Hirihattaya PHETMUNG, Munee WATEH, Chaveng PAKAWATCHAI

4869

Microwave-assisted synthesis, spectroscopy, and crystal structures of $[(H_2 -(4,4'-bipy)]^{2+} [Cr_2O_7]^{2−}$ and one-dimensional polymeric ${[Mn(4,4' -bipy)(Cr_2O_7)(H_2O)_2]}_n$ compounds

Microwave-assisted synthesis, spectroscopy, and crystal structures of $[(H_2 -(4,4'-bipy)]^{2+} [Cr_2O_7]^{2−}$ and one-dimensional polymeric ${[Mn(4,4' -bipy)(Cr_2O_7)(H_2O)_2]}_n$ compounds

A compound (1), [H2 -(4,4' -bipy)$]^{2+}$ [($Cr_2O_7$)$]^{2-}$ and a metal organic-inorganic coordination framework (2), [Mn(4,4'-bipy)($Cr _2O_7$)($H_2 O)_2$] (4,4' bipy=4,4' -bipyridine) were successfully synthesized by microwave method. Their characterization was performed by single crystal X-ray crystallography and FTIR spectroscopy. The crystal structure of 1 revealed a diprotonated 4,4' -bipyridium dichromate compound while compound 2 is an onedimensional (1D) polymer in which ($Cr _20_7)^{2-}$ acts as a bridging ligand supporting the formation of infinite {[Mn(4,4' -bipy)($Cr _2O_7)(H_2 O)_2$ ]}n polymeric chains. The geometry of the 4,4' -bipy ring in 1 is typical coplanar, but twists in 2. In the free molecule 1, dichromate ligand adopts an eclipsed conformation, but adopts a staggered conformation in complex. The principal features of the crystal supramolecularity of 1 and 2 are non-covalent weak interactions which occurred via N-H· · ·O and C-H· · ·O hydrogen bonding.
PDF

___

  • 1. Yaghi, O. M.; O’Keeffe, M.; Ockwig, N. W.; Chae, H. K.; Eddaoudi, M.; Kim J. Nature 2003, 423, 705-714.
  • 2. Parodi, F. SPIE Proceedings 1998, 4017, 2-17.
  • 3. Committee on microwave processing of materials, National materials advisory board, Microwave processing of materials, National Academy Press, Washington, D.C., 1994.
  • 4. Giguere, R. J.; Bray, T. L.; Duncan, S. M. Tetrahedron Lett. 1986, 27, 4945-4948.
  • 5. Baxendale, I. R.; Ley, S. V. Nat. Rev. Drug. Disc. 2002, 1, 573-586.
  • 6. Tan, Y.; Cai, S.; Liao, L.; Wang, Q.; Liu, L. Polym. J. 2009, 41, 899-928.
  • 7. Kajiwara, Y.; Nagai A.; Chujo, Y. Polym. J. 2009, 41, 1080-1084.
  • 8. Doran, T. J.; Lul, P. J; Vanier, G. S.; Collins, M. J.; Wu, B.; Lu, Q. L. Gene. Ther. 2009, 16, 119-126.
  • 9. Horcajada, P.; Chalati, T.; Serre, C.; Gillet, B.; Sebrie, C.; Baati, T.; Eubank, J. F.; Heurtaux, D.; Clayette, P.; Kreuz, C.; Chang, J. S.; Hwang, Y. K.; Marsaud, V.; Bories, P. N.; Cynober, L.; Gil, S.; F´erey, G.; Couvreur, P.; Gref, R. Nat. Mat. 2010, 9, 172-178.
  • 10. Stears, R.L.; Martinsky, T.; Schena, M. Nat. Med. 2003, 9, 140-145.
  • 11. Phetmung, H.; Wongsawat, S.; Pakawatchai; C.; Harding, D. R. Inorg. Chim. Acta. 2009, 362, 2435-2439.
  • 12. Roesky, H. W.; Ruh, M. Coordin. Chem. Rev. 2003, 236, 91-119.
  • 13. Woodward, J. D.; Backov, R.; Abboud, K. A.; Ohnuki, H.; Meisel, M. W.; Talham, D. R. Polyhedron 2003, 22, 2821-2829.
  • 14. Rodman, D. L.; Carrington; N. A.; Xue, Z. L. Talanta 2006, 70, 668-675.
  • 15. a) Cieslak-Golonka; M.; Daszkiewicz, M. Coordin. Chem. Rev. 2005, 249, 2391-2407; b) Sharma, R. P.; Sharma, R.; Bala, R.; Salas; J. M.; Quiros M. J. Chem. Crystallogr. 2005, 35, 769-775.
  • 16. Gili P.; Lorenzo-Luis, P. A. Coordin. Chem. Rev. 1999, 193, 747-768.
  • 17. Chen, X. Y.; Zhao, B.; Cheng, P.; Ding, B.; Liao, D. Z.; Yan; S. P.; Jiang, Z. H. Eur. J. Inorg. Chem. 2004, 3, 562-569.
  • 18. a) Kopf, A. L.; Maggard, P. A.; Stern; C. L.; Poeppelmeier, K. R. Acta Cryst. 2005, C61, m165-m168; b) Karmakar, R.; Choudhury, C. R.; Gramlich V.; Mitra, S. Inorg. Chim. Acta. 2004, 357, 3785-3788; c) Krivovichev, S. V.; Tananaev, I. G.; Kahlenberg, V.; Myasoedov, B. F. Radiochemistry 2006, 48, 213-216.
  • 19. a) Pecoraro, V. L. Manganese Redox Enzymes VCH Publishers Inc., New York, 1992; b) Wieghardt, K. Angew. Chem., Int. Ed. Engl. 1989, 28, 1153-1172; c) Christou, G. Acc. Chem. Res. 1989, 22, 328-335.
  • 20. SMART Version 5.618, Madison, Wisconsin, USA, 2002; Bruker AXS Inc., SAINT Version 6.02a.
  • 21. Kingston, H. M.; Introduction to Microwave Sample Preparation Theory and Practice, American Chemical Society Publishing: Washington DC, 1988.
  • 22. Spek, A. L. PLATON Version of June 2002, University of Utrecht, The Netherlands, 2002.
  • 23. Sheldrick, G. M. SHELXL-97 Program for the Refinement of Crystal Structures University of G¨ottingen, Germany, 1997.
  • 24. Brandenburg, K.; Putz, H. Diamond Version 3 Crystal Impact, Germany, 2005.
  • 25. Martin-Zarza, P.; Gili, P.; Rodriguez-Romero, F. V.; Ruiz-Pere; C.; Solans, X. Polyhedron 1995, 14, 2907-2917.
  • 26. Mestres, J.; Duran, M.; Martin-Zarza, P.; Medina de la Rosa; E.; Gili, P. Inorg. Chem. 1993, 32, 4708-4713.
  • 27. Brandon; J. K.; Brown, I. D. Can. J. Chem. 1968, 46, 933-941.
  • 28. Nedelcu, A.; Zak, Z.; Madalan, A. M.; Pinkas, J.; Ruh, M. Polyhedron 2003, 22, 789-794.
  • 29. Dave, B. C.; Czernuszewicz, R. S. Inorg. Chem. 1994, 33, 847-848.
Turkish Journal of Chemistry-Cover
  • ISSN: 1300-0527
  • Yayın Aralığı: 6
  • Yayıncı: TÜBİTAK
Arşiv
Sayıdaki Diğer Makaleler

