[Pd(Me-Xanthate)2]: Synthesis, Characterization, and X-Ray Structure

Potassium methyl xanthate and its complex [Pd(Me-Xanthate)2] were synthesized at room temperature under stirring conditions. The ligand and the complex were characterized by elemental analysis, IR, NMR (1H, 13C) and XRD. NMR data revealed that potassium methyl xanthate acts as a bidentate specie and the complex exhibits 4-coordinated geometry in solution. In solid state, the palladium atom is coordinated to the 2 sulfur atoms of the xanthate ligand and the complex exhibits distorted square planar geometry.

[Pd(Me-Xanthate)2]: Synthesis, Characterization, and X-Ray Structure

Potassium methyl xanthate and its complex [Pd(Me-Xanthate)2] were synthesized at room temperature under stirring conditions. The ligand and the complex were characterized by elemental analysis, IR, NMR (1H, 13C) and XRD. NMR data revealed that potassium methyl xanthate acts as a bidentate specie and the complex exhibits 4-coordinated geometry in solution. In solid state, the palladium atom is coordinated to the 2 sulfur atoms of the xanthate ligand and the complex exhibits distorted square planar geometry.
Turkish Journal of Chemistry-Cover
  • ISSN: 1300-0527
  • Yayın Aralığı: Yılda 6 Sayı
  • Yayıncı: TÜBİTAK
Sayıdaki Diğer Makaleler

Water-gas shift reaction over bimetallic Pt-Ni/ $Al_2O_3$ catalysts

Ahmet Erhan AKSOYLU, Burcu selen ÇAĞLAYAN

[Pd(Me-Xanthate)2]: Synthesis, Characterization, and X-Ray Structure

Saira SHAHZADI, Saqib ALI, Rehana Jabeen And M. Kaleem KHOSA

Synthesis and Biological Activity of 4-(4-Hydroxybenzylidene)-2- (substituted styryl) oxazol-5-ones and Their o-glucosides

Vijay TAILE, Kishor HATZADE, Pravin Gaidhane And Vishwas INGLE

A Mild Method for the Cleavage of Ketals Using IBX

Abdul Rauf RAZA

Investigation of Biodiesel Production from Canola Oil Using Amberlyst-26 as a Catalyst

Oğuzhan İLGEN, Ayşe Nilgün AKIN, Nezahat BOZ

Synthesis, spectral characterization, and antimicrobial activity of arsenic (ııı) and bismuth (ııı) tri (3(2'-hydroxyphenyl)-5-(4-subsituted phenyl) pyrazolinates)

Arpan BHARDWAJ, Tulsi Ram THAPAK, Umesh Nath TRIPATHI, Mohammad Safi AHMAD, Afshan SIDDIQUI, Jeeven Singh SOLANKI

Development of Alumina Supported Alkaline Catalysts Used for Biodiesel Production

Oğuzhan İLGEN, Ayşe Nilgün AKIN

Synthesis of 5-Arylamino-1H (2H)-tetrazoles and 5-Amino-1-aryl-1H-tetrazoles from Secondary Arylcyanamides in Glacial Acetic Acid: A Simple and Efficient Method

Ali Reza Modarresi Alam And Mahmoud NASROLLAHZADEH

Ferric Hydrogen Sulfate as an Efficient Heterogeneous Catalyst for Environmentally Friendly Greener Synthesis of 1,8-Dioxo-Octahydroxanthenes

Hamid Reza SHATERIAN, Asghar Hosseinian And Majid GHASHANG

The Role of the Entropy Factor on the Adsorption of an Optical Brightener on Pulp

Greta RADEVA, Eva VALCHEVA, Stefka VELEVA