Somayeh GHAMARI, Massomeh GHORBANLOO, Hidenori YAHIRO

5988

Encapsulation of copper(II) complexes with three dentate NO2 ligands derived from 2,6-pyridinedicarboxylic acid in NaY zeolite

Encapsulation of copper(II) complexes with three dentate NO2 ligands derived from 2,6-pyridinedicarboxylic acid in NaY zeolite

Abstract: 2,6-Pyridinedicarboxylic acid (H2dipic) reacts with copper-exchanged zeolite NaY to form [Cu(dipic)(H2O)2]n, which is encapsulated in the pores of the zeolite. In this zeolite-encapsulated form, the copper derivative functions as an efficient catalyst for the oxidation of cyclohexene, toluene, cyclohexane, and ethyl benzene in the presence of hydrogen peroxide (as an oxidant). The catalyst was readily recovered from the reaction mixture, and it could be reused for an additional three runs without perceptible loss of activity. The heterogeneous catalyst exhibited considerably higher activity and selectivity compared with [Cu(dipic)(H2O)2]n itself.
PDF

___

  • Baca, S. G.; Reetz, M. T.; Goddard, R.; Filippova, I. G.; Simonov, Y. A.; Gdaniec, M.; Gerbeleu, N. Polyhedron 2006, 25, 1215–1222.
  • Ghorbanloo, M.; Rahmani, S.; Yahiro, H. Transit. Metal. Chem. 2013, 38, 725–732.
  • Mozgawa, W.; Krol, M.; Pichor, W. J. Hazard. Mater. 2009, 168, 1482–1489.
  • Kumar Bansala, V.; Protasis Thankachana, P.; Prasad, R. Appl. Catal. A: Gen. 2010, 381, 8–17.
  • Jin, C.; Fan, W.; Jia, Y.; Fan, B.; Ma, J.; Li, R. J. Mol. Catal. A: Chem. 2006, 249, 23–30.
  • Ghorbanloo, M.; Hosseini-Monfared, H.; Janiak, C. J. Mol. Catal. A: Chem. 2011, 345, 12–20.
  • Ghorbanloo, M.; Jaworska, M.; Paluch, P.; Li, G. D.; Zhou, L. Transit. Metal. Chem. 2013, 38, 511–521.
  • Ghorbanloo, M.; Tarasi, R.; Tao, J.; Yahiro, H. Turk. J. Chem. 2014, 38, 488–503.
  • Fan, B.; Li, H.; Fan, W.; Jin, C.; Li, R. Appl. Catal. A: Gen. 2008, 340, 67–75.
  • Xie, C.; Zhang, Z.; Wang, Z.; Liu, X.; Shen, G.; Wang, R.; Shen, D. J. Coord. Chem. 2004, 57, 1173–1178.
  • Van Albada, G. A.; Haasnoot, J. G.; Reedijk, J.; Biagini-Cingi, M.; Manotti-Lanfredi, A. M.; Ugozzoli, F. Polyhe- dron 1995, 14, 2467–2473.
  • Carmona, P. Spectrochim Acta A-M. 1980, 36, 705–712.
  • Li, W.; Juan, L.; En-bo, W. Chem. Res. Chinese. U. 2004, 20, 127–130.
  • Nakamoto, K. Infrared and Raman Spectra of Inorganic and Coordination Compounds. Wiley, New York, NY, USA 1986.
  • Bloomquist, D. R.; Willet, R. D. Coord. Chem. Rev. 1982, 47, 125–164.
  • Abraham, R.; Yuseff, K. K. M. J. Mol. Catal. A, Chem. 2003, 198, 175–183.
  • Bennur, T. H.; Srinivas, D.; Sivasanker, S. J. Mol. Catal. A: Chem. 2004, 207, 163–171.
  • Kapoor, P.; Pathak, A.; Kapoor, R.; Venugopalan, P.; Corbella, M.; Rodriguez, M.; Robles, J.; Llobet, A. Inorg. Chem. 2002, 41, 6153–6160.
  • Koval, I. A.; Sgobba, M.; Huisman, M.; Luken, M.; Saint-Aman, E.; Gamez, P.; Krebs, B.; Reedijk. J . Inorg. Chim. Acta. 2006, 359, 4071–4078.
  • Alves, W. A.; de Almeida Santos, R. H.; Paduan-Filho, A.; Becerra, C. C.; Borin, A. C.; Da Costa Ferreira, A. M. Inorg. Chim. Acta. 2004, 357, 2269–2278.
  • Singh, L. J.; Devi, N. S.; Devi, S. P.; Devi, W. B.; Singh, R. K. H.; Rajeswari, B.; Kadam, R. M. Inorg. Chem. Commun. 2010, 13, 365–368.
  • Hoffmann, S. K.; Towle, D.; Hatfield, W. E.; Chaudhuri, P.; Wieghardt, K. Inorg. Chem. 1985, 24, 1307–1312.
  • Gelasco, A.; Kirk, M. L.; Kampf, J. W.; Pecoraro, V. L. Inorg. Chem. 1997, 36, 1829–1837.
  • Salavati-Niasari, M.; Salimi, Z.; Bazarganipour, M.; Davar, F. Inorg. Chim. Acta 2009, 362, 3715–3724.
  • Parida, K. M.; Sahoo, M.; Singha, S. J. Catal. 2010, 276, 161–169.
  • Hosseini-Monfared, H.; Kheirabadi, S.; Asghari-Lalami, N.; Mayer, P. Polyhedron 2011, 30, 1375–1384.
  • de Vos, D.; Bein, T. Chem. Commun. 1996, 8, 917–918.
  • Jin, C.; Fan, W.; Jia, Y.; Fan, V.; Ma, J.; Li, R. J. Mol. Catal. A: Chem. 2006, 249, 23–30.
  • Xavier, K. O.; Chacko, J.; Mohammed Yusuff, K. K. Appl. Catal. A: Gen. 2004, 258, 251–259.
  • Salavati-Niasari, M. J. Mol. Catal. A: Chem. 2008, 284, 97–107.
  • Salavati-Niasari, M. J. Mol. Catal. A: Chem. 2008, 283, 120–128.
  • De Vos, D. E.; Dams, M.; Sels, B. F.; Jacobs, P. A. Chem. Rev. 2002, 102, 3615–3640.
  • Cardoso, B.; Pires, J.; Carvalho, A. P.; Kuzniarska-Biernacka , I.; Silva, A. R.; de Castro, B.; Freire, C. Micropor. Mesopor. Mater. 2005, 86, 295–302.
  • Farzaneh, F.; Soleimannejad, J.; Ghandi, M. J. Mol. Catal. A. 1997, 118, 223–227.
Turkish Journal of Chemistry-Cover
  • ISSN: 1300-0527
  • Yayın Aralığı: 6
  • Yayıncı: TÜBİTAK
Arşiv
Sayıdaki Diğer Makaleler

