Ayşe DEMİR, Abdulhadi BAYKAL, Hüseyin SÖZERİ

Green synthesis of Fe3O4 nanoparticles by one-pot saccharide-assisted hydrothermal method

A saccharide-assisted hydrothermal route starting from a single iron precursor was employed to study the influence of reducing saccharides on the formation of iron oxide (Fe3O4) nanoparticles (NPs). Fe3O4 NPs, which were confirmed by X-ray diffraction analysis, were successfully synthesized by a hydrothermal method in which mannose, maltose, lactose, and galactose served as reducing agents. The formation of Fe3O4 NPs was also confirmed by Fourier transform infrared spectroscopy. Samples exhibited different crystallite sizes estimated based on line profile fitting as 12 \pm 2, 9 \pm 2, 13 \pm 3, and 9 \pm 3 nm for mannose, maltose, lactose, and galactose, respectively. Magnetic characterization results revealed superparamagnetic features of the NPs obtained with galactose, mannose, and maltose.

Anahtar Kelimeler:

Magnetic nanomaterials, Fe3O4, green synthesis, sugars, magnetic properties

Green synthesis of Fe3O4 nanoparticles by one-pot saccharide-assisted hydrothermal method

Keywords:

Magnetic nanomaterials, Fe3O4, green synthesis, sugars, magnetic properties,

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He, Z.; Fang, Y.; Wang, X.; Pang, H. Synth. Met. 2011, 161, 420–425.
G´omez, H.; Ram, M. K.; Alvi, F.; Villalba, P.; Stefanakos, E.; Kumar, A. J. Power Sources 2011, 196, 4102–4108.
Rajesh, T.; Ahuja, D.; Kumar, D. Sens. Actuators B 2009, 136, 275–286.
Jafarzadeh, S.; Adhikari, A.; Sundall, P. E.; Pan, J. Prog. Org. Coat. 2011, 70, 108–115.
Lu, X.; Zhang, W.; Wang, C.; Wen, T. C.; Wei, Y. Prog. Polym. Sci. 2011, 36, 671–712.
Karao˘glu, E.; Baykal, A.; Delig¨oz, H.; S¸enel, M.; S¨ozeri, H.; Toprak, M. S. J. Alloys Compd. 2011, 509, 8460–8468.
Karaoglu, E.; Baykal, A.; Erdemi, H.; Alpsoy, L.; Sozeri, H. J. Alloys Compd. 2011, 509, 9218–9225.
Temizel, E.; Ayan, E.; Senel, M.; Erdemi, H.; Yavuz, M. S.; Kavas, H.; Baykal, A.; ¨Ozt¨urk, R. Mater. Chem. Phys. 2011, 131, 284–291.
Karaoglu, E.; Kavas, H.; Baykal, A.; Toprak, M. S.; S¨ozeri, H. Nano-Micro Lett. 2011, 3, 79–85.
Kemikli, N.; Kavas, H.; Kazan, S.; Baykal, A.; Ozturk, R. J. Alloys Compd. 2010, 502, 439–444.
Si, F.; Li, C. H.; Wang, X.; Yu, D.; Peng, Q.; Li, Y. D. Cryst. Growth Des. 2005, 5, 391–393.
Sun, S. H.; Zeng, H. J. Am. Chem. Soc. 2002, 124, 8204–8205.
Ozkaya, T.; Toprak, M. S.; Baykal, A.; Kavas, H.; K¨oseo˘glu, Y.; Akta¸s, B. J. Alloys Compd. 2009, 472, 18–23. ¨
Tang, N. J.; Zhong, W.; Jiang, H. Y.; Wu, X. L.; Liu, W.; Du, Y. W. J. Magn. Magn. Mater. 2004, 282, 92–95.
Wang, P.; Lee, C.; Young, T. J. Polym. Sci., Part A: Polym. Chem. 2005, 43, 1342–1356.
Cain, J. L.; Harrison, S. R.; Nikles, J. A.; Nikles, D. E. J. Magn. Magn. Mater. 1996, 155, 67–69.
Qian, Y.; Wang, C.; Le, Z. G., Appl. Surf. Sci. 2011, 257, 10758–10762.
