PRODUCTION OF LIGHTWEIGHT AGGREGATES FROM DIFFERENT TYPES OF BORON WASTES

Four boron wastes (BW), named as Sieve (SBW), Dewatering (DBW), Thickener (TBW) and Mixture (MBW) waste, from Kirka plant (Turkey) were investigated for the formation of Artificial Lightweight Aggregates (LWA). The characterization involved chemical, mineralogical and thermal analyses. The bloating behavior was examined by heating microscopy. SBW and DBW expanded in two stages, at 300°C approximately and subsequently at 550°C with concurrent formation of liquid phase. However, at 650-700°C there is excessive liquid phase formed resulting in large, non uniform porosity of irregular shape. On the contrary, in the case of TBW and MBW no noticeable expansion or glassy surface was formed. An optimization route, involved the formation of a mixture with 20wt% clay, 40wt% SBW, 40wt% DBW and one with 20wt% clay, 35wt% SBW, 35wt% DBW, 10wt% quartz sand. The raw aggregates were fired in a rotating crucible at 650°C, 700°C, 710°C and 760°C for 2-5 min. It was observed that the clay addition leads to better plasticity and cohesion between the particles whereas the quartz addition shifts the softening point 50°C higher. Water absorption was 56.8-60.5%, apparent specific gravity 2.3-2.4g/cm3 and bulk density 0.9-1.1g/cm3 . The analysis of microstructure with electron microscopy revealed a glassy phase matrix and an extended formation of both open and closed pores. The results indicate that SBW and DBW boron wastes can be utilized in LWA production. 
Anahtar Kelimeler:

xx

PRODUCTION OF LIGHTWEIGHT AGGREGATES FROM DIFFERENT TYPES OF BORON WASTES

Four boron wastes (BW), named as Sieve (SBW), Dewatering (DBW), Thickener (TBW) and Mixture (MBW) waste, from Kirka plant (Turkey) were investigated for the formation of Artificial Lightweight Aggregates (LWA). The characterization involved chemical, mineralogical and thermal analyses. The bloating behavior was examined by heating microscopy. SBW and DBW expanded in two stages, at 300°C approximately and subsequently at 550°C with concurrent formation of liquid phase. However, at 650-700°C there is excessive liquid phase formed resulting in large, non uniform porosity of irregular shape. On the contrary, in the case of TBW and MBW no noticeable expansion or glassy surface was formed. An optimization route, involved the formation of a mixture with 20wt% clay, 40wt% SBW, 40wt% DBW and one with 20wt% clay, 35wt% SBW, 35wt% DBW, 10wt% quartz sand. The raw aggregates were fired in a rotating crucible at 650°C, 700°C, 710°C and 760°C for 2-5 min. It was observed that the clay addition leads to better plasticity and cohesion between the particles whereas the quartz addition shifts the softening point 50°C higher. Water absorption was 56.8-60.5%, apparent specific gravity 2.3-2.4g/cm3 and bulk density 0.9-1.1g/cm3 . The analysis of microstructure with electron microscopy revealed a glassy phase matrix and an extended formation of both open and closed pores. The results indicate that SBW and DBW boron wastes can be utilized in LWA production. 

