Şeftali Çekirdeği Kabuğu Kullanarak Metilen Mavisi Boyasının Giderilmesi İçin Sabit Yataklı Kolonun Adsorpsiyon Performansı

Sabit yataklı kolonda sürekli adsorpsiyon çalışması, metilen mavisinin (MM) sulu çözeltiden giderilmesiiçin adsorbent olarak şeftali çekirdeği kabuğu kullanılarak gerçekleştirildi. Adsorpsiyon özellikleriüzerine başlangıç MM konsantrasyonu (20-60 mg/L), akış hızı (5-10 mL/dk) ve adsorbent miktarının (1.5-2.5 g) etkisi incelendi. Elde edilen veriler, breakthrough eğrilerinin akış hızına, başlangıç boyakonsantrasyonuna ve adsorbent miktarına bağlı olduğunu doğruladı. Thomas, Yoon-Nelson ve AdamsBohart kinetik modelleri breakthrough eğrilerini tahmin etmek ve proses tasarımında faydalı olankolonun karakteristik parametrelerini belirlemek için deneysel verilere uygulandı. Yanlızca AdamsBohart modeli dinamik prosesin başlangıç kısmını tahmin etmek için uygun bulundu.

Adsorption Performance of Fixed-Bed Column for the Removal of Methylene Blue Dye Using Peach Stone Shell

The continuous adsorption study in the fixed bed column was carried out using the peach stone shell as adsorbent to remove methylene blue (MB) from the aqueous solution. The effect of initial MB concentration (20-60 mg / L), flow rate (5-10 mL / min) and adsorbent amount (1.5-2.5 g) on adsorption properties were investigated. The data obtained confirmed that breakthrough curves were dependent on flow rate, initial dye concentration and adsorbent amount. To predict breakthrough curves and to determine the characteristic parameters of the column useful in process design, Thomas, Yoon-Nelson and Adams-Bohart kinetic models were applied to experimental data. Only the Adams-Bohart model was found suitable for predicting the initial part of the dynamic process.