Hou, Y. L.; Hiroshi, K.; Masatsugu, S.; Erika, O. S.; Noriaiki, O.; Toshihiro, K.; Toshiaki, O. J. Phys. Chem. B. 2005, 109, 4845–4852.
Mondal, K.; Lorethova, H.; Hippo, E.; Wiltowski, T.; Lalvani, S. B. Fuel Process. Technol. 2004, 86, 33–47.
Jian, P.; Yahui, H.; Yang, W.; Linlin, L. J. Membr. Sci. 2006, 284, 9–16.
Kharissova, O. V.; Dias, H. V. R.; Kharisov, B. I.; P´erez, B. O.; P´erez, V. M. J. Trends Biotechnol. 2013, 31, 240–248.
Panigrahi, S.; Kundu, S.; Kumar, S.; Nath, S.; Pal, T. Colloids Surf. A 2005, 264, 133–138.
Lartigue, L.; Oumzil, K.; Guari, Y.; Larionova, Gu´erin, J. C.; Montero, J. L.; Montero, V. B.; Sangregorio, C.; Caneschi, A.; Innocenti, C.; et al. Org. Lett. 2009, 11, 2992–2995.
Shimomura, M.; Ono, B.; Oshima, K.; Miyauchi, S. Polymer 2006, 47, 5785–5790.
El-Boubbou, K.; Gruden, C.; Huang, X. J. Am. Chem. Soc. 2007, 129, 13392–13393.
Astete, C. E.; Kumar, C. S. S. R.; Sabilov, C. M. Coll., Surf. A: Physicochem. Eng. Aspects 2007, 299, 209–216.
Horac, D.; Babic, M.; Jendelova, P.; Herynek, V.; Trchova, M.; Pientka, Z.; Pollert, E.; Sykova, E. Bioconjugate Chem. 2007, 18, 635–644.
Gittleman, J. I.; Abeles, B.; Bozowski, S. Physical Review B 1974, 9, 3891–3897.
Kumar, A.; Tandon, R. P.; Awana, V. P. S. J. Magn. Magn. Mater 2014, 349, 224–231.
Wejrzanowski, T.; Pielaszek, R.; Opalinska, A.; Matysiak, H.; Lojkowski, W.; Kurzydlowski, K. J. Appl. Surf. Sci. 2006, 253, 204–208.
Pielaszek, R. Analytical expression for diffraction line profile for polydispersive powders, Appl. Crystallography, Proceedings of the XIX Conference, Krakow, Poland, 2003, 43–50.
Kenouche, S.; Larionova, J.; Bezzi, N.; Guari, Y.; Bertin, N.; Zanca, M.; Lartigue, L.; Cieslak, M.; Godin, C.; Morrot, G. Powder Technology 2014, 255, 60–65 .
Lu, W.; Shen, Y.; Xie, A.; Zhang, W. J. Magn. Magn. Mater 2010, 322, 1828–1933.
Sun, X.; Zheng, C.; Zhang, F.; Yang, Y.; Wu, G.; Yu, A.; Guan, N. J. Phys. Chem. C 2009, 113, 16002–16006.
Angyal, S. J. In Glycoscience: Epimerisation, Isomerisation and Rearrangement Reactions of Carbohydrates, Vol. 215; St¨utz, A. E., Ed. Springer-Verlag: Berlin, Germany, 2001, pp. 1–14.
Daniel J.; Reducing sugar structure, http://www.cfs.purdue.edu/fn/fn453/pdf full/Reducing sugar structure.pdf (Accessed on April 30, 2014).
Shafi, K. V. P. M.; Ulman, A.; Yan, X.; Yang, N. L.; Estourn`es, C.; White, H.; Rafailovich, M. Langmuir 2001, 17, 5093–5097.
Tao, Y. T. J. Am. Chem. Soc. 1993, 115, 4350–4358.
Xuan, S.; Hao, L.; Jiang, W.; Gong, X.; Hu, Y.; Chen, Z. J. Magn. Magn. Mater. 2007, 308, 210–213.
Zhang, L.; He, R.; Gu, H. C. Appl. Surf. Sci. 2006, 253, 2611–2617.
Demir, A.; Topkaya, R.; Baykal, A. Polyhedron 2013, 65, 282–287.
Zhang, M.; Zhang, Q.; Itoh, T.; Abe, M. IEEE Trans. Magn. 1994, 30, 4692–4694.
Kodama, R. H.; Berkowitz, A. E.; McNiff, E. J.; Foner, S. Phys. Rev. Lett. 1996, 77, 394–397.
Batlle, X.; Labarta, A. J. Phys. D: Appl. Phys. 2002, 35, R15–R42.