Synthesis and Spectral Characterisation of Chloro Organotin(IV) di[3(2`-hydroxyphenyl)-5-(4-substituted phenyl) Pyrazolinates]

Chloro organotin(IV) dipyrazolinates of the type RSnCl(C15H12N2OX)2 [where C15H12N2OX = 3(2'-Hydroxyphenyl)-5(4-X-phenyl)pyrazoline {where X = H (a); CH3 (b); OCH3 (c); Cl (d) and R = Me, Prn and Ph] were synthesised by the reaction of RSnCl3 with sodium salt of pyrazolines in 1:2 molar ratio, in anhydrous benzene. These newly synthesised derivatives were characterised by elemental analysis (C, H, N, Cl and Sn), molecular weight measurement and spectral [IR and multinuclear NMR (1H, 13C and 119Sn)] studies. The bidentate behaviour of the pyrazoline ligands was confirmed by IR, 1H and 13C NMR spectral data. An octahedral structure around the tin(IV) atom for RSnCl(C15H12N2OX)2 is suggested.

Synthesis and Spectral Characterisation of Chloro Organotin(IV) di[3(2`-hydroxyphenyl)-5-(4-substituted phenyl) Pyrazolinates]

Chloro organotin(IV) dipyrazolinates of the type RSnCl(C15H12N2OX)2 [where C15H12N2OX = 3(2'-Hydroxyphenyl)-5(4-X-phenyl)pyrazoline {where X = H (a); CH3 (b); OCH3 (c); Cl (d) and R = Me, Prn and Ph] were synthesised by the reaction of RSnCl3 with sodium salt of pyrazolines in 1:2 molar ratio, in anhydrous benzene. These newly synthesised derivatives were characterised by elemental analysis (C, H, N, Cl and Sn), molecular weight measurement and spectral [IR and multinuclear NMR (1H, 13C and 119Sn)] studies. The bidentate behaviour of the pyrazoline ligands was confirmed by IR, 1H and 13C NMR spectral data. An octahedral structure around the tin(IV) atom for RSnCl(C15H12N2OX)2 is suggested.

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Kaynak Göster

Bibtex @ { tbtkchem142501, journal = {Turkish Journal of Chemistry}, issn = {1300-0527}, eissn = {1303-6130}, address = {}, publisher = {TÜBİTAK}, year = {2007}, volume = {31}, pages = {45 - 54}, doi = {}, title = {Synthesis and Spectral Characterisation of Chloro Organotin(IV) di[3(2`-hydroxyphenyl)-5-(4-substituted phenyl) Pyrazolinates]}, key = {cite}, author = {Trıpathı, Umesh Nath and Ahmad, Mohammad Safi and Venubabu, Goriparthi} }
APA Trıpathı, U , Ahmad, M , Venubabu, G . (2007). Synthesis and Spectral Characterisation of Chloro Organotin(IV) di[3(2`-hydroxyphenyl)-5-(4-substituted phenyl) Pyrazolinates] . Turkish Journal of Chemistry , 31 (1) , 45-54 .
MLA Trıpathı, U , Ahmad, M , Venubabu, G . "Synthesis and Spectral Characterisation of Chloro Organotin(IV) di[3(2`-hydroxyphenyl)-5-(4-substituted phenyl) Pyrazolinates]" . Turkish Journal of Chemistry 31 (2007 ): 45-54 <
Chicago Trıpathı, U , Ahmad, M , Venubabu, G . "Synthesis and Spectral Characterisation of Chloro Organotin(IV) di[3(2`-hydroxyphenyl)-5-(4-substituted phenyl) Pyrazolinates]". Turkish Journal of Chemistry 31 (2007 ): 45-54
RIS TY - JOUR T1 - Synthesis and Spectral Characterisation of Chloro Organotin(IV) di[3(2`-hydroxyphenyl)-5-(4-substituted phenyl) Pyrazolinates] AU - Umesh Nath Trıpathı , Mohammad Safi Ahmad , Goriparthi Venubabu Y1 - 2007 PY - 2007 N1 - DO - T2 - Turkish Journal of Chemistry JF - Journal JO - JOR SP - 45 EP - 54 VL - 31 IS - 1 SN - 1300-0527-1303-6130 M3 - UR - Y2 - 2021 ER -
EndNote %0 Turkish Journal of Chemistry Synthesis and Spectral Characterisation of Chloro Organotin(IV) di[3(2`-hydroxyphenyl)-5-(4-substituted phenyl) Pyrazolinates] %A Umesh Nath Trıpathı , Mohammad Safi Ahmad , Goriparthi Venubabu %T Synthesis and Spectral Characterisation of Chloro Organotin(IV) di[3(2`-hydroxyphenyl)-5-(4-substituted phenyl) Pyrazolinates] %D 2007 %J Turkish Journal of Chemistry %P 1300-0527-1303-6130 %V 31 %N 1 %R %U
ISNAD Trıpathı, Umesh Nath , Ahmad, Mohammad Safi , Venubabu, Goriparthi . "Synthesis and Spectral Characterisation of Chloro Organotin(IV) di[3(2`-hydroxyphenyl)-5-(4-substituted phenyl) Pyrazolinates]". Turkish Journal of Chemistry 31 / 1 (Ocak 2007): 45-54 .
AMA Trıpathı U , Ahmad M , Venubabu G . Synthesis and Spectral Characterisation of Chloro Organotin(IV) di[3(2`-hydroxyphenyl)-5-(4-substituted phenyl) Pyrazolinates]. Turk J Chem. 2007; 31(1): 45-54.
Vancouver Trıpathı U , Ahmad M , Venubabu G . Synthesis and Spectral Characterisation of Chloro Organotin(IV) di[3(2`-hydroxyphenyl)-5-(4-substituted phenyl) Pyrazolinates]. Turkish Journal of Chemistry. 2007; 31(1): 45-54.
IEEE U. Trıpathı , M. Ahmad ve G. Venubabu , "Synthesis and Spectral Characterisation of Chloro Organotin(IV) di[3(2`-hydroxyphenyl)-5-(4-substituted phenyl) Pyrazolinates]", Turkish Journal of Chemistry, c. 31, sayı. 1, ss. 45-54, Oca. 2007
  • ISSN: 1300-0527
  • Yayın Aralığı: Yılda 6 Sayı
  • Yayıncı: TÜBİTAK

10.5b 6.3b

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