Synthesis and characterization of hybrid congo red from chloro-functionalized silsesquioxanes

Congo red dye has been bonded to the functionalized octameric polyhedral silsesquioxanes (POSS), which were prepared by hydrolytic condensation of chloro-functionalized organosilicon monomers in the presence of a catalyst. The binding reaction of congo red to the POSS with chloro groups was achieved via the addition of the congo red via NaCl elimination. The structures of POSS with chloro side groups provided an attractive site for binding congo red that not only retains some of its characteristic properties, but also has exceptional hybrid properties possessed by the silica. The dye characteristics of the material were determined by means of UV spectroscopy as well as other conventional techniques.

Synthesis and characterization of hybrid congo red from chloro-functionalized silsesquioxanes

Congo red dye has been bonded to the functionalized octameric polyhedral silsesquioxanes (POSS), which were prepared by hydrolytic condensation of chloro-functionalized organosilicon monomers in the presence of a catalyst. The binding reaction of congo red to the POSS with chloro groups was achieved via the addition of the congo red via NaCl elimination. The structures of POSS with chloro side groups provided an attractive site for binding congo red that not only retains some of its characteristic properties, but also has exceptional hybrid properties possessed by the silica. The dye characteristics of the material were determined by means of UV spectroscopy as well as other conventional techniques.

___

  • Turnell, W. G.; Finch, J. T. J. Mol. Biol. 1992, 227, 1205-1223.
  • Prival, M. J.; Bell, S. J.; Mitchell, V. D.; Peiperl M. D.; Vaughan, V. L. Mutattion Res./Genetic Toxicology 1984, 136, 33-47.
  • Feher, F. J.; Soulivong, D.; Eklund, A. G. Chem. Commun 1998, 399-400.
  • Feher, F. J.; Soulivong, D.; Nguyen, F. Chem. Commun 1998, 1279-1280.
  • Feher, F. J.; Wyndham, K. D.; Knauer D. J. Chem. Commun 1998, 2393-2394.
  • Feher, F. J.; Wyndham, K. D.; Scialdone, M. A.; Hamuro, Y. Chem. Commun 1998, 1469-1470.
  • Feher, F. J.; Soulivong, D.; Eklund, A. G.; Wyndham, K. D. Chem. Commun 1997, 1185-1186.
  • Mantz, R. A.; Jones, P. F.; Chaffe, K. P.; Lichtenhan J. D.; Gilman, J. W. Chem. Mater. 1996, 8, 1250-1259.
  • Feher, F. J.; Soulivong, D. T.; Lewis, G. T. J. Am. Chem. Soc. 1997, 119, 11323-11324.
  • Lee, A.; Lichtenhan, J. D. Macromolecules 1998, 31, 4970-4974.
  • G¨ultek, A.; Se¸ckin T.; Adıg¨uzel, H. ˙I. Turk. J. Chem. 2005, 29, 391-399.
  • Marui, A. N.; Riccardi, C. C.; Williams, R. J. J. Poly. Bull. 2001, 45, 523-530.
  • Sellinger, A.; Laine, R. M. Chem. Mater. 1996, 8, 1592-1593.
  • Feher, F. J.; Phillips, S. H.; Ziller, J. W. J. Am. Chem. Soc. 1997, 119, 3397-3398.
  • Zhang, C.; Babonneau, F.; Bonhemme, C.; Laine, R. M.; Soles, C. L.; Hristov, H. A.; Yee, A. F. J. Am. Chem. Soc. 1998, 120, 8380-8391.
  • Kudo, T.; Gordon, M. S. J. Am. Chem. Soc. 1998, 120, 11432-11438.
  • Sellinger, A.; Laine, R. M. Macromolecules 1996, 29, 2327-2330.
  • Haddad, T. S.; Lichtenhan, J. D. Macromolecules 1996, 29, 7302-7304.
  • Tsuchida, A.; Bolln, C.; Sernetz, F. G.; Frey H.; M¨ulhaupt, R. Macromolecules 1997, 30, 2818-2824.
  • Hedrick, J. L.; Cha, H. J.; Miller, R. D.; Yoon, D. Y.; Brown, H. R.; Srinivasan, S.; Pietro, R. D.; Cook, R. F.; Hummel, J. P.; Klaus, D. P.; Liniger, E. G.; Simonyi, E. E., Macromolecules 1997, 30, 8512-8515.
  • Lee, A.; Lichtenhan, J. D. Macromolecules 1998, 31, 4970-4974.
  • Harkness, B. R.; Takeuchi K.; Tachikawa, M. Macromolecules 1998, 31, 4798-4805.
  • Fasce, D. P.; Williams, R. J. J.; Mechin, F.; Pascault, J. P.; Llauro, M. F.; Petiaud, R. Macromolecules 1999, 32, 4757-4763.
  • Pyun, J.; Matyjaszewski, K. Macromolecules 2000, 33, 217-220.
  • Eisenberg, P.; Erra-Balsells, R.; Ishikawa, Y.; Lucas, J. C.; Mauri, A. N.; Nonami, H; Riccardi, C. C.; Williams, R. J. J. Macromolecules 2000, 33, 1940-1947.
  • Chandrasekhar, V.; Murugavel, R.; Voigt, A.; Roesky, H. W.; Schmidt, H. G.; Noltemeyer, M. Organometallic 1996, 15, 918-922.
  • Klemp, A.; Roesky, H. W.; Schmidt, H. G.; Park, H. S.; Noltemeyer, M. Organometallics 1998, 17, 5225-5227.
  • Duchateau, R.; Abbenhuis, H. C. L.; van Santen, R. A.; Thiele, S. K. H.; van Tol, M. F. H. Organometallics 1998, 17, 5222-5224.
  • Duchateau, R.; Cremer, U.; Harmsen, R. J.; Mohamud, S. I.; Abbenhuis, H. C. L.; van Santen, R. A.; Meetsma, A.; Thiele, S. K. T.; van Tol, M. F. H.; Kranenburg, M. Organometallics 1999, 18, 5447-5459.
  • Duchateau, R.; van Santen, R. A.; Yap, G. P. A. Organometallics 2000, 19, 809-816.
  • Yermiyahu, Z.; Landau, A.; Zaban, A.; Lapides I.; Yariv, S. J. Thermal Analysis and Calorimetry 2003, 72, 431-441.
  • Kiuchi, M.; Uchikawa, A.; Tanigmai, T.; Matsuzawa, S.; Yamura, K. J. Appl. Polym. Sci. 2002, 85, 632-637.
  • Kabalka, G. W.; Namboodri, V.; Akula, M. R. J. Labelled Cpd. Radiopharm. 2001, 44, 921-929.
  • Cui, Y.; Wang, M.; Chen, L.; Qian, G. Dyes and Pigments 2004, 62, 43-47.
  • Lye, J.; Freeman, H. S.; Cox, R. D. Dyes and Pigments 2000, 47, 53-64.
  • Neumann, B. Dyes and Pigments 2002, 52, 47-53.
  • Salem, I. A. Transition Metal Chemistry 2000, 25, 599-604.
  • Denizli, A.; K¨okt¨urk, G.; Salih, B.; Kozluca, A.; Pi¸skin. E. J. Appl. Polym. Sci. 1997, 63, 27-33.
  • Caerts, B.; Mol, V.; Sainte, T.; Wilms, G.; Van Den Berg, V.; Stessens, L. Eur. Radiol. 2001, 7, 474-476.
  • Anderson, S. A.; Frank, J. A.; NMR Biomed. 2007, 20, 200-215.
  • Biswas, S.; Hussain, S. A.; Deb, S.; Nath, R. K.; Bhattacharjee, D.; Spectrochimica Acta Part A. 2006, 65, 628-632.
Turkish Journal of Chemistry-Cover
  • ISSN: 1300-0527
  • Yayın Aralığı: Yılda 6 Sayı
  • Yayıncı: TÜBİTAK
Sayıdaki Diğer Makaleler