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Aksu, Z., Gonen, F. 2004. Biosorption of phenol by immobilized activated sludge in a continuous packed bed: prediction of breakthrough curves. Process Biochemistry 39, 599–613.
Albert, M., Lessin, M. S. and Gilchrist, B. F., 2003. Methylene blue, dangerous dye for neonates. Journal of Pediatric Surgery, 38, 1244–1245.
Afroze, S., Sen, T.K. and Ang H.M., 2016. Adsorption performance of continuous fixed bed column for the removal of methylene blue (MB) dye using Eucalyptus sheathiana bark biomass. Res Chem Intermed, 42, 2343–2364.
Barragán, B. E., Costa, C., Márquez, M.C., 2007. Biodegradation of azo dyes by bacteria inoculated on solid media. Dyes and Pigments, 75 (1), 73-81.
Bazrafshan, E., Zarei, A.A., Nadi, H., Zazouli, M.A., 2014. Adsorptive removal of methyl orange and reactive red 198 dyes by Moringa peregrina ash. Indian Journal of Chemical Technology, 21, 105-113.
Benadjemia, M., Millière, L., Reinert, L., Benderdouche, N., Duclaux, L., 2011. Preparation, characterization and Methylene Blue adsorption of phosphoric acid activated carbons from globe artichoke leaves. Fuel Processing Technology, 92, 1203-1212.
Bhatnagar, A., Jain, A.K., 2005. A comparative adsorption study with different industrial wastes as adsorbents for the removal of cationic dyes from water. Journal of Colloid and Interface Science, 281(1), 49-55.
Bohart, G., Adams, E., 1920. Some aspects of the behavior of charcoal with respect to chlorine. Journal of the American Chemical Society, 42, 523–544.
Charola, S., Yadav, R., Das, P., Maiti, S., 2018. Fixed-bed adsorption of Reactive Orange 84 dye onto activated carbon prepared from empty cotton flower agrowaste, Sustainable Environment Research, 28, 298- 308.
Girish, C., Murty, V.R., 2015. Adsorption of phenol from aqueous solution using Lantana camara, forest waste: packed bed studies and prediction of breakthrough curves. Environmental Processes, 2, 773-796.
Gulnaz, O., Kaya, A., Matyar, F., Arikan, B., 2004. Sorption of basic dyes from aqueous solution by activated sludge. Journal of Hazardous Materials, 108 (3), 183- 188.
Hameed, B. H., Ahmad, A. A., 2009. Batch adsorption of methylene blue from aqueous solution by garlic peel, an agricultural waste biomass. J. Hazard. Mater., 164, 870–875.
Han, R., Wang, Y., Zhao, X., Wang, Y., Xie, F., Cheng, J. and Tang, M., 2009. Adsorption of methylene blue by phoenix tree leaf powder in a fixed-bed column: Experiments and prediction of breakthrough curves. Desalination, 245 (1-3), 284–297.
Kumar, K. V. and Porkodi, K., 2009. Equilibrium and thermodynamics of dye removal from aqueous solution by adsorption using rubber wood saw dust. International Journal of Environmental Technology and Management, 10 (3-4), 295–307.
Kumar, S., Gunasekar, V. and Ponnusami, V. 2013. Removal of Methylene Blue from Aqueous Effluent Using Fixed Bed of Groundnut Shell Powder, Journal of Chemistry, 2013, 1-5.
Mirjalili, M., Tabatabai, M. B. and Karimi, L., 2011. Novel herbal adsorbent based on wheat husk for reactive dye removal from aqueous solutions. African Journal of Biotechnology, 10 (65), 14478–14484.
Murugan, T., Ganapathi, A. and Valliappan, R., 2010. Removal of grey BL from dye wastewater by derris (Pongamia glabra) leaf powder by adsorption. EJournal of Chemistry, 7 (4), 1454–1462.
Ong, S. T., Keng, P. S., Voon, M. S. and Lee, S. L., 2011. Application of durian peel (Durio zibethinus Murray) for removal of methylene blue from aqueous solution. Asian Journal of Chemistry, 23 (7), 2898–2902.
Özdemir, Ç.S. 2014. Removal of Methylene Blue by Activated Carbon Prepared from Waste in a Fixed-Bed Column, Particulate Science and Technology, 32(3), 311-318.
Patel, H. 2019. Fixed‑bed column adsorption study: a comprehensive review, Applied Water Science, 9 (45), 1-17.
Safa, Y. and Bhatti, H. N., 2011. Biosorption of direct red31 and direct orange-26 dyes by rice husk: application of factorial design analysis. Chemical Engineering Research and Design, 89 (12), 2566–2574.
Song, J., Zou, W., Bian, Y., Su, F., Han, R. 2011. Adsorption characteristics of methylene blue by peanut husk in batch and column modes, Desalination, 265, 119– 125.
Tsai, W. T., Chang, C. Y., Lin, M. C., Chien, S. F., Sun, H. F., Hsieh, M. F., 2001. Adsorption of Acid Dye onto Activated Carbons Prepared from Agricultural Waste Bagasse by ZnCl2 Activation. Chemosphere, 45 (1), 51- 58.
Thomas, H. C. 1944. Heterogeneous ion exchange in a flowing system. Journal of the American Chemical Society, 66, 1664–1666.
Vijayaraghavan, K., Jegan, J., Palanivelu, K., Velan, M., 2004. Removal of nickel(II) ions from aqueous solution using crab shell particles in a packed bed up flow column, Journal of Hazardous Materials, 113B (1–3), 223–230.
Yagub, M.T., Sen, T.K., Afroze, S., Ang, H.M. 2015. Fixedbed dynamic column adsorption study of methylene blue (MB) onto pine cone. Desalin Water Treat, 55, 1026-1039.
Yang, Y., Wei, X., Sun, P. Wan, J., 2010. Preparation, characterization and adsorption performance of a novel anionic starch microsphere. Molecules, 15 (4), 2872–2885.
Yoon, Y.H. and Nelson, J.H., 1984. Application of gas adsorption kinetics. I. A theoretical model for respirator cartridge service life. American Industrial Hygiene Association Journal, 45, 509-516.
Zheng, P., Bai, B.,Guan, W.,Wang, H., Suo, Y., 2016. Fixedbed column studies for the removal of anionic dye from aqueous solution using TiO2@glucose carbon composites and bed regeneration study, J Mater Sci: Mater Electron, 27, 867–877.