The effect of peripheral circuits on the total $Pi$-electron energies of cyclacenes

The effect of peripheral circuits on the total $Pi$-electron energies of cyclacenes

Within the framework of the Hückel molecular orbital theory, certain linear models are developed to express the contribution of peripheral circuits of cyclacenes into their total $Pi$-electron energies, which explain why cyclacenes exhibit the cryptoannulenic behavior as their peripheral circuits which are annulenic in character.

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