A novel selective fluorescent chemosensor for Fe3+ ions based on phthalonitrile dimer: synthesis, analysis, and theoretical studies

Öz Phenyl-4,4-di(3,6-dibutoxyphthalonitrile) (3) was synthesized by the reaction of 1,4-phenylenebisboronic acid (1) and 4-bromo-3,6-dibutoxyphthalonitrile (2), using Suzuki cross-coupling reaction. The newly synthesized compound (3) was characterized by FT-IR, MALDI-MS, ESI-MS, 1H-NMR, 13C-NMR, and 13C-DEPT-135-NMR. The fluorescence property of phenyl-4,4-di(3,6-dibutoxyphthalonitrile) (3) towards various metal ions was investigated by fluorescence spectroscopy, and it was observed thatthe compound (3) displayed a significantly ‘turn-off’ response to Fe3+, which was referred to 1:2 complex formation between ligand (3) and Fe3+. The compound was also studied via density functional theory calculations revealing the interaction mechanism of the molecule with Fe3+ ions.

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Kaynak Göster

Bibtex @araştırma makalesi { tbtkchem945450, journal = {Turkish Journal of Chemistry}, issn = {1300-0527}, eissn = {1303-6130}, address = {}, publisher = {TÜBİTAK}, year = {2020}, volume = {44}, pages = {1254 - 1264}, doi = {}, title = {A novel selective fluorescent chemosensor for Fe3+ ions based on phthalonitrile dimer: synthesis, analysis, and theoretical studies}, key = {cite}, author = {Al-raqa, Shaya and Omeroglu, Ipek and Erbahar, Dogan and Durmus, Mahmut} }
APA Al-raqa, S , Omeroglu, I , Erbahar, D , Durmus, M . (2020). A novel selective fluorescent chemosensor for Fe3+ ions based on phthalonitrile dimer: synthesis, analysis, and theoretical studies . Turkish Journal of Chemistry , 44 (5) , 1254-1264 .
MLA Al-raqa, S , Omeroglu, I , Erbahar, D , Durmus, M . "A novel selective fluorescent chemosensor for Fe3+ ions based on phthalonitrile dimer: synthesis, analysis, and theoretical studies" . Turkish Journal of Chemistry 44 (2020 ): 1254-1264 <
Chicago Al-raqa, S , Omeroglu, I , Erbahar, D , Durmus, M . "A novel selective fluorescent chemosensor for Fe3+ ions based on phthalonitrile dimer: synthesis, analysis, and theoretical studies". Turkish Journal of Chemistry 44 (2020 ): 1254-1264
RIS TY - JOUR T1 - A novel selective fluorescent chemosensor for Fe3+ ions based on phthalonitrile dimer: synthesis, analysis, and theoretical studies AU - Shaya Al-raqa , Ipek Omeroglu , Dogan Erbahar , Mahmut Durmus Y1 - 2020 PY - 2020 N1 - DO - T2 - Turkish Journal of Chemistry JF - Journal JO - JOR SP - 1254 EP - 1264 VL - 44 IS - 5 SN - 1300-0527-1303-6130 M3 - UR - Y2 - 2020 ER -
EndNote %0 Turkish Journal of Chemistry A novel selective fluorescent chemosensor for Fe3+ ions based on phthalonitrile dimer: synthesis, analysis, and theoretical studies %A Shaya Al-raqa , Ipek Omeroglu , Dogan Erbahar , Mahmut Durmus %T A novel selective fluorescent chemosensor for Fe3+ ions based on phthalonitrile dimer: synthesis, analysis, and theoretical studies %D 2020 %J Turkish Journal of Chemistry %P 1300-0527-1303-6130 %V 44 %N 5 %R %U
ISNAD Al-raqa, Shaya , Omeroglu, Ipek , Erbahar, Dogan , Durmus, Mahmut . "A novel selective fluorescent chemosensor for Fe3+ ions based on phthalonitrile dimer: synthesis, analysis, and theoretical studies". Turkish Journal of Chemistry 44 / 5 (Ekim 2020): 1254-1264 .
AMA Al-raqa S , Omeroglu I , Erbahar D , Durmus M . A novel selective fluorescent chemosensor for Fe3+ ions based on phthalonitrile dimer: synthesis, analysis, and theoretical studies. Turk J Chem. 2020; 44(5): 1254-1264.
Vancouver Al-raqa S , Omeroglu I , Erbahar D , Durmus M . A novel selective fluorescent chemosensor for Fe3+ ions based on phthalonitrile dimer: synthesis, analysis, and theoretical studies. Turkish Journal of Chemistry. 2020; 44(5): 1254-1264.
IEEE S. Al-raqa , I. Omeroglu , D. Erbahar ve M. Durmus , "A novel selective fluorescent chemosensor for Fe3+ ions based on phthalonitrile dimer: synthesis, analysis, and theoretical studies", Turkish Journal of Chemistry, c. 44, sayı. 5, ss. 1254-1264, Eki. 2020
  • ISSN: 1300-0527
  • Yayın Aralığı: Yılda 6 Sayı
  • Yayıncı: TÜBİTAK

18.1b 10.5b

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