Characterization of a Cu$^{2+}$-selective fluorescent probe derived from rhodamine B with 1,2,4-triazole as subunit and its application in cell imaging

Na LI, Chunwei YU, Yuxiang JI, JUN ZHANG

One-pot and solvent-free synthesis of 3-(9-hydroxy-3-methoxy-7-aryl-6,7,9,10-tetrahydro-5$H$-benzo[$h$]thiazolo[2,3-$b$]quinazolin-9-yl)-2$H$-chromen-2-ones and their antibacterial evaluation

RAVIBABU VELPULA, JANARDHAN BANOTHU, RAJITHA GALI, YAKAIAH SARGAM, RAJITHA BAVANTULA

Green synthesis of 2-amino-7-hydroxy-4-aryl-4$H$-chromene-3-carbonitriles using ZnO nanoparticles prepared with mulberry leaf extract and ZnCl$_{2}$

AKBAR MOBINIKHALEDI, ATISA YAZDANIPOUR, MAJID GHASHANG

Synthesis, characterization, biological studies, and molecular modeling of mixed ligand bivalent metal complexes of Schiff bases based on $N$-aminopyrimidine-2-one/2-thione

HATİCE GAMZE SOĞUKÖMEROĞULLARI, TUĞBA TAŞKIN TOK, FEYZA YILMAZ, İSMET BERBER, MEHMET SÖNMEZ

Kojic acid in organic synthesis

MARYAM ZIRAK, BAGHER EFTEKHARI-SIS

Encapsulation of copper(II) complexes with three dentate NO$_{2}$ ligands derived from 2,6-pyridinedicarboxylic acid in NaY zeolite

MASSOMEH GHORBANLOO, SOMAYEH GHAMARI, HIDENORI YAHIRO

Sustainable activity of hydrothermally synthesized mesoporous silicates in acetic acid esterification

VELİ ŞİMŞEK, LEVENT DEĞİRMENCİ, KIRALİ MÜRTEZAOĞLU

The effect of temperature and concentration for methanol electrooxidation on Pt-Ru catalyst synthesized by microwave assisted route

HİLAL DEMİR KIVRAK

One-pot and solvent-free synthesis of 3-(9-hydroxy-3-methoxy-7-aryl-6,7,9,10-tetrahydro-5H-benzo[h]thiazolo[2,3-b]quinazolin-9-yl)-2H-chromen-2-ones and their antibacterial evaluation

Ravibabu VELPULA, Janardhan BANTHU, Rajitha GALI, Rajitha BAVANTULA, Yakaiah SARGAM

Acid-free synthesis of S-nitrosothiols at neutral pH by shock-freezing in liquid nitrogen

DIMITRIOS TSIKAS, Dimitrios TSIKAS, ANKE BÖHMER, ARNE TRETTIN, ARSLAN ARINÇ KAYAÇELEBİ