Ultrarapid catalytic reduction of some dyes by reusable novel erythromycin-derived silver nanoparticles

A novel green approach for the synthesis of silver nanoparticles using erythromycin as a reducing/capping agent is presented. Erythromycin-derived silver nanoparticles were characterized by ultraviolet-visible spectroscopy, scanning electron microscopy, high resolution transmission electron microscopy, X-ray powder diffraction, and Fourier transform infrared spectroscopy. Monodispersed silver nanoparticles showed excellent and promising catalytic activity for reduction of 3 differently charged dyes (eosin B, methylene blue, and rose bengal) in the presence of NaBH4. The study revealed that 100% reduction of these dyes can be achieved efficiently in just 150--250 s. They were easily recovered from the reaction medium and were reused 5 times, showing enhanced catalytic potential each time. Glass-supported Ag(0) NPs (0.15 mg) were removed by washing sequentially and reused 5 times for catalytic reduction of these dyes at 10 m M. All dyes were successfully reduced by erythromycin-derived silver nanoparticles up to 7%. Based upon these results, it was concluded that erythromycin-derived silver nanoparticles are a novel, rapid, and highly economical alternative for environmental protection against pollution caused by dyes and can be extended for the control of other reducible contaminants.

Anahtar Kelimeler:

Inorganic compounds, chemical synthesis, X-ray diffraction, catalytic properties

Ultrarapid catalytic reduction of some dyes by reusable novel erythromycin-derived silver nanoparticles

Keywords:

Inorganic compounds, chemical synthesis, X-ray diffraction, catalytic properties,

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Sondi, I.; Goia, D. V.; Matijevic, E. J. Colloid Interface Sci. 2003, 260, 75–81.
Edison, T. I.; Sethuraman, M. G. Process. Biochem. 2012, 47, 1351–1357.
Aksomaityte, G.; Poliakoff, M.; Lester, E. Chem. Eng. Sci. 2013, 85, 2–10.
Darroudi, M.; Zak, A. K.; Muhamad, M. R.; Huang, N. M.; Hakim, M. Mater. Lett. 2012, 117, 117–120.
Kim, S. E.; Park, J. H.; Lee, B.; Lee, J. C.; Kwon, Y. K. Radiat. Phys. Chem. 2012, 81, 978–981.
Balamurugan, A., Ho, K. C.; Chen, S. M. Synth. Met. 2009, 159, 2544–2549.
Tagar, Z. A.; Sirajuddin, Memon, N.; Agheem M. H.; Junejo, Y.; Hassan, S. S.; Kalwar, N. H.; Khattak, M. I. Sens. Actuators B 2011, 157, 430-37.
Junejo, Y.; Karao˘glu, E.; Baykal, A.; Sirajuddin J. Inorg. Organomet. Polym. 2013, 23, 970–975.
Kouvaris, P.; Delimitis, A.; Zaspalis, V.; Papadopoulos, D.; Tsipas, S. A.; Michailidis, N. Mater. Lett. 2012, 76, 18–
Jagtap, U. B.; Bapat, V. A. Ind. Crops Prod. 2013, 46, 132–137.
Bar, H.; Bhui, D. K.; Sahoo, G. P.; Sarkar, P.; Pyne, S.; Misra, A. Colloids Surf. A: Physicochem. Eng. Aspects 2009, 348, 212–216.
Saha, S.; Wang, J. M.; Pal, A. Sep. Purif. Technol. 2012, 89, 147–159.
Nanda, A.; Saravanan, M. Nanomedicine: Nanotechnology Biology and Medicine 2009, 5, 452–456.
Cho, K. H.; Park, J. E.; Osaka, T.; Park, S. G. Electrochim. Acta 2005, 51, 956–960.
Sondi, I.; Sondi, B. S. J. Colloid Interface Sci. 2004, 275, 177–182.
Shahverdi, A. R.; Fakhimi, A.; Shahverdi, H. R.; Minaian, S. Nanomedicine: Nanotechnology Biology and Medicine 2007, 3, 168–171.
Maneerung, T.; Tokur,a S.; Rujiravanit, R. Carbohydr. Polym. 2008, 72, 43–51.
Pradhan, N.; Pal, A.; Pal, T. Langmuir 2001, 17, 1800–1802.
Burda, C.; Chen, X.; Narayanan, R.; El-Sayed, M. A. Chem. Rev. 2005, 105, 1025–1102.
Siani, A.; Wigel, K. R.; Alexeev, O. S.; Amiridis, M. D. J. Catal. 2008, 257, 5–15.
Cortie, M. B.; Van der Lingen, E. Mater. Forum 2002, 26, 1–14.
Brown, M. A.; De Vito, S. C. Crit. Rev. Environ. Sci. Technol. 1993, 23, 249–324.
Safarik, I.; Ptackova, L.; Safarikova, M. Eur. Cell Mater. 2002, 3, 52–55.
Lin, J.; Zong, R.; Zhou, M.; Zhu, Y. Appl. Catal. B: Environ. 2009, 89, 425–431.
Ibhadon, A. O.; Greenway, G. M.; Yue, Y. Catal. Commun. 2008, 9, 153–157.
Lachheb, H.; Puzenat, E.; Houas, A.; Ksibi, M.; Elaloui, E.; Guillard, C.; Herrmann, J. M. Appl. Catal. B: Environ. 2002, 39, 75–90.
Ferreira-Leitao, V. S.; da Silva, J. G.; Bon, E. P. S. Appl. Catal. B Environ. 2003, 42, 213–221.
Daneshvar, N.; Aleboyeh, A.; Khataee, A. R. Chemosphere 2005, 59, 761–767.
Jana, N. R.; Wang, Z. L.; Pal, T. Langmuir 2000, 16, 2457–2463.
Fan, J.; Guo, Y.; Wang, J.; Fan, M. J. Hazard. Mater. 2009, 166, 904–910.
Sau, T. K.; Pal, A.; Pal, T. J. Phys. Chem. B 2001, 105, 9266–9272.
Martin, C. F.; Birot, M.; Deleuze, H.; Desforges, A.; Backov, R. React. Funct. Polym. 2007, 67, 1072–1082.
Kumar, P.; Govindaraju, M.; Senthamilselvi, S.; Premkumar, K. Colloids Surf. B 2013, 103, 658–661.
Kalwar, N. H.; Sirajuddin; Sherazi, S. H.; Khaskheli, A. R.; Hallam, K. R.; Scott, T. B.; Tagar, Z. A.; Hassan, S. S. Appl. Catal. A: Gen. 2013, 453, 54–59. 35. Peng, H.; Yang, A.; Xiong, J. Carbohydr. Polym. 2013, 91, 348–355.
Philip, D.; Unni, C.; Aromal, S. A.; Vidhu, V. K. Spectrochim. Acta A 2011, 78, 899–904.
Wejrzanowski, T.; Pielaszek, R.; Opalinska, A.; Matysiak, H.; Lojkowski, W.; Kurzydowski, K. J. Appl. Surf. Sci. 2006, 31, 253–264.