Emine Özge ÖZCAN, Deniz MERCAN, Nevin GÜRBÜZ, Engin ÇETİNKAYA

7022

In situ catalytic activities of 1,3-dialkyltetrahydropyrimidinium salts/[RuCl2(p-cymene)]2 system for transfer hydrogenation reactions

Hydrogen-transfer reduction processes are attracting increasing interest from synthetic chemists in view of their operational simplicity. In the present study novel ruthenium carbene complexes were generated in situ and tested for their transfer hydrogenation reactions. The in situ prepared 3 component 1,3-dialkyltetrahydropyrimidinium salts (LHX)/[RuCl2(p-cymene)]2 and KOH catalyzed quantitatively the transfer hydrogenation of ketones under mild reaction conditions in 2-propanol.
Anahtar Kelimeler:

Ruthenium, tetrahydropyrimidin-2-ylidene, N-heterocyclic carbene, transfer hydrogenation, ketone

In situ catalytic activities of 1,3-dialkyltetrahydropyrimidinium salts/[RuCl2(p-cymene)]2 system for transfer hydrogenation reactions

Hydrogen-transfer reduction processes are attracting increasing interest from synthetic chemists in view of their operational simplicity. In the present study novel ruthenium carbene complexes were generated in situ and tested for their transfer hydrogenation reactions. The in situ prepared 3 component 1,3-dialkyltetrahydropyrimidinium salts (LHX)/[RuCl2(p-cymene)]2 and KOH catalyzed quantitatively the transfer hydrogenation of ketones under mild reaction conditions in 2-propanol.
Keywords:

Ruthenium, tetrahydropyrimidin-2-ylidene, N-heterocyclic carbene, transfer hydrogenation, ketone,

PDF
Turkish Journal of Chemistry-Cover
  • ISSN: 1300-0527
  • Yayın Aralığı: Yılda 6 Sayı
  • Yayıncı: TÜBİTAK
Arşiv
Sayıdaki Diğer Makaleler

A computational study on substituted diazabenzenes

Selçuk GÜMÜŞ

In situ catalytic activities of 1,3-dialkyltetrahydropyrimidinium salts/[RuCl2(p-cymene)]2 system for transfer hydrogenation reactions

Emine Özge ÖZCAN, Deniz MERCAN, Nevin GÜRBÜZ, Engin ÇETİNKAYA

Synthesis of starch-g-poly(acrylic acid-co-2-hydroxy ethyl methacrylate) as a potential pH-sensitive hydrogel-based drug delivery system

Mohammad SADEGHI

Polyphenolic compounds from Geranium purpureum Vill. growing in Turkey

Didem ŞÖHRETOĞLU, Mahmut Koray SAKAR, Olov STERNER

In situ catalytic activities of 1,3-dialkyltetrahydropyrimidinium salts/[$RuCl_2(p-cymene)]_2$ system for transfer hydrogenation reactions

Nevin GÜRBÜZ, İsmail ÖZDEMİR, Engin ÇETİNKAYA, Bekir ÇETİNKAYA, Emine Özge ÖZCAN, Deniz MERCAN

Studies on the mechanism of phosphazene ring-opening polymerization (ROP)

Selen BİLGE

Electrocatalytic oxidation of methanol at Pd and Pt ad-layer modified Au(111) electrodes in alkaline solution

Süleyman KOÇAK, Zekerya DURSUN, Fatma Nil ERTAŞ

Electrochemical impedance spectroscopy study on intercalation and anomalous diffusion of $AlCl^-_4$ ions into graphite in basic molten salt

Ali EHSANI, Mohammad Ghasem MAHJANI, Majid JAFARIAN

Preparation and characterization of a series of thiourea derivatives as phase change materials for thermal energy storage

Cemil ALKAN, Yusuf TEK, Derya KAHRAMAN

Electrochemical impedance spectroscopy study on intercalation and anomalous diffusion of AlCl4- ions into graphite in basic molten salt

Ali EHSANI, Mohammad Ghasem MAHJANI, Majid JAFARIAN