Synthesis and electrochemical and spectroelectrochemical characterization of chloromanganese(III) phthalocyanines

The synthesis of novel, symmetrical, tetrasubstituted manganese phthalocyanine complexes bearing 4 hexylthio, 2',3',4',5',6'-pentafluorobenzyloxy, 2',3',5',6'-tetrafluoro-4'-hexylthio-benzyloxy, and 2',3',5',6'-tetrafluoro-4'-pentoxy-benzyloxy units is reported. The new compounds have been characterized by using elemental analyses and UV-Vis, FT-IR, and mass spectroscopic data. The electrochemical properties of the manganese phthalocyanine complexes were investigated by cyclic and square wave voltammetry and the nature of the observed redox processes was studied by spectroelectrochemistry.

Synthesis and electrochemical and spectroelectrochemical characterization of chloromanganese(III) phthalocyanines

The synthesis of novel, symmetrical, tetrasubstituted manganese phthalocyanine complexes bearing 4 hexylthio, 2',3',4',5',6'-pentafluorobenzyloxy, 2',3',5',6'-tetrafluoro-4'-hexylthio-benzyloxy, and 2',3',5',6'-tetrafluoro-4'-pentoxy-benzyloxy units is reported. The new compounds have been characterized by using elemental analyses and UV-Vis, FT-IR, and mass spectroscopic data. The electrochemical properties of the manganese phthalocyanine complexes were investigated by cyclic and square wave voltammetry and the nature of the observed redox processes was studied by spectroelectrochemistry.

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Turkish Journal of Chemistry-Cover
  • ISSN: 1300-0527
  • Yayın Aralığı: Yılda 6 Sayı
  • Yayıncı: TÜBİTAK
Sayıdaki Diğer Makaleler

History, development, and a new concept of phthalocyanines in Turkey

Özer BEKAROĞLU

Water-soluble phthalocyanines containing azo dye; microwave-assisted synthesis and photochemical properties of ZnPcs

Cihan KANTAR, Emrah ATACI, Selami ŞAŞMAZ

Microwave-assisted synthesis and characterization of Co(II) phthalocyanine and investigation of its catalytic activity on 4-nitrophenol oxidation

Ece Tuğba SAKA, Zekeriya BIYIKLIOĞLU, Halit KANTEKİN

Synthesis and characterization of novel 2-{[2-(dimethylamino)ethyl](methyl)amino} ethoxy-substituted metallophthalocyanines

Hilal ZENGİN, Hacer Yasemin YENİLMEZ, Ayfer Kalkan BURAT, Zehra Altuntaş BAYIR

Novel metal-free and metallophthalocyanines containing four 21-membered pentathiadiaza macrocycles: synthesis, characterization, and study of aggregation properties

Halil Zeki GÖK, Berna FARSAK, Hülya KELEŞ, Mustafa KELEŞ

Synthesis and properties of novel polymeric metal-free and metallophthalocyanines containing peripherally long 1,2-bis[(3-oxapropyl)oxa]benzene derivatives

Ahmet BİLGİN, Durmuş YANMAZ, Çiğdem YAĞCI

New soluble amidoamine substituted phthalocyanines: synthesis, characterization, and investigation of their solution properties

Senem ÇOLAK, Salih Zeki YILDIZ

TD-DFT calculations and MCD spectroscopy of porphyrin and phthalocyanine analogues: rational design of photosensitizers for PDT and NIR region sensor applications

John MACK, Martijn WILDERVANCK, Tebello NYOKONG

Diphenylethoxy-substituted metal-free and metallophthalocyanines as potential photosensitizer for photodynamic therapy: synthesis and photophysical and photochemical properties

Yusuf YILMAZ, Ali ERDOĞMUŞ, Muhammet Kasım ŞENER

Synthesis and characterization of tetra-substituted titanium(IV) phthalocyanines with axial ligand

Deniz Kutlu TARAKCI, İlke GÜROL