Sinkrotron Işınımı: Depolama Halkasından Sert X-ışını Demet Hattına

Bu çalışmada, elektronların bir elektron kaynağından salınması ile başlayıp sinkrotron ışınımı elde edilmesine kadarki birbirini izleyen adımları kapsayan genel bir bakış sunulmuştur. Üçüncü nesil ışınım kaynaklarının ana karakteristikleri ve temel bileşenleri ile farklı eklenti aygıtlarının ışınım karakteristikleri de tartışılmıştır. Tipik bir sert X-ışını sinkrotron demet hattının kısaca tasvirinden sonra, rezonans olmayan inelastik sert X-ışını tekniği olan, sinkrotron ışınımına dayalı X-ışını Raman saçılma spektroskopisi açıklanmıştır. Son olarak, DESY-PETRA III sinkrotronundaki X-ışını Raman spektrometresi kullanılarak, 10 keV enerjide 0.8 eV çözünürlükle kaydedilen sıvı fazdaki suyun oksijen K-soğurma sınırı spektrumu sunulmuş ve literatürde geleneksel X-ışını soğurma spektroskobisi ile ölçülen spektrum ile karşılaştırılmıştır.

Anahtar Kelimeler:

Sinkrotron ışınımı, depolama halkası, demet hattı, üçüncü nesil ışınım kaynağı, Inelastik X-ışını Saçılması, X-ışını Raman saçılma spektroskopisi

SYNCHROTRON RADIATION: FROM STORAGE RING TO A HARD X-RAY BEAMLINE

In the present study, a general overview covering the consecutive steps, starting with the release of electrons from an electron source until the generation of synchrotron radiation, is presented. A brief introduction regarding the main characteristics and fundamental components of third generation light sources as well as the radiation characteristics of different Insertion Devices are discussed. Following a concise description of a typical hard X-ray synchrotron beamline, synchrotron radiation based X-ray Raman scattering spectroscopy, which is a non-resonant inelastic hard X-ray technique, is explained. Finally, liquid water oxygen K-edge absorption spectrum recorded with a resolution of 0.8 eV at 10 keV utilizing X-ray Raman spectrometer at PETRA III facility of DESY is presented and compared to the spectrum from the literature measured by conventional X-ray absorption spectroscopy.

Keywords:

Synchrotron radiation, storage ring, beamline, third generation light source, Inelastic X-ray Scattering, X-ray Raman scattering spectroscopy,

