Umesh Nath TRIPATHI, Afshan SIDDIQUI, Jeeven Singh SOLANKI

9084

Synthesis, Spectral Characterization, and Antimicrobial Activity of Arsenic(III) and Bismuth(III) tri[3(2´-hydroxyphenyl)-5-(4-subsituted phenyl)pyrazolinates]

Arsenic(III) tripyrazolinates and bismuth(III) tripyrazolinates of the type M(C15H12N2OX)3 [where C15H12N2OX = 3(2'-hydroxyphenyl)-5-(4-substituted phenyl)pyrazoline] have been synthesized by the reaction of MCl3 and sodium salt of pyrazolines in 1:3 molar ratio in anhydrous benzene at elevated temperature. These newly synthesized derivatives have been characterized by elemental analysis (C, H, N, As, and Bi), molecular weight measurement, spectral [IR and multinuclear NMR (1H & 13C)] and x-ray diffraction studies. The bonding mode of pyrazolines and coordination no. of arsenic(III) and bismuth(III) in these derivatives have been discussed. Antibacterial and antifungal potential of free pyrazoline and some arsenic(III) tripyrazolinates and bismuth(III) tripyrazolinates have also been discussed.
Anahtar Kelimeler:

Arsenic , Bismuth , Pyrazolinates, Antimicrobial activity

Synthesis, Spectral Characterization, and Antimicrobial Activity of Arsenic(III) and Bismuth(III) tri[3(2´-hydroxyphenyl)-5-(4-subsituted phenyl)pyrazolinates]

Arsenic(III) tripyrazolinates and bismuth(III) tripyrazolinates of the type M(C15H12N2OX)3 [where C15H12N2OX = 3(2'-hydroxyphenyl)-5-(4-substituted phenyl)pyrazoline] have been synthesized by the reaction of MCl3 and sodium salt of pyrazolines in 1:3 molar ratio in anhydrous benzene at elevated temperature. These newly synthesized derivatives have been characterized by elemental analysis (C, H, N, As, and Bi), molecular weight measurement, spectral [IR and multinuclear NMR (1H & 13C)] and x-ray diffraction studies. The bonding mode of pyrazolines and coordination no. of arsenic(III) and bismuth(III) in these derivatives have been discussed. Antibacterial and antifungal potential of free pyrazoline and some arsenic(III) tripyrazolinates and bismuth(III) tripyrazolinates have also been discussed.
Keywords:

Arsenic , Bismuth , Pyrazolinates, Antimicrobial activity,

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Turkish Journal of Chemistry-Cover
  • ISSN: 1300-0527
  • Yayın Aralığı: 6
  • Yayıncı: TÜBİTAK
Arşiv
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Synthesis, Spectral Characterization, and Antimicrobial Activity of Arsenic(III) and Bismuth(III) tri[3(2´-hydroxyphenyl)-5-(4-subsituted phenyl)pyrazolinates]

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