Synthesis of nonperipherally tetra-[5-(diethylamino)-2-formylphenoxy] substituted metallophthalocyanines and their electrochemistry
3-[5-(diethylamino)-2-formylphenoxy]phthalonitrile (n-TY-CN), metallophthalocyanines n-TY-Co, n-TY-Cu, and n-TY-Mn bearing [5-(diethylamino)-2-formylphenoxy] groups at nonperipheral positions were prepared for the first time. These compounds were characterized with IR, NMR (only for n-TY-CN), mass and UV-vis (except n-TY-CN) spectroscopy. Voltammetric characterizations of n-TY-Co, n-TY-Cu, and n-TY-Mn revealed that while n-TY-Co, n-TY-Cu, and n-TY-Mn showed characteristic Pc ring and/or metal-based reduction reaction, n-TY-Co, n-TY-Cu, and n-TY-Mn were coated on the working electrode during the oxidation processes owing to the cationic electropolymerizations of the [5-(diethylamino)-2-formylphenoxy] substituents.
___
- Akyuz D, 2020, J MOL STRUCT, V1206, DOI 10.1016/j.molstruc.2019.127674
- Akyuz D, 2017, ELECTROANAL, V29, P2913, DOI 10.1002/elan.201700366
- Attia MS, 2019, TALANTA, V201, P185, DOI 10.1016/j.talanta.2019.03.119
- Barut B, 2020, DYES PIGMENTS, V172, DOI 10.1016/j.dyepig.2019.107794
- Barut B, 2016, DALTON T, V45, P14301, DOI 10.1039/c6dt02720b
- Bas H, 2017, INORG CHIM ACTA, V467, P56, DOI 10.1016/j.ica.2017.07.042
- Biyiklioglu Z, 2020, TURK J CHEM, V44, P687, DOI 10.3906/kim-2001-54
- Biyiklioglu Z, 2020, J MOL STRUCT, V1212, DOI 10.1016/j.molstruc.2020.128144
- Biyiklioglu Z, 2018, DYES PIGMENTS, V148, P417, DOI 10.1016/j.dyepig.2017.09.051
- Biyiklioglu Z, 2017, J MOL STRUCT, V1148, P15, DOI 10.1016/j.molstruc.2017.07.021
- Biyiklioglu Z, 2015, DALTON T, V44, P18993, DOI 10.1039/c5dt03421c
- Biyiklioglu Z, 2014, SYNTHETIC MET, V196, P166, DOI 10.1016/j.synthmet.2014.07.023
- Biyiklioglu Z, 2014, J ORGANOMET CHEM, V752, P59, DOI 10.1016/j.jorganchem.2013.12.004
- Biyiklioglu Z, 2014, DYES PIGMENTS, V100, P150, DOI 10.1016/j.dyepig.2013.09.023
- Cakir D, 2015, DALTON T, V44, P9646, DOI 10.1039/c5dt00747j
- Cakir V, 2014, J ORGANOMET CHEM, V768, P28, DOI 10.1016/j.jorganchem.2014.06.006
- Filippova A, 2017, J MOL STRUCT, V1149, P17, DOI 10.1016/j.molstruc.2017.07.086
- Goktug O, 2017, NEW J CHEM, V41, P14080, DOI 10.1039/c7nj03250a
- Gungor O, 2016, DALTON T, V45, P7634, DOI 10.1039/c6dt00874g
- Hohnholz D, 2000, J MOL STRUCT, V521, P231, DOI 10.1016/S0022-2860(99)00438-X
- Keles T, 2017, ELECTROANAL, V29, P2125, DOI 10.1002/elan.201700249
- Keles T, 2017, DYES PIGMENTS, V139, P575, DOI 10.1016/j.dyepig.2016.12.045
- Li Y, 2020, CHEM-ASIAN J, V15, P1970, DOI 10.1002/asia.202000438
- Majeed SA, 2019, J LUMIN, V213, P88, DOI 10.1016/j.jlumin.2019.04.034
- Ogbodu RO, 2020, J PHOTOCH PHOTOBIO B, V208, DOI 10.1016/j.jphotobiol.2020.111915
- Olgac R, 2017, BIOSENS BIOELECTRON, V98, P202, DOI 10.1016/j.bios.2017.06.028
- Omeroglu I, 2019, MACROHETEROCYCLES, V12, P255, DOI 10.6060/mhc190763m
- Ozmen OT, 2012, SYNTHETIC MET, V162, P2188, DOI 10.1016/j.synthmet.2012.10.013
- Porto LS, 2019, ELECTROANAL, V31, P820, DOI 10.1002/elan.201800789
- Sari FA, 2018, CHEMISTRYSELECT, V3, P13692, DOI 10.1002/slct.201802991
- Sekhosana KE, 2017, POLYHEDRON, V138, P154, DOI 10.1016/j.poly.2017.09.033
- Sen P, 2019, SYNTHETIC MET, V258, DOI 10.1016/j.synthmet.2019.116203
- Sen P, 2019, RES CHEM INTERMEDIAT, V45, P687, DOI 10.1007/s11164-018-3637-0
- Tejerina L, 2016, J PORPHYR PHTHALOCYA, V20, P1361, DOI 10.1142/S1088424616501121
- Yildiz B, 2019, SOL ENERGY, V191, P654, DOI 10.1016/j.solener.2019.09.043