Voltammetric and Spectroscopic Studies of Vanadium(V)-- Nicotinamide Interactions at Physiological pH

The interaction of nicotinamide (NA) with NH4VO3 at the physiological pH (pH 7.4) was studied by voltammetry and UV-Vis spectroscopy. The reduction of V(V) ions complexed with NA in phosphate buffer (pH 7.4) was observed as a well-defined reversible reduction peak at --0.35 V. The stoichiometric (metal:ligand) ratio of the complex of V(V) with NA was determined as 1:2 by the mole ratio method.

Voltammetric and Spectroscopic Studies of Vanadium(V)-- Nicotinamide Interactions at Physiological pH

The interaction of nicotinamide (NA) with NH4VO3 at the physiological pH (pH 7.4) was studied by voltammetry and UV-Vis spectroscopy. The reduction of V(V) ions complexed with NA in phosphate buffer (pH 7.4) was observed as a well-defined reversible reduction peak at --0.35 V. The stoichiometric (metal:ligand) ratio of the complex of V(V) with NA was determined as 1:2 by the mole ratio method.

___

  • Y. Shechter and A. Shisheva, Endeavour 17, 27-31 (1993).
  • N.D. Chasteen, (Ed.), “Vanadium in Biological Systems”, Kluwer Academic Publishers, Dordrecht, the Netherlands, 1990.
  • A. Butler and C.J. Carrano, Coord. Chem. Rev. 109, 61-105 (1991).
  • D. Rehder, Angew. Chem. Int. Ed. Engl. 30, 148-167 (1991).
  • D. Rehder, Biometals 5, 3-12 (1992).
  • A.M. Cortizo and S.B. Etcheverry, Mol. Cell. Biochem. 145, 97-102 (1995).
  • S. Verma, M.C. Cam and J.H. McNeil, J. Am. Coll. Nutr. 17, 11-18 (1998).
  • K. Cusi, S. Cukier, R.A. DeFronzo, M. Torres, F.M. Puchulu and J.C.P. Redondo, J. Clin. Endocrinol. Metab. 86, 1410-1417 (2001).
  • C. Caruso-Neves, J.R. Meyer-Fernandes, J. Saad Nehme, F. Proverbio, R. Marin and A.G. Lopes, Comp. Biochem. Physiol. B 119, 807-811 (1998).
  • S.G. O’Neal, D.B. Rhoads and E. Racker, Biochem. Biophys. Res. Commun. 89, 845-850 (1979).
  • R. Wever and K. Kustin, Adv. Inorg. Chem. 35, 81-115 (1990).
  • A. Kumar and R.N. Mehrotra, J. Org. Chem. 40, 1248-1252 (1975). S. C
  • ¸ akır and E. Bi¸cer, Bioelectrochemistry 64, 1-6 (2004).
  • E.A.M. Gale, Horm. Metab. Res. 28, 361-364 (1996).
  • V. Polo, A. Saibene and A.E. Pontiroli, Acta Diabetol 35, 61-64 (1998).
  • N. Hassan and M.Z. Janjua, J Ayub Med Coll Abbottabad 13, 26-30 (2001).
  • J. Gosteli, Med. Hypotheses 64, 1062-1063 (2005).
  • J.R. Allan, N.D. Baird and A.L. Kassyk, J. Therm. Anal. Calorim. 16, 79-90 (1979). S. C
  • ¸ akır, E. Bi¸cer, H. ˙I¸cbudak, P. Naumov, H. Korkmaz, and O. C¸ akır, Polish J. Chem. 75, 371-377 (2001). S. C
  • ¸ akır, E. Bi¸cer, K. Aoki and E. Co¸skun, Cryst. Res. Technol. 41, 314-320 (2006).
  • L.G. Hargis, “Analytical Chemistry: Principles and Techniques”, p. 426, Prentice-Hall, Inc., New Jersey, S. C ¸ akır, ˙I. Bulut, E. Bi¸cer, E. Co¸skun and O. C¸ akır, J. Electroanal. Chem. 511, 94-100 (2001).
  • P. Zuman, “Topics in Organic Polarography”, p. 31, Plenum Press, London, 1970.
  • Y. Israel and L. Meites, “Vanadium” in: A.J. Bard (Ed.), Encyclopedia of Electrochemistry of the Elements, Vol. VII, Chap. VII-2, p. 336, 337, 378, Marcel Dekker Inc., New York, 1976.
  • J. Chakravarty, S. Dutta, A. Dey and A. Chakravorty, J. Chem. Soc. Dalton Trans., 557-561 (1994).
  • M.J. Clague, N.L. Keder and A. Butler, Inorg. Chem. 32, 4754-4761 (1993).
  • J.A. Bonadies and C.J. Carrano. J. Am. Chem. Soc. 108, 4088-4095 (1986).
  • S. Pal, K. R. Radhika and S. Pal, Z. Anorg. Allg. Chem.,627, 1631-1637 (2001).
  • A.C. Gonzalez-Baro and E.J. Baran, J. Braz. Chem. Soc.,12, 208-214 (2001).
  • W.R. Browne, A.G.J. Ligtenbarg, J.W. de Boer, T.A. van den Berg, M. Lutz, A.L. Spek, F. Hartl, R. Hage and B.L. Feringo, Inorganic Chemistry,45,2903-2916 (2006).
  • T.K. Paine, “Transition Metal Complexes of Tridentate Bisphenol Ligands and Their Reactivity towards Organic Substrates”, PhD Thesis, Universit¨at-Paderborn, Germany, 2003.
  • A.H. Jubert, A.C. Gonzalez-Baro, R. Pis-Diez and E.J. Baran, J. Raman Spectrosc. 23, 273-279 (1992).
  • A.C. Gonz´alez-Bar´o, O.E. Piro, B.S. Paraj´on-Costa, E.J. Baran and E.E. Castellano, Monatsh. Chem. 129, 39 (1998).
  • N. Agnihotri, R. Dass and J.R. Mehta, Analytical Sciences,15,1261-1264 (1999).
Turkish Journal of Chemistry-Cover
  • ISSN: 1300-0527
  • Yayın Aralığı: Yılda 6 Sayı
  • Yayıncı: TÜBİTAK
Sayıdaki Diğer Makaleler

Chemoenzymatic Synthesis of 2-Bromo-6-Hydroxy-3-Methoxy-2-Cyclohexen-1-one

Emine Özgül KARAASLAN, Yasemin TOKA

Synthesis of 2-Acylamino, 2-Aroylamino and Ethoxycarbonyl Imino-1,3,4-thiadiazoles as Antitumor Agents

Kemal SANCAK, Yasemin ÜNVER, Mustafa ER

Synthesis of Nitrogen-Containing Heterocycles from the Reaction of Amidrazones with a-Haloesters

Hany M. DALLOUL, Peter H. BOYLE

Investigation of some 1-3-diols for the requirements of solvent extraction of boron: 2,2,6-trimethyl-1,3 heptanediol as a potential boron extractant

Servet TURAL, Bilsen TURAL, Halil HOŞGÖREN

Investigation of Some 1,3-Diols for the Requirements of Solvent Extraction of Boron: 2,2,6-Trimethyl-1,3 Heptanediol as a Potential Boron Extractant

Bilsen TURAL, Servet TURAL, Halil HOŞGÖREN

Synthesis and physico-chemical and spectroscopic investigations of sodium dihydrobis (1,2,3-benzotriazoly) borate ligand and its transition metal complexes

Mohammed Muzibur RAHMAN, Ahmad Umar LUTFULLAH, Mohammad Mansoob KHAN, Yoon Bong HAHN

Voltammetric and spectroscopic studies of vanadium (V)-nicotinamide interactions at physiological pH

Ender BİÇER, Semiha ÇAKIR

On-Line Preconcentration and Speciation of Chromium by an 8-Hydroxyquinoline Microcolumn Immobilized on Surfactant-Coated Alumina and Flow Injection Atomic Absorption Spectrometry

Seyyed Hamid AHMADI, Ali Mohammad Haji SHABANI

On-line preconcentration and speciation of chromium by an 8-hidroxyquinoline microcolumn immobilized on surfactant-coated alumina and flow injection atomic absorption spectrometry

Hajı Ali Mohammad SHABANI, Masoumeh TAEI, Seyyed Hamid AHMADI, Shayessteh DADFARNIA

Voltammetric and Spectroscopic Studies of Vanadium(V)-- Nicotinamide Interactions at Physiological pH

Semiha ÇAKIR, Ender BİÇER