Evaluation of solid-phase extraction sorbent with ketoimine groups for the preconcentration of benzene and phenolic compounds in water

The applicability of silica gel, modified with ketoimine groups, to solid phase extraction (SPE) was tested. Basic characteristics of the modified silica were determined using elemental analysis, and 29Si CP MAS NMR spectroscopy, as well as measurement of specific surface area. Some applications of the sorbent studied to preconcentration and further determination of organic compounds, such as benzene, phenol, and o-chlorophenol, by means of solid-phase extraction (SPE) and gas chromatography are presented. The determined recovery rates were about 95%-98%.

Anahtar Kelimeler:

Modified silica, solid-phase extraction SPE, sorbents, hydrocarbon analysis.

Evaluation of solid-phase extraction sorbent with ketoimine groups for the preconcentration of benzene and phenolic compounds in water

Keywords:

Modified silica, solid-phase extraction SPE, sorbents, hydrocarbon analysis.,

PDF

___

Zhang, A.; Li, Q.; Chen, J.; Fei, Z.; Long, C.; Li, W. React. Funct. Polym. 2001, 49, 225-233.
Bianchi F., Careri M., Mucchino C., Musci M. Chromatographia 2002, 55, 595-600.
Kovacs, A.; Kende, A.; Mortl, M.; Volk, G.; Rikker, T.; Torkos, K. J. Chromatogr. A 2008, 1194, 139-142.
Puig, D.; Barcelo, D. Trends Anal. Chem. 1996, 15, 362-365.
Cernakova, M.; Zemanovicova, A. Folia Microbiol. 1998, 43, 411-416.
Li, J.; Zhao, X.; Shi, Y.; Cai, Y.; Mou, S.; Jiang, G. J. Chromatogr. A 2008, 1180, 24-31.
Michaowicz, J.; Duda, W. J. Chemosphere 2007, 66, 657-663.
Saitoh, T.; Kondo, T.; Hiraide, M. J. Chromatogr. A 2007, 1164, 40-47.
Schnatter, R. J. Toxicol. Environ. Health. Part A 2000, 61, 433-437.
Roma-Torres, J.; Teixeira, J. P.; Silva, S.; Laﬀon, B.; Cunha, L. M.; M´endez, J.; Mayan, O. Mutation Research
, 604, 19-27. 11. Eining, T.; Dehnen, W. J. Chromatogr. A 1995, 697, 371-375. 12. Manini, P.; De Palma, G.; Andreoli, R.; Poli, D.; Mozzoni, P.; Folesani, G.; Mutti, A.; Apostoli, P. Toxicology
Soc. 2006, 27, 77-81. 32. Karen, D.; Pawillszyn, J. Environ. Sci. Technol. 1993, 27, 2844-2848. 33. Biernat, J. F.; Makuch, B. Polish. J. Environ. Stud. 2000, 9, 71-75.