Filiz DEREKAYA BALIKÇI, Derya ERMERGEN MERCAN

3124

Selective CO methanation over CeO 2 ZrO 2 -composed NiO and Co 3 O 4 catalysts

Selective CO methanation over CeO 2 ZrO 2 -composed NiO and Co 3 O 4 catalysts

CeO 2 ZrO 2 -composed NiO and Co 3 O 4 catalysts were prepared by 3 different methods. Both CO methana- tion and selective CO methanation were carried out. All catalysts were prepared by (1) co-precipitation, (2) surfactant- assisted co-precipitation, and (3) surfactant-assisted co-precipitation with ultrasound mixing methods. Catalysts were characterized by using N 2 physisorption, XRD, SEM, TEM, and TPR-H 2 techniques. The highest surface area value, uniform pore size distribution, and pores having small diameters were observed for the catalysts prepared by using the surfactant and ultrasound. The NiO/CeO 2 /ZrO 2 prepared by the surfactant-assisted co-precipitation was the most ◦ active catalyst for CO methanation. It gave 50% CO conversion to CH 4 at 150C and all CO was converted to CH 4 ◦◦ after T > 225C. Moreover, 22.3% CH 4 was formed and the CO level decreased below 100 ppm at 200C during the selective CO methanation activity test over this catalyst.
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  • Habazaki, H.; Yamasaki, M.; Zhang, B. P.; Kawashima, A.; Konho, S.; Takai, T.; Hashimoto, K. Appl. Catal. A- Gen. 1998, 172, 131–140.
  • Fujita, S. I.; Takezawa, N. Chem. Eng. J. 1977, 68, 63–68.
  • Xavier, K. O.; Sreekala, R.; Rashid, K. K. A.; Yusuf, K. K. M.; Sen, B. Catal. Today 1999, 49, 17–21.
  • Xu, G.; Chen, X.; Zhang, Z. G. Chem. Eng. J. 2006, 121, 97–107.
  • Galletti, C.; Specchia, S.; Sorocco, G.; Specchia, V. Int. J. Chem. React. Eng. 2007, 5, Article A110.
  • Moretti, E.; Storaro, L.; Talon, A.; Lenarda, M.; Riello, P.; Frattini, R.; Yuso, M. V. M.; Jimenez-Lopez, A.; Rodr ́ıguez-Castellon, E.; Ternero, F.; et al. Appl. Catal. B- Environ. 2011, 102, 627–637.
  • Xu, R.; Wang, X.; Wang, D.; Zhou, K.; Li, Y. J. Catal. 2006, 237, 426–430.
  • Gomez, L. E.; Tiscornia, I. S.; Boix, A. V.; Miro, E. E. Int. J. Hydrogen Energ. 2012, 37, 14812–14819.
  • Takenaka, S.; Shimizu, T.; Otsuka, K. Int. J. Hydrogen Energ. 2004, 29, 1065–1073.
  • Choudhury, M. B. I.; Ahmed, S.; Shalabi, M. A.; Inui, T. Appl. Catal. A- Gen. 2006, 314, 47–53.
  • Panagiotopoulou, P.; Kondarides, D. I.; Verykios, X. E. Appl. Catal. A- Gen. 2008, 344, 45–54.
  • Zhou, G.; Lu, M.; Gu, F.; Wang, S.; Xiu, Z. Mater. Lett. 2005, 59, 2706–2709.
  • Streethawong, T.; Yamada, Y.; Kobayashi, T.; Yoshikawa, S. J. Mol. Catal. A- Chem. 2005, 241, 23–52.
  • Liu, H.; Ma, Z.; Chu, Y.; Sun, W. Colloids and Surfaces A: Physicochemical Engineering Aspects 2006, 287, 10–15.
  • Laosiripojana, N.; Assabumrungrat, S.; Charojrochkul, S. Appl. Catal. A- Gen. 2007, 327, 180–188.
  • Laosiripojana, N.; Sutthisripok, W.; Assabumrungrat, S. Chem. Eng. J. 2007, 127, 31–38.
  • Ganesan, R.; Ham, D. J.; Lee, J. S. Electrochem. Commun. 2007, 9, 2576–2579.
  • Yang, H. M.; Chen, Y. C. J. Taiwan Inst. Chem. E. 2012, 43, 897–903.
  • Chung, H. T.; Hsiao, H. C.; Weng, H. S. J. Chin. Inst. Chem. Eng. 2008, 39, 449–455.
  • Li, H.; Zhang, J.; Li, H. Catal. Commun. 2007, 8, 2212–2216.