PDF

___

Ascone, I. et al. (2004) PETRA III: A Low Emittance Synchrotron Radiation Source, Technical Design Report, EDMS ID: D00000000822371,A,1,1
Balerna, A. and Mobilio, S. (2015) Introduction to synchrotron radiation, Springer-Verlag Berlin Heidelberg. doi: 10.1007/978-3-642-55315-8_1
Basile, F. et al. (2010) Combined Use of Synchrotron‐Radiation‐Based Imaging Techniques for the Characterization of Structured Catalysts, Advanced Functional Materials, 20, 4117–4126. doi: 10.1002/ADFM.201001004
Bergmann, U. et al. (2002a) Bulk-sensitive XAS characterization of light elements: From X-ray Raman scattering to X-ray Raman spectroscopy, Microchemical Journal, 71, 221–230. doi: 10.1016/S0026-265X(02)00014-0
Bergmann, U. et al. (2002b) X-ray Raman spectroscopy at the oxygen K edge of water and ice: Implications on local structure models, Physical Review B, 66, 092107. doi: 10.1103/PhysRevB.66.092107
Braun, A. et al. (2015) Hard X-rays in–soft X-rays out: An operando piggyback view deep into a charging lithium ion battery with X-ray Raman spectroscopy. Journal of Electron Spectroscopy and Related Phenomena, 200, 257-263. doi: 10.1016/j.elspec.2015.03.005
Brown, G.E. and Sturchio, N.C. (2002) An Overview of Synchrotron Radiation Applications to Low Temperature Geochemistry and Environmental Science, Reviews in Mineralogy and Geochemistry, 49 (1) , 1-115. doi: 10.2138/gsrmg.49.1.1
Cai Y. Q. et al. (2005) Ordering of hydrogen bonds in high-pressure low-temperature H2O, Physical Reiew Letters, 94, 025502. doi: 10.1103/PhysRevLett.94.025502
Cotte, M. et al. (2010) Synchrotron-Based X-ray Absorption Spectroscopy for Art Conservation: Looking Back and Looking Forward, Accounts of Chemical Research, 43 (6),705–714. doi: 10.1021/ar900199m
Fukui, H. et al. (2007) Oxygen K-edge fine structures of water by x-ray Raman scattering spectroscopy under pressure conditions, Journal of Chemical Physics, 127, 134502. doi: 10.1063/1.2774988
Gomez, A. et al. (2018) The high-energy x-ray diffraction and scattering beamline at the Canadian Light Source, Review of Scientific Instruments, 89, 063301. doi: 10.1063/1.5017613
Gueriau, P. et al. (2017) Noninvasive Synchrotron-Based X-ray Raman Scattering Discriminates Carbonaceous Compounds in Ancient and Historical Materials. Analytical Chemistry, 89 (20), 10819-10826. doi: 10.1021/acs.analchem.7b02202
Hämäläinen, K. and Manninen, S. (2001) Resonant and non-resonant inelastic x-ray scattering, Journal of Physics-Condensed Matter, 13 (34), 7539–7555. doi: 10.1088/0953-8984/13/34/306
Huotari, S. et al. (2010) Direct tomography with chemical-bond contrast, Nature Materials, 10 (7), 489–493. doi: 10.1038/nmat3031
Iwamoto, H. (2018) Synchrotron Radiation X-ray Diffraction Techniques Applied to Insect Flight Muscle, International Journal of Molecular Sciences, 19 (6), 1748. doi: 10.3390/ijms19061748
Iitaka T. et al. (2015) Pressure-induced dissociation of water molecules in ice VII, Scientific Reports, 5, 12551. doi: 10.1038/srep12551
Jonas A. et al. (2014) Comparison of x-ray absorption spectra between water and ice: New ice data with low pre-edge absorption cross-section, Journal of Chemical Physics, 141, 034507. doi: 10.1063/1.4890035
Lee, S. K. et al. (2014) Probing of pressure-induced bonding transitions in crystalline and amorphous earth materials: insights from X-ray Raman scattering at high pressure, Reviews in Mineralogy and Geochemistry, 78 (1), 139-174. doi: 10.2138/rmg.2014.78.4
Lindegaard-Andersen, A. and Gerward, L. (1995) Röntgen centenary-100 years of X-rays, Radiation Physics and Chemistry, 46 (3), 299–302. doi: 10.1016/0969-806X(95)00063-4
Lutzenkirchen-Hecht, D. et al. (2014) The multi-purpose hard X-ay beamline BL10 at the DELTA storage ring, Journal of Synchrotron Radiation, 21, 819-826. doi: 10.1107/S1600577514006705
Mao W. L. et al. (2006) X-ray-induced dissociation of H2O and formation of an H2O2 alloy at high pressure, Science, 314, 636–638. doi: 10.1126/science.1132884
McCarthy, A. A. et al. (2018) ID30B–a versatile beamline for macromolecular crystallography experiments at the ESRF, Journal of Synchrotron Radiation, 25, 1249–1260 doi: 10.1107/S1600577518007166
Moffat, K. and Ren, Z. (1997) Synchrotron radiation applications to macromolecular crystallography, Current Opinion in Structural Biology, 7 (5), 689-696. doi: 10.1016/S0959-440X(97)80079-6
Myneni, S. et al. (2002) Spectroscopic probing of local hydrogen-bonding structures in liquid water, Journal of Physics Condensed Matter, 14 (8), L213. doi: 10.1088/0953-8984/14/8/106
Näslund, L. Å. et al. (2005) X-ray absorption spectroscopy measurements of liquid water, Journal of Physical Chemistry B, 109 (28), 13835-13839. doi: 10.1021/jp052046q
Nilsson, A. et al. (2010) X-ray absorption spectroscopy and x-ray Raman scattering of water and ice: an experimental view, Journal of Electron Spectroscopy and Related Phenomena, 177 (2-3), 99–129. doi: 10.1016/j.elspec.2010.02.005
Parent, P. et al. (2002) Structure of the water ice surface studied by x-ray absorption spectroscopy at the O K-edge, Journal of Chemical Physics, 117, 10842–10851. doi: 10.1063/1.1519256
Richard, F. et al. (2001) TESLA Technical Design Report Part I Executive Summary, ISBN: 3-935702-00-0, ISSN: 0418-9833
Sahle C. J. et al. (2013) Microscopic structure of water at elevated pressures and temperatures, Proceedings of the National Academy of Sciences, 110, 6301–6306. doi: 10.1073/pnas.1220301110
Sahle, C. J. et al. (2015) Planning, performing and analyzing X-ray Raman scattering experiments, Journal of Synchrotron Radiation, 22, 400-409. doi: 10.1107/S1600577514027581
Sahle, C. J. et al. (2016). In situ characterization of the decomposition behavior of Mg (BH4)2 by X-ray Raman scattering spectroscopy. Physical Chemistry Chemical Physics, 18 (7), 5397-5403. doi: 10.1039/C5CP06571B
Smith, J. D. et al. (2006) Probing the local structure of liquid water by x-ray absorption spectroscopy, Journal of Physical Chemistry B, 110 (40), 20038–20045. doi: 10.1021/jp063661c
Tse, J. S. et al. (2008) X-ray Raman spectroscopic study of water in the condensed phases, Physical Reiew Letters, 100, 095502. doi: 10.1103/PhysRevLett.100.095502
Yano, J. and Yachandra, V. K. (2009) X-ray absorption spectroscopy, Photosynthesis Research, 102, 241–254. doi: 10.1007/s11120-009-9473-8