Liliana Marinela ŞTEFAN, Ana-Maria PANA, Mihai-Cosmin PASCARIU

17799

Synthesis and characterization of a new methacrylic glycomonomer

The carbohydrate containing monomer 3-O-(2'-hydroxy-3'- methacryloyloxypropyl)-1,2:5,6-di-O-isopropylidene-a -D-glucofuranose was easily prepared from D-glucose and methacrylic acid in 4 steps. The structure of the new methacrylic monomer was confirmed using FTIR, NMR (including 1H-NMR, 13C-NMR, COSY, HMQC and HMBC), and HPLC-MS. This work is part of our group's effort to obtain new polymers based on renewable resources with enhanced biodegradability and biocompatibility.

Anahtar Kelimeler:

D-glucose, glycomonomer, biodegradability, methacrylic acid, epoxidation

Synthesis and characterization of a new methacrylic glycomonomer

The carbohydrate containing monomer 3-O-(2'-hydroxy-3'- methacryloyloxypropyl)-1,2:5,6-di-O-isopropylidene-a -D-glucofuranose was easily prepared from D-glucose and methacrylic acid in 4 steps. The structure of the new methacrylic monomer was confirmed using FTIR, NMR (including 1H-NMR, 13C-NMR, COSY, HMQC and HMBC), and HPLC-MS. This work is part of our group's effort to obtain new polymers based on renewable resources with enhanced biodegradability and biocompatibility.

Keywords:

D-glucose, glycomonomer, biodegradability, methacrylic acid, epoxidation,

Turkish Journal of Chemistry-Cover

ISSN: 1300-0527
Yayın Aralığı: 6
Yayıncı: TÜBİTAK

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