  • Lin, S. S. Y.; Daimon, H.; Ha, S. Y. Appl. Catal. A- Gen. 2009, 366, 252–261. Khaodee, W.; Jongsomjit, B.; Assabumrungrat, S.; Praserthdam, P.; Goto, S. Catal. Commun. 2007, 8, 548–556.
  • Fischer, N.; Van Steen, E.; Claeys, M. Catal. Today 2011, 171, 174–179.
  • Takeguchi, T.; Furukawa, S.; Inoue, M. J. Catal. 2011, 202, 14–24.
  • Asencios, Y. J. O.; Assaf, E. M. Fuel Process. Technol. 2013, 106, 247–252.
  • Sing, K. S. W.; Everett, D. H.; Haul, R. A. W.; Moscou, L.; Pierotti, R. A.; Rouquerol, J.; Siemieniewska, T. International Union of Pure and Applied Chemistry 1985, 57, 603–619.
  • Pavasupree, S.; Ngamsinlapasathian, S.; Pivsa-art, S.; Suzuki, Y.; Yoshikawa, S. Asian J. Energ. Environ. 2005, 6, 193–201.
  • Tsoncheva, T.; Ivanova, L.; Micchev, C.; Froba, M. J. Colloid Interf. Sci. 2009, 333, 277–284.
  • Cao, J. L.; Wang, Y.; Zhang, T. Y.; Wu, S. H.; Yuan, Z. Y. Appl. Catal. B- Environ. 2008, 78, 120–128.
  • Jiang, H.; Meng, X.; Dai, H.; Deng, J.; Liu, Y.; Zhang, L.; Zhao, Z. J. Hazard. Mater. 2012, 217–218, 92–99.
  • Xuehong, Z.; Rui, W.; Licheng, L.; Honxing, D.; Guizhen, Z.; Hang, H. Chin. J. Catal. 2011, 32, 827–835.
  • Hernandez, M. L.; Montoya, J. A.; Del Angel, P.; Hernandez, I.; Espinosa, G.; Lianoz, M. E. Catal. Today 2006, 116, 169–178.
  • Boffito, D. C.; Crocella, V.; Pirola, C.; Neppolian, B.; Cerrato, G.; Ashokkumar, M.; Bianchi, C. L. J. Catal. 2013, 297, 17–26.
  • Lee, J., Ashokkumar, M., Kentish, S. E. Ultrason. Sonochem. 2014, 21, 60–68.
  • Guo, Z., Jones, A. G., Li, N., Germena S. Powder Technol. 2007, 171, 146–153.
  • Okkay, H., Bayramoglu, M., Oksuzomer, M. F. Ultrason. Sonochem. 2013, 20, 978–983.
  • Cai, X.; Cai, Y.; Lin, W. J. Nat. Gas Chem. 2008, 17, 201–207.
  • Li, H.; Wang, J. Chem. Eng. Sci. 2004, 59, 4861–4867.
  • Li, H.; Xu, H.; Wang, J. J. Nat. Gas Chem. 2011, 20, 1–8.
  • Dajiang, M.; Yaoqiang, C.; Junber, Z.; Zhenling, W.; Di, M.; Maochu, G. J. Rare Earths 2007, 25, 311–315.
  • Lertwittayanon, K.; Atong, D.; Aungkavattena, P.; Wasanapiarnpong, T.; Wada, S.; Sricharoenchaikul, V. Int. J. Hydrogen Energ. 2010, 35, 12277–12285.
  • Wang, N.; Chu, W.; Zhang, T.; Zhaou, X. S. Chem. Eng. J. 2011, 170, 457–463.
  • Yongzhao, W.; Ruifang, W.; Yongxiang, Z. Catal. Today 2010, 158, 470–474.
  • Batista, M. S.; Santiago, E.; Assaf, E. M.; Ticianelli, E. A. J. Power Sources 2005, 145, 50–54.
  • Wu, R. F.; Zhang, Y.; Wang, Y. Z.; Gao, C. G.; Zhao, Y. X. J. Fuel Chem. Technol. 2009, 37, 578–582.
  • Liu, Q.; Dong, X.; Sons, Y.; Lin, W. J. Nat. Gas Chem. 2009, 18, 173–178.
  • Wang, Y.; Wu, R.; Zhao, Y. Catal. Today 2010, 158, 470–474.
  • Zhang, H.; Dong, Y.; Fang, W.; Lian, Y. Chinese J. Catal. 2013, 34, 330–335.
  • Zyryanova, M. M.; Synthikov, P. V.; Amasov, Yu. I.; Kuzmin, V. A.; Kirilov, V. A.; Sobyanin, V. A. Chem. Eng. J. 2011, 176–177, 106–113.
  • Jiang, M.; Wang, B.; Yao, Y.; Wang, H.; Li, Z.; Ma, X.; Qin, S.; Son, Q. Appl. Catal. A- Gen. 2014, 469, 89–97.
  • Liu, Q.; Dong, X.; Mo, X.; Lin, W. J. Nat. Gas Chem. 2008, 17, 268–272.
Turkish Journal of Chemistry-Cover
  • ISSN: 1300-0527
  • Yayın Aralığı: Yılda 6 Sayı
  • Yayıncı: TÜBİTAK
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