Asymmetric synthesis of 8-O-4'-neolignan perseal B

Ya-mu XIA, Wei WANG, Ying-lan Guo And Jun-feng LI, Ying-lan GUO, Jun-feng LI

(E)-3-[(3-(Trifluoromethyl)phenylimino)methyl] benzene-1,2-diol: X-ray and DFT calculated structures

Başak KOŞAR, Çiğdem ALBAYRAK, Mustafa Odabaşoğlu AND

Synthesis, characterization, antibacterial and antifungal evaluation of some new platinum(II) complexes of 2-phenylbenzimidazole ligands

Semra UTKU, Mustafa TOPAL, Aylin DÖĞEN

Electrochemical properties of 1-(o-, m-, p-nitrophenyl)-3-(m-nitrophenyl)- 5-phenylformazans and their nickel complexes

Habibe TEZCAN, Mehmet Levent AKSU

Evaluation of solid-phase extraction sorbent with ketoimine groups for the preconcentration of benzene and phenolic compounds in water

İwona RYKOWSKA, Wiesllaw WASIAK

A theoretical study of the effects of polar substitution on the activation barriers for internal rotation around the C-N bond in p-substituted nitrosobenzenes: comparison of DFT and MP2 calculations

Şafak Özhan Kocakaya And Necmettin PİRİNÇÇİOĞLU

Molecular recognition of aromatic amines by coumarin substituted azacrown ether

Hiten MEHTA, Harjinder Kaur And Shobhana MENON

Mannich base derivatives of 3-hydroxy-6- methyl-4H-pyran-4-one with antimicrobial activity

Demet US, Barkın BERK, Ece GÜRDAL, Nihan AYTEKIN, Tanıl KOCAGÖZ, Berrak ÇAĞLAYAN, İşıl AKSAN KURNAZ, Dilek DEMİR EROL

Synthesis and antimicrobial activities of 2-(5-mercapto)-1,3-oxadiazol-2-ylmethyl-1,2,4-triazol-3-one derivatives

Ahmet DEMİRBAŞ, Deniz ŞAHİN, Neslihan DEMİRBAŞ

Synthesis and characterization of hybrid congo red from chloro-functionalized silsesquioxanes

Ahmet GÜLTEK