemicals from Biomass Pyrolisis in a Fluidised Bed”, Advances in Thermochemical Biomass Conversion, Brigdwater A.V., editor, Vol.2
  • 27. Caballero J.A., Front R., “Characterisation of Sewage Sludges by Primary and Secondary Pyrolysis”, J. Anal. And Applied Pyrolysis, 4041, 1997.
  • 28. Loll U., “Sewage Sludge”, ATV Handbuch, 4th edn., Berlin, 1996.
  • 29. Kyriakos M., “Flash Pyrolsis of Wood and Dried Sewage Sludge for Liquid Fuel Production”, Grass G., Gosse G., editors, Biomass for Energy and Industry, 5th EC Conference, Vol. 2, Conversion and Utilisation of Biomass, p.2611-2615, 1998.
  • 30. Campbell H.W., “Converting Sludge to Fuel-a Status Report”, Hogan et al., editor, Biomass thermal Processing, Proceedings of the 1st Canada/European Community R. And D. Contructors Meeting, Ottawa, Canada, 78-85, 1990.
  • 31. Inguanzo M., Dominguez J.A., Menendez C.G., Blanco J.J., “On the Pyrolysis of Sewage Sludge: The Influence of Pyrolysiconditions on Solid, Liquid and Gas Fraction”, Journal of Analytical and Applied Prolysis, Vol 63, p.209-222, 2002.
  • 32. Hudson J.A., Lowe P., “Current Technologies for Sludge Treatment and Disposal”, J CIWEWM, 10:p.436-440, 1996.
  • 33. Shiota T.,“Economical Evaluation of a System for Making a Fuel from Sludge”, Recycling von Klarschlom. Berlin. EF für Energie, p.223-239. 1987.
  • 34. Bress D.F., Greenfield B.S., Haug R.T.,“Energy from Sludge Derived Fuels” Energy From Biomass and Wastes, Instiştute of Gas Technology. p.1173- 1182, 1987.
  • 35. Lohse U., “Pelleting and Gasification of Sewage Sludge”, Umwelt Bd, 26 (5), 1996.
  • 36. Lungwitz H., “Thermal Treatment of Sewage Sludge – New Trends for the Treatment and Disposal of Industrial and Municipal Sludges”, Darmstadt Schriftreihe WAR, 1997.
  • 37. Company Information Booklet-Krupp Uhde PreCon Process, Germany.
  • 38. Wolfgang K., Langer R., Kilian R., Wieling N.,“The Siemens- Pyrolysis/Combustion Plant Process and Material Concept”, Umwelt Bd, 21(6):p.361-363, 1991.
  • 39. Berwein H.J., “Siemens-Pyrolysis/Combustion Process for Wastes and Sewage Sludge”, Ensorgungspraxis, No 5, p.227-234, 1991.
  • 40. Company Information Booklet-Schwel-Brenn Process Siemens, Germany.
  • 41. Company Information Booklet-Recycled Clean Products von Roll GmbH, Germany.
  • 42. Company Information Booklet-Noell Conversion Process Noell, Germany.
  • 43. Company Information Booklet-Recycled Clean Products, Germany.
  • 44. Company Information Booklet-Thermoselect Process-Thermoselect, Germany.