Crystal structure of dichlorodiaquabis-(p-dimethylaminobenzaldehyde) manganese (II)

Crystal structure of dichlorodiaquabis-(p-dimethylaminobenzaldehyde) manganese (II)

The crystal structure of dichlorodiaquabis-(p-dimethylammobenzaldehyde)manganese(II), $[MnCl_2 (OH_2)_2(C_9H_{11}NO)_2]$, was determined from X-ray intensity data. The structure consists of the isolated molecules of the complex. The central Mn atom in the complex is coordinated by txo p-dimethylaminobenzaldehyde and two water molecules and also two chlorine atoms, resulting in a distorted octahedral environment. The same molecules or ions occupy trans positions. The crystal structure is stabilized by weak hydrogen bonds present between the isolated molecules.

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  • 1. P. Byrom and J.H. Turnbull,Talanta 10, 1217-21 (1963).
  • 2. M. Pesez and A. Petit,Bull. Soc. Chim. Fr., 122-128 (1947).
  • 3. V.I. Rychkova and Y.I. Belskaya,Energetik 3, 28-33 (1984).Chem. Abstr. 101, 287 (1984).
  • 4. H. Falter, K. Jayasimhulu and R.A. Day,Analyt. Biochem. 67, 359-366 (1975).
  • 5. A.A. Kulikov, M.K. Lukyanova and A.V. Nishlyuk,Neftepererab. Neftekhim. 9, 31-32 (1988).Chem.Abstr. 109, 184 (1988).
  • 6. M.S. Kravchenko, A.V. Chernaya, L.V. Tokar and V.N. Kleshchevnikova,Khim. Tekhnol. Vody 10, 126-129(1988).Chem.Abstr.109, 317 (1988).
  • 7. E. Sawicki and C.R. Sawicki,Aldehydes-Photometric Analysis", Vols. 1 and 2, Academic Press, NewYork, 1975.
  • 8. H.S. Rathore, A. Mohammad, F. Prakash and K. Kumari,J.Chem.Sci.6, 20-51 (1980).Chem. Abstr.96, 830 (1982).
  • 9. J.G. Rosencrance and P.W. Jagodzinski,Spectrochim. Acta, 42A, 869-879 (1986).
  • 10. J.K. Dattagupta and N.N. Saha,Acta Cryst. B29, 1228 (1973).
  • 11. C. Mahadevan, M. Seshasayee and A.S. Kothiwal,Crys. Struct. Commun. 11, 1725-30 (1982).Chem.Abstr. 99, 510 (1983).
  • 12. T.K. Yazclar, V.T. Ylmaz and H. ̈Olmez,Synth. React. Inorg. Met-Org. Chem. 27,825-833 (1997).
  • 13. R.A. Howie,RDNIC, Data Reduction Program for Nicolet P3 Di ractometer", Univ. of Aberdeen,Scotland 1980
  • 14. G.M. Sheldrick,Acta Cryst. A46, 467 (1990).
  • 15. G.M. Sheldrick,SHELX76, Program for Crystal Structure Determination", Univ. of Cambridge,England 1976.
  • 16.International Tables for X-ray Crystallography", Vol.4, Kynoch Press, Birmingham, U.K., 1974.
  • 17. P.D.G. Cradwick, PLOTAID,A Fortran Program for the Preparation of Molecular Drawings",Macaulay Land Use Research Inst., Aberdeen Scotland (1970).
  • 18. P. McArdle,J. Appl. Cryst. 27, 438 (1994).
  • 19. T.C.W. Mak and J. Trotter,Acta Cryst. 18, 68-74 (1965).
Turkish Journal of Chemistry-Cover
  • ISSN: 1300-0527
  • Yayın Aralığı: Yılda 6 Sayı
  • Yayıncı: TÜBİTAK