Facile and rapid synthesis of some novel polysubstituted imidazoles by employing magnetic $Fe_3O_4$ nanoparticles as a high efficient catalyst

Khalil ESKANDARI, Abdolmohammad GHASEMI, Bahador KARAMI

In situ formed 1-hexyl-3-methylimidazolium hexafluorophosphate for dispersive liquid-liquid microextraction of Pd(II) prior to electrothermal AAS and spectrophotometry

Habibollah ESKANDARI

Microwave-assisted synthesis, spectroscopy, and crystal structures of [(H2-(4,4'-bipy)]2+ [Cr2O7]2- and one-dimensional polymeric {[Mn(4,4'-bipy)(Cr2O7)(H2O)2]\}n compounds

Hirihattaya PHETMUNG, Munee WATEH, Chaveng PAKAWATCHAI

Design, synthesis, and biological evaluation of indole-based 1,4-disubstituted piperazines as cytotoxic agents

Meriç KÖKSAL AKKOÇ, Mine YARIM YÜKSEL, İrem DURMAZ

Determination of lidocaine based on electrocatalysis of a chemically modified electrode

Gamze TAN, Gülçin BOLAT, Mehmet Ali ONUR, Serdar ABACI

Simultaneous determination of dopamine, uric acid, and tryptophan using an MWCNT modified carbon paste electrode by square wave voltammetry

Hadi BEITOLLAHI, Alireza MOHADESI, Saeedeh KHALILIZADEH MAHANI

Three-component Passerini-Smiles coupling reaction of aldehydes and isocyanides with tropolone catalyzed by silica nanoparticles

Abdolhossain MASSOUDI, Issa AMINI, Ali RAMAZANI And

Titrimetric determination of anionic surfactant content in anionic/nonionic surfactant mixture solution by anionic surfactant selective electrode

Junwei WANG, Zhiping DU, Wanxu WANG, Wei XUE

Synthesis and structural characterization of novel square pyramidal oxovanadium(IV) complexes with ligands having N and O donor atoms

Ashok Kumar YADAVA, Hardeo Singh YADAV, Uma Shanker YADAV

A new absorption based CO2 sensor based on Schiff base doped ethyl cellulose

Sevinç Zehra TOPAL, Kadriye ERTEKİIN, Berrin YENİIGÜL, Ayşe ERÇAĞ