___

  • E. G. Ehlers, The Mechanism of Lightweight Aggregate Formation, Ceramic Buletin, Vol. 37, No.2, 95-99,1958
  • Su-Chen Huang et al, Production of lightweight aggregates from mining residues, heavy metal sludge, andincinerator fly ash, J. Hazard. Mater. 144, 52-58, 2007
  • M. Aineto, A. Acosta, J. M. Rincon, M. Romero, Production of Lightweight Aggregates from Coal Gasification Fly Ash and Slag, Submitted for consideration in the 2005 World of Coal Ash 11-15, Lexington, Kentucky, USA, 2005
  • I. Anagnostopoulos, V. Stivanakis, Utilization of lignite power residues for the production of lightweight aggregates, J. Hazard. Mater. (2008), doi:10.1016/j.jhazmat.2008.06.125
  • H. R. Blank, Red Mud from Alumina Plants as a Possible Source of Synthetic Aggregate, Journal of Testing and Evaluation, JTEVA, Vol. 4, No. 5, 355-358, 1976
  • V. Ducman, A. Mladenovič, J. S. Šuput, Lightweight aggregate based on waste glass and its alkali-silica reactivity, Cem. Conr. Res. 32, 223-226, 2002
  • R. de Gennaro, P. Cappelletti, G. Cerri, M. de Gennaro, M. Dondi, A. Langella, Zeolitic tuffs as raw materials for lightweight aggregates, App. Clay Sci. 25, 71-81, 2004
  • http://www.etimaden.gov.tr
  • P. M. Mobbs, The Mineral Industry of Turkey, U.S. Geological Survey Minerals Yearbook-2004.
  • European Commission, Reference Document on Best Available Techniques for Management of Tailings and Waste-Rock in Mining Activities, Chapter 3, July 2004.
  • A. Ekmekyapar, A. Baysar, A. Künkül, Dehydration Kinetics of Tincal and Borax by Thermal Analysis, Ind. Eng. Chem. Res. 36, 3487-3490, 1997
  • I. Waclawska, Thermal decomposition of borax, J. Therm. Anal., 43, 261-269, 1995
Afyon Kocatepe Üniversitesi Fen ve Mühendislik Bilimleri Dergisi-Cover
  • Yayın Aralığı: 6
  • Başlangıç: 2015
  • Yayıncı: AFYON KOCATEPE ÜNİVERSİTESİ
Sayıdaki Diğer Makaleler

NiO / YSZ (YİTRİYA İLE KARARLI HALE GETİRİLMİŞ ZİRKONYA) SERAMİKLERİN KIRILMA TOKLUĞUNA MİKRO YAPININ ETKİSİ

B. AKTAŞ, S. TEKELİ, G. KÜPELİ, Y. BOZKURT, Ö. GÜLSOY, S. SALMAN

USE OF COMBINED NON-DESTRUCTIVE METHODS TO ASSESS THE STRENGTH OF CONCRETE IN STRUCTURES

Ömer ARIÖZ, Ahmet TUNCAN, Mustafa TUNCAN, Taner KAVAS, Kambiz RAMYAR, Kadir KILINÇ, Bekir KARASU

PRODUCTION OF LIGHTWEIGHT AGGREGATES FROM DIFFERENT TYPES OF BORON WASTES

Taner KAVAS, Angeliki CHRİSTOGEROU, Yiannis PONTİKES, Tuğba TUNÇ, George N. ANGELOPOULOS

FARKLI TANE BOYUTLARINDA FRİT KATKISI İLE DÜŞÜK SICAKLIKLARDA PİŞİRİLMİŞ VİTRİFİYE MASSESİ TEKNİK ÖZELLİKLERİNİN ARAŞTIRILMASI

Reyhan GÖZEL, Taner KAVAS, Ali KARTAL

FACTORS AFFECTING THE DRYING BEHAVIOR OF CERAMIC FILMS

Aylin ŞAKAR-DELİORMANLI, Erdal ÇELİK, Mehmet POLAT

SOL-JEL YÖNTEMİYLE DÜŞÜK ERGİME SICAKLIKLI SIR ÜRETİMİ

A. EVCİN, C. DEMİŞULAM

Borik Asit İlavesinin Elektroporselen Bünyelerin Sinterleme Davranışları Üzerine Etkisinin İncelenmesi

Tuna AYDIN, Alpagut KARA

DORYLAION (ESKİŞEHİR-ŞARHÖYÜK) HELLENİSTİK DÖNEM BATI YAMACI SERAMİKLERİNİN KARAKTERİZASYONU

Ali İSSİ, Alpagut KARA, Taciser SİVAS, Hakan SİVAS

DİNAMİK KARBOTERMAL YÖNTEM İLE α-Si3N4 SERAMİK TOZU ÜRETİMİ

Ali Osman KURT, Yusuf GÜZELVARDAR

ZrO2-Y2O3 İlaveli MgO-MgAl2O4 Kompozit Refrakterlerin Mekanik Özelliklerinin Ve Mikroyapısal Karakteristiklerinin İncelenmesi

Tuba AKSOY, Cemail AKSEL