Preparation of porphyrinated polyacrylonitrile fiber mat supported $TiO_2$ photocatalyst and its photocatalytic activities
Preparation of porphyrinated polyacrylonitrile fiber mat supported $TiO_2$ photocatalyst and its photocatalytic activities
Fe(III)meso-tetraphenylporphyrinated polyacrylonitrile fiber mat supported $TiO_2$ photocatalyst (PANC/ $TiO_2$ mat) was prepared via copolymerization and electrospinning. SEM images showed that well-defined fibers with diameters around 1.47 ± 0.26 μm were fabricated from Fe(III)meso-tetraphenylporphyrin (FeTPP)-acrylonitrile copolymer (PANC) and $TiO_2$ mixture. The XRD characterizations demonstrated that the electrospinning process had no effect on the anatase structure of TiO2 . The photocatalytic activity of the PANC/$TiO_2$ mat was examined for the photodegradation of methyl red in aqueous solution under the irradiation of visible light. The results showed that this PANC/$TiO_2$ fiber mat was very efficient for the photodegradation of methyl red, with a degradation percentage over 94%. It is worth noting that the PANC/$TiO_2$ mat could be easily recovered and reused 3 times without any destruction of fiber morphologies.
___
- 1. Soto, M. L.; Moure, A.; Parajo, J.C.; Dominguez, H. J. Food Eng. 2011, 105, 1-27.
- 2. Busca, G.; Berardinelli, S.; Resini, C.; Arrighi, L. J. Hazard. Mater. 2008, 160, 265-288.
- 3. Bhatnagar, A.; Vilar, V. J. P.; Botelho, C. M. S.; Boaventura, R. A. R. Environ Technol. 2011, 32, 231-249.
- 4. Sayılkan, F.; Asilt¨urk, M.; S¸ener, S¸.; Erdemo˘glu, S.; Erdemo˘glu, M.; Sayılkan, H. Turk. J. Chem. 2007, 31, 211-221.
- 5. Wang, C.; Li, J.; Mele, G.; Yang G. M.; Zhang, F. X.; Palmisano, L.; Vasapollo, G. Appl. Catal. B: Environ. 2007, 76, 218-226.
- 6. Pourahmad, A.; Sohrabnezhad, S.; Radaee, E. J. Porous. Mat. 2010, 17, 367-375.
- 7. Alex, S.; Santhosh, U.; Das, S. J. Photoch. Photobio. A 2005, 172, 63-71.
- 8. Gupta, S.; Tripathi, M. Chinese. Sci. Bull. 2011, 56, 1639-1657.
- 9. Wang, C.; Li, J.; Mele, G.; Duan, M. Y.; Lu, X. F.; Palmisano, L.; Vasapollo, G.; Zhang, F. X. Dyes Pigments 2010, 84, 183-189.
- 10. Granados-Oliveros, G.; Paez-Mozo, E. A.; Ortega, F. M.; Ferronato, C.; Chovelon, J. M. Appl. Catal. B: Environ. 2009, 89, 448-454.
- 11. Agarwala, A.; Bandyopadhyay, D. Catal. Lett. 2008, 124, 256-261.
- 12. Hequet, V.; Le Cloirec, P.; Gonzalez, C.; Meunier, B. Chemosphere 2000, 41, 379-386.
- 13. Kim, W.; Park, J.; Jo, H. J.; Kim H, -J.; Choi, W. J. Phys. Chem. C 2008, 112, 491-499.
- 14. Teo, W. E.; Ramakrishna, S. Nanotechnolgoy 2006, 17, 89-106.
- 15. Alves, A. K.; Berutti, F. A.; Bergmann, C. P. J. Environ. Sci. Heal. A 2009, 44, 835-840.
- 16. Huang, Z. M.; Zhang, Y. Z.; Kotaki, M.; Ramakrishna, S. Compos. Sci. Technol. 2003, 63, 2223-2253.
- 17. Beglou, M. J.; Haghi, A. K. Cell. Chem. Technol. 2008, 42, 441-462.
- 18. Son, W. K.; Cho, D.; Park, W. H. Nanotechnology 2006, 17, 439-443.
- 19. Kim, Y. B.; Cho, D. W.; Park, W. H. J. Appl. Polym. Sci. 2010, 116, 449-454.
- 20. Deniz, A. E.; Celebioglu, A.; Kayaci, F.; Uyar, T. Mater. Chem. Phys. 2011, 129, 701-704.
- 21. Dadvar, S.; Tavanai, H.; Dadvar, H.; Morshed, M.; Ghodsi, F. E. J. Sol-Gel. Sci. Techn. 2011, 59, 269-275.
- 22. Shao, L. J.; Liu, J.; Ye, Y. H.; Zhang, X. M.; Qi, C. Z. Appl. Organometal. Chem. 2011, 25, 699-703.
- 23. Wan, L. S.; Wu, J.; Xu, Z. K. Macromol. Rapid Commun. 2006, 27, 1533-1538.
- 24. Fenton, H. J. H. J. Chem. Soc. 1894, 65, 899-905.
- 25. Kim, Y. H.; Jung, Y. S.; Lim, W.T.; Park, J. Y. Environ. Technol. 2009, 30, 183-190.
- 26. Chu, W.; Kwan, C. Y.; Chan, K. H.; Kam, S. K. J. Hazard. Mater. 2005, 121, 119-126.
- 27. Gouterman, M. The Porpyrins (Vol III) [M], Academic Press, New York, 1978.
- 28. McKee, M. G.; Wilkes, G. L.; Colby, R. H.; Long, T. E. Macromolecules 2004, 37, 1760-1767.
- 29. Masocolo, G.; Comparelli, R.; Curri, M. L.; Lovecchio, G.; Lopez, A.; Agostiano, A. J. Hazard. Mater. 2007, 142, 130-137.
- 30. Chan, K. H.; Chu, W. Appl. Catal. B: Environ. 2005, 58, 157-163.
- 31. Li, X. Q.; Cheng, Y.; Kang, S. Z.; Mu, J. Appl. Surf. Sci. 2010, 256, 6705-6709.