Preparation and characterization of an aromatic polyimide and its use as a selective membrane for $H_2O_2$
Preparation and characterization of an aromatic polyimide and its use as a selective membrane for $H_2O_2$
Selectivity behavior to electroactive and non-electroactive substances of a polyimide prepared from 2,2'-dimethyl-4,4'-diaminobiphenyl and the corresponding dianhydride was examined by electrochemical methods. From the excellent electrochemical findings obtained, it was observed that polyimide film was only permeable to hydrogen peroxide among the substances examined. Therefore, it is claimed that the mentioned polymeric film can be successfully used as a hydrogen peroxide-selective membrane in the presence of electroactive and non-electroactive interferents.
___
- 1.S. Isik, S. Alkan, L. Toppare, I. Cianga and Y. Yağcı, European Polymer Journal, 39(12), 2375-2381 Dec(2003).
- 2.S. Tirkes, L. Toppare, S. Alkan, U. Bakir, A. Önen and Y. Yağcı, International Journal of Biological Macromolecules, 30(2) 81-87 Apr 8 (2002).
- 3.Y. Yang, S. Mu and H. Chen, Synthetic Metals, 92 73-178 (1998).
- 4.H. Gülce, İ. Ataman, A. Gülce, &A. Yıldız, Enz. and Microb. Technol., 30, 41-44 (2002).
- 5.K.L. Mittal, Polyimides: Synthesis, Characterization and Applications, Plenum, New York, 1984, Vols.1 & 2.
- 6.M.T. Bessonov, M.M. Koton, V.V. Kudryavtsev, and L.A. Laius, Polyimides: Thermally Stable Polymers,Consultants Bureau, New York, 1987.
- 7.D. Wilson, H.D. Stenzenberger, and P.M. Hergenrother, Polyimides Blackie, Glasgow, 1990.
- 8.M.K. Ghosh and K.L. Mittal, "Polyimides: Fundamentals and Applications," Marcel Dekker, New York 1996.
- 9.K. Yamanaka, M. Jikei, and M.A. Kakimoto; Macromolecules, 33, 6937 (2000).
- 10.J. Fang, H. Kita, and K.I. Okamoto, Macromolecules, 33, 4639 (2000).
- 11.H. Seino, A. Mochizuki, and M. Ueda, J. Polym. Sci. Part A: Polym. Chem. 37, 3584 (1999).
- 12.S. Tamai, A. Yamashita, and A. Yamaguchi, J. Polym. Sci. Part A: Polym. Chem. 36, 1717 (1998).
- 13.C.E. Sroog, J. Poly. Sci. Part C. 16, 1191 (1967).
- 14.Y. Imai, N.N. Maldar, M. Kakimato, J.Poly.Sci. Part A: Poly. Chem. 22, 2189 (1984).
- 15.U. Keller, P. Eiselt, H. Schmidt, J.Poly.Sci. Part A: Poly. Chem. 31, 141 (1993).
- 16.A.E. Lozano, J.G. de la Campa, J. de Abajo and J.Preston, J. Poly. Sci. Part A: Poly. Chem. 35, 873 (1994).
- 17.T. Kaneda, T. Katsura, K. Nakagawa and H. makino, J. App. Poly. Sci. 32, 3151 (1986).i
- 18.L. Xiao, H. Zhang, E. Choe, W. Scanlon, E. Ramanathan, Fuel Chem. Div. Prepr. 48(1), 447 (2003).
- 19.K. Uno, K. Niume, Y. Iwata, F. Toda, Y. Iwakura, J. Poly. Sci. Part A: Poly. Chem. 15, 1309 (1977).
- 20.J.A. Asensio, S. Borros, P. Romeo, J. Poly. Sci. Part A: Poly. Chem. 40, 3703 (2002).
- 21.Y. Skaguchi, K. Kitamura, J. Nakao, S. Hamamoto, H. Tachimori, S. Takase, ACS Poly. Mat. Sci& Eng.(PMSE), 84, 899 (2001).
- 22.J.R. Reynolds, Y. Lee, S. Kim, R.L. Bartling, M.B.Gieselman, C.S.Savage, ACS Poly. Mat. Sci& Eng.(PMSE), 34(1), 1065 (1993)
- 23.N. Venkatasubramanian, T.D. Dang, T.A. Vance, F.E. Arnold, ACS Poly. Mat. Sci& Eng.(PMSE), 84,601 (2001).
- 24.M. Eashoo, Z. Wu, A. Zhang, D. Shen, C. Tse, F.W. Harris, S.Z.D. Cheng, K.H. Gardner, B.S. Hsiao,Macromolecular Chemistry and Physics, 195, 2207-2225